← Back to Patent Explorer
US4405749A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic elastomer compositions

Assignee: Hoechst Celanese Chemical Co
•
Filing: 1982-06-04
•
Granted: 1983-09-20
•
Expires: 2002-06-04
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris-(2-hydroxyethyl)-s-triazine-2,4-6-(1H, 3H, 5H) trione.

Inventors

  • 👤 Suzanne B. Nelsen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 05:20
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/676; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34924

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 190 words
White thermoplastic elastomer composition consisting essentially of: (a) segmented thermoplastic copolyester elastomer consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head to tail through ester linkages, said long chain units being represented by the formula ##STR3## and said short chain units being represented by the formula ##STR4## where G is a divalent radical remaining after the removal of the terminal hydroxyl groups from a difunctional polyether glycol having a molecular weight in the range from about 400 to about 6,000, R is a hydrocarbon radical remaining after removal of the carboxyl groups from terephthalatic acid or isophthalic acid, and D is a divalent radical remaining after removal of hydroxyl groups from 1,4 butanediol or 1,4 butenediol; provided, (i) said short chain segments amount to between about 30% and about 85% by weight of the copolyester, and (ii) between about 10% and about 40% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4 butenediol; and (b) between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris-(2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione.
Claim 2
Dependent Claim 190 words
White thermoplastic elastomer composition consisting essentially of: (a) segmented thermoplastic copolyester elastomer consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head to tail through ester linkages, said long chain units being represented by the formula ##STR3## and said short chain units being represented by the formula ##STR4## where G is a divalent radical remaining after the removal of the terminal hydroxyl groups from a difunctional polyether glycol having a molecular weight in the range from about 400 to about 6,000, R is a hydrocarbon radical remaining after removal of the carboxyl groups from terephthalatic acid or isophthalic acid, and D is a divalent radical remaining after removal of hydroxyl groups from 1,4 butanediol or 1,4 butenediol; provided, (i) said short chain segments amount to between about 30% and about 85% by weight of the copolyester, and (ii) between about 10% and about 40% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4 butenediol; and (b) between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris-(2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione.
Claim 3
Dependent Claim 37 words
Elastomer according to claim 1 wherein G is a divalent radical remaining after removal of terminal hydroxy groups from a difunctional polyether glycol having a carbon to oxygen ratio between about 2.5 and about 4.3 to 1.
Claim 4
Dependent Claim 23 words
Elastomer according to claim 1 wherein the short chain segments amount to between about 45 and about 65% by weight of the copolyester.
Claim 5
Dependent Claim 28 words
Elastomer according to claim 1 wherein between about 20 and about 30% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4 butenediol.
Claim 6
Dependent Claim 30 words
Elastomer according to claim 4 wherein between about 1 and about 20% of the R groups are hydrocarbon radicals remaining after removal of the carboxyl groups from dimethyl isophthalic acid.
Claim 7
Dependent Claim 21 words
Elastomer according to claim 1 wherein G is a divalent radical remaining after removal of terminal hydroxyl groups from poly(tetramethylene oxide)glycol.
Claim 8
Dependent Claim 21 words
Elastomer according to claim 1 wherein G is a divalent radical remaining after removal of terminal hydroxyl groups from poly(ethylene oxide)glycol.

References Cited (Backward Citations)

US3023192A Cited
US3651014A Cited
US3766146A Cited
US3763109A Cited
US3784520A Cited
DE2408149A1 Cited
US4013614A Cited
US4156774A Cited
US4205158A Cited
US4264761A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-19 1987-03-21 1987-09-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-19 1991-03-21 1991-09-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-19 1995-03-21 1995-09-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag