Method of producing rod-shaped ZSM-5 zeolite

Claim 1

In the process for the production of high-silica ZSM-5 zeolites having a silica to alumina molar ratio of greater than 70 from a reaction mixture containing a source of alkali metal oxide, a source of silica, quaternary ammonium ion and water wherein the reaction mixture is held at elevated temperatures and pressures until crystals are formed, the improvment which comprises adding to said reaction mixture a non-fluoride buffer capable, at temperatures of about 200° C., of controlling the final pH to a value within the range of 9.5-10.5, in such amounts that about 0.1 to 0.35 equivalents of buffer per mol of silica are present in the reaction medium, so as to produce rod-shaped ZSM-5 having a length-to-width ratio greater than 3, wherein the buffer is selected from the group consisting of ammonium or alkali metal salts of phosphate, tartrate, citrate, oxalate, ethylenediaminetetraacetate and acetate.