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US4791005A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the manufacture of silicon oxide layers doped with boron and phosphorus

Assignee: Siemens AG
•
Filing: 1987-10-27
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Granted: 1988-12-13
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Expires: 2007-10-27
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Abstract

Abstract A method for the manufacture of silicon layers containing boron and phosphorus dopants wherein the silicon wafers are positioned in a reaction chamber into which there is introduced, from separate sources, (a) tetraethylorthosilicate as a source of silicon dioxide, (b) trimethylborate as a source of boron, and (c) a phosphorus source. The three reactants are decomposed in the reaction chamber to deposit silicon dioxide doped with boron and phosphorus onto the wafers, the decomposition being carried out at a temperature of at least 600° C. and at a substantially subatmospheric pressure.

Inventors

  • 👤 Frank S. Becker
  • 👤 Dieter Pawlik

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:57
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6334; H10P14/69; H10P14/692; H10P14/6921; H10P14/69215; H10P14/6922; H10P14/6923

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 130 words
A method for the manufacture of silicon oxide layers doped with boron and phosphorus which is stable in contact with water comprises: providing a reaction chamber, positioning silicon wafers in said reaction chamber, introducing into said reaction chamber form separate sources, the reactants; (a) tetraethylorthosilicate (b) trimethylborate and (c) a phosphorus source consisting of trimethylphosphate and passing said trimethylphosphate and said trimethylborate in one direction through said reaction chamber and passing said tetraethylorthosilicate through said reaction chamber in the opposite direction, and decomposing said reactants in said reaction chamber to deposit silicon dioxide doped with boron and phosphorus onto said wafers, the decomposition being carried out at a temperature of at least 600° C. and at a substantially sub-atmospheric pressure, the resulting deposite containing at least 5% by weight boron.
Claim 2
Independent Claim 130 words
A method for the manufacture of silicon oxide layers doped with boron and phosphorus which is stable in contact with water comprises: providing a reaction chamber, positioning silicon wafers in said reaction chamber, introducing into said reaction chamber form separate sources, the reactants; (a) tetraethylorthosilicate (b) trimethylborate and (c) a phosphorus source consisting of trimethylphosphate and passing said trimethylphosphate and said trimethylborate in one direction through said reaction chamber and passing said tetraethylorthosilicate through said reaction chamber in the opposite direction, and decomposing said reactants in said reaction chamber to deposit silicon dioxide doped with boron and phosphorus onto said wafers, the decomposition being carried out at a temperature of at least 600° C. and at a substantially sub-atmospheric pressure, the resulting deposite containing at least 5% by weight boron.
Claim 3
Dependent Claim 19 words
A method according to claim 1 wherein said subatmospheric pressure is in the range from 15 to 100 Pa.
Claim 4
Dependent Claim 18 words
A method according to claim 1 wherein said temperature is in the range from 600° to 700° C.
Claim 5
Dependent Claim 30 words
A method according to claim 1 wherein the temperature of said tetraethylorthosilicate and said trimethylborate are in the rnage of 30° to 60° C. when introduced into said reaction chamber.
Claim 6
Dependent Claim 24 words
A method according to claim 4 wherein the temperature of said phosphorