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Isoparaffin synthesis over cadmium catalysts

Assignee: BP Corp North America Inc
•
Filing: 1987-08-03
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Granted: 1989-01-03
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Expires: 2007-08-03
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Abstract

Abstract A process for reacting synthesis gas in the presence of a cadmium-containing catalyst to selectively produce isoparaffin hydrocarbons is disclosed.

Inventors

  • 👤 Jeffrey T. Miller
  • 👤 Thomas D. Nevitt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:37
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/02; C07C1/04; C07C1/08; C07C2521/00; C07C2521/02; C07C2521/04; C07C2521/12; C07C2521/16; C07C2523/00; C07C2523/06; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/08; C07C2529/18

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 92 words
A process for producing isoparaffins from synthesis gas which comprises contacting the synthesis gas with a catalyst comprising a cadmium component and an acidic support component wherein the iso/normal paraffin ratio of butane in the product is greater than about five, and the iso/normal paraffin ratio of pentane in the product is greater than about eight when the catalyst is tested at reaction pressures above 20 atm, temperatures from 315° to 400° C., synthesis gas rates between 1400 and 2800 cc/h/g catalyst, and hydrogen to carbon monoxide ratios from 2/1 to 1/1.
Claim 2
Dependent Claim 92 words
A process for producing isoparaffins from synthesis gas which comprises contacting the synthesis gas with a catalyst comprising a cadmium component and an acidic support component wherein the iso/normal paraffin ratio of butane in the product is greater than about five, and the iso/normal paraffin ratio of pentane in the product is greater than about eight when the catalyst is tested at reaction pressures above 20 atm, temperatures from 315° to 400° C., synthesis gas rates between 1400 and 2800 cc/h/g catalyst, and hydrogen to carbon monoxide ratios from 2/1 to 1/1.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein the catalyst comprises about 5 weight percent cadmium oxide.
Claim 4
Dependent Claim 16 words
The process of claim 1 wherein the acidic support material is rare-earth-exchanged Y zeolite and alumina.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein the acidic support material is rare-earth-exchanged X zeolite and alumina.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein the acidic support material is ultrastable Y zeolite and alumina.
Claim 7
Dependent Claim 14 words
The process of claim 1 wherein the acidic support material is aluminum-expanded bentonite clay.
Claim 8
Dependent Claim 16 words
The process of claim 1 wherein the acidic support material is cadmium-exchanged Y zeolite and alumina.
Claim 9
Dependent Claim 15 words
The process of claim 1 wherein the acidic support material is H mordenite and alumina.
Claim 10
Dependent Claim 13 words
The process of claim 1 wherein the acidic support material is amorphous silica-alumina.

References Cited (Backward Citations)

GB300294A Cited
GB306471A Cited
US2478899A Cited
US4294725A Cited
US4496785A Cited
US4559363A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-01-03 1992-07-04 1993-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-01-03 1996-07-04 1997-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-01-03 2000-07-04 2001-01-03 $7700.00 Window Closed / Lapsed

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