Magnetic materials and permanent magnets

Claim 2

An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron and an intrinsic coercivity of at least 1 kOe, and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the material, at least 50 vol % of the entire material is occupied by a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure and a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co.

Claim 3

A sintered anisotropic permanent magnet having a maximum energy product of at least 10 MGOe and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet and said permanent magnet has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co.

Claim 4

A sintered anisotropic permanent magnet having a maximum energy product of at least 10 MGOe and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet and said permanent magnet has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co.

Claim 5

A sintered anisotropic permanent maget having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet and at least 50 vol % of the entire magnet is occupied by a ferromagnetic compound of an (Fe,Co)-B-R type tetragonal crystal structure which has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co, the magnet having a maximum energy product of at least 10 MGOe.

Claim 6

A sintered anisotropic permanent maget having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet and at least 50 vol % of the entire magnet is occupied by a ferromagnetic compound of an (Fe,Co)-B-R type tetragonal crystal structure which has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co, the magnet having a maximum energy product of at least 10 MGOe.

Claim 7

A permanent magnet as defined in claim 3, which contains no less than 1 vol % of nonmagnetic phases.

Claim 8

A permanent magnet as defined in claim 2 or 3, in which the mean crystal grain size is 1 to 100 microns.

Claim 9

A permanent magnet as defined in claim 5, in which the mean crystal grain size is 1.5 to 50 microns.

Claim 10

A permanent magnet as defined in claim 2 or 3, in which Co is 5 atomic percent or more.

Claim 11

A permanent magnet as defined in claim 2 or 3, in which Sm does not exceed 3 atomic percent in the entire magnet.

Claim 12

A permanent magnet as defined in claim 2 or 3, in which R is about 15 atomic percent, and B is about 8 atomic percent.

Claim 13

A permanent magnet as defined in claim 2 or 3, in which the maximum energy product is at least 20 MGOe.

Claim 14

A permanent magnet as defined in claim 10, in which the maximum energy product is at least 30 MGOe.

Claim 15

A permanent magnet as defined in claim 11, in which the maximum energy product is at least 33 MGOe.

Claim 16

An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron and an intrinsic coercivity of at least 1 kOe, and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein when more than one element comprises M, the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and up to 25 percent of the material and a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol% of the entire material: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; and which has a higher Curie Temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co and having said crystal structure.

Claim 17

An anisotropic magnetic material having a mean crystal grain size of at least about 1 micron and an intrinsic coercivity of at least 1 kOe, and having a maximum energy product of at least 10 MGOe upon sintering, said material consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein when more than one element comprises M, the sum of M is no more than the maximum value of any one of the values specified below for M actually added and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and up to 25 percent of the material and a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol% of the entire material: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; and which has a higher Curie Temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co and having said crystal structure.

Claim 18

A magnetic material as defined in claim 1 or 13, in which Sm does not exceed 3 atomic percent in the entire material.

Claim 19

A sintered anisotropic permanent magnet consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe wherein Co is substituted for Fe in an amount greater than zero and up to 25 percent of the magnet: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; said permanent magnet having a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co, and having a maximum energy product of at least 10 MGOe.

Claim 20

A sintered anisotropic permanent magnet consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe wherein Co is substituted for Fe in an amount greater than zero and up to 25 percent of the magnet: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; said permanent magnet having a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co, and having a maximum energy product of at least 10 MGOe.

Claim 21

A sintered anisotropic permanent magnet having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the amount of M is not zero and wherein when more than one element comprises M, the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; in which a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol % of the entire magnet and which has a maximum energy product of at least 10 MGOe and a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co.

Claim 22

A sintered anisotropic permanent magnet having a mean crystal grain size of at least about 1 micron and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected from the group given below in the amounts of no more than the atomic percentages specified below wherein the amount of M is not zero and wherein when more than one element comprises M, the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the magnet: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; in which a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol % of the entire magnet and which has a maximum energy product of at least 10 MGOe and a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co.

Claim 23

A permanent magnet as defined in claim 16, which contains no less than 1 vol % of nonmagnetic phases.

Claim 24

A permanent magnet as defined in claim 15 or 16, in which the mean crystal grain size is 1 to 100 microns.

Claim 25

A permanent magnet as defined in claim 18, in which the mean crystal grain size is 1.5 to 50 microns.

Claim 26

A permanent magnet as defined in claim 15 or 16, in which Co is 5 atomic percent or more.

Claim 27

A permanent magnet as defined in claim 15 or 16, in which Sm does not exceed 3 atomic percent in the entire magnet.

Claim 28

A magnetic material as defined in claim 13, in which Sm does not exceed 3 atomic percent in the entire material.

Claim 29

A permanent magnet as defined in claim 15 or 16, in which R is about 15 atomic percent, and B is about 8 atomic percent.

Claim 30

A permanent magnet as defined in claim 15 or 16 in which the maximum energy product is at least 20 MGOe.

Claim 31

A permanent magnet as defined in claim 24, in which the maximum energy product is at least 30 MGOe.

Claim 32

A permanent magnet as defined in claim 25, in which the maximum energy product is at least 33 MGOe.

Claim 33

A magnetic material as defined in claim 1 or 13, wherein R is about 15 atomic percent and B is about 8 atomic percent.

Claim 34

A magnetic article in the form of powder compact or sintered mass of the magnetic material as defined in any of claims 1 and 13.

Claim 35

A sintered anisotropic permanent magnet as defined in claim 3 or 16, wherein said (Fe,Co)-B-R type tetragonal crystal structure has the lattice constants Ao of about 8.8 angstroms and Co of about 12 angstroms.

Claim 36

A magnet as defined in claim 15 or 16, wherein said additional element(s) M is at least one selected from the group consisting of V, Nb, Mo, W and Al.

Claim 37

A magnet as defined in claim 31, wherein said additional element(s) M is contained no more than the amount of atomic percent as specified below: 3.5% V, 6.4% Nb, 4.1% Mo, 3.9% W, and 3.8% Al; wherein the sum of M does not exceed the maximum value of any one of the values specified above for M actually added.

Claim 38

A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the material and at least 50 vol. % of the entire material is occupied by a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure, and which has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co.

Claim 39

A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the material and at least 50 vol. % of the entire material is occupied by a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure, and which has a higher Curie temperature than a corresponding ferromagnetic Fe-B-R base compound containing no Co.

Claim 40

A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected form the group given below in the amounts of no more than the atomic percentages for any one of the elements specified below wherein the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the material and a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol. % of the entire material: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; the magnetic material having a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co.

Claim 41

A powdery magnetic material capable of uniaxial alignment upon orientation in a magnetic field to provide magnetic anisotropy, and having a maximum energy product of at least 10 MGOe and an intrinsic coercivity of at least 1 kOe upon sintering, said material having a mean crystal grain size of at least about 1 micron, and consisting essentially of, by atomic percent, 12-20 percent R wherein R is at least one element selected from the group consisting of Nd, Pr, La, Ce, Tb, Dy, Ho, Er, Eu, Sm, Gd, Pm, Tm, Yb, Lu and Y and wherein at least 50% of R consists of Nd and/or Pr, 5-18 percent B, at least one additional element M selected form the group given below in the amounts of no more than the atomic percentages for any one of the elements specified below wherein the sum of M does not exceed the maximum value of any one of the values specified below for M actually added, and the balance being at least 62 percent Fe, in which Co is substituted for Fe in an amount greater than zero and not exceeding 25 percent of the material and a crystal phase of a ferromagnetic compound having an (Fe,Co)-B-R type tetragonal crystal structure occupies at least 50 vol. % of the entire material: 3.4% Ti, 6.5% Ni, 5.0% Bi, 6.8% V, 9.6% Nb, 8.3% Ta, 5.4% Cr, 6.1% Mo, 6.0% W, 6.0% Mn, 6.3% Al, 1.3% Sb, 4.2% Ge, 2.0% Sn, 4.2% Zr, and 4.2% Hf; the magnetic material having a higher Curie temperature than a corresponding ferromagnetic Fe-B-R-M base composition containing no Co.

Claim 42

A magnetic material as defined in claim 1, 13, 32 or 33, wherein said (Fe,Co)-B-R type tetragonal crystal structure has the lattice constants Ao of about 8.8 angstroms and Co of about 12 angstroms.

Claim 43

A magnetic article in the form of powder compat or sintered mass of the magnetic material as defined in claim 34.

Claim 44

A sintered anisotropic permanent magnet as defined in claim 2, 3, 15 or 16, in which Si does not exceed 5 atomic percent.

Claim 45

A sintered anisotropic permanent magnet as defined in claim 2, 3, 15 or 16, in which R is Nd.

Claim 46

A sintered anisotropic permanent magnet as defined in claim 2, 3, 15 or 16, in which Co is present in at least 1 atomic percent.

Claim 47

A magnetic material as defined in claim 1, 13, 32 or 33, in which Co is present in at least 1 atomic percent.

Claim 48

A magnet or material as defined in claim 1, 2, 3, 13, 15, 16, 32 or 33 wherein oxygen is present in an amount of not more than 1 at %.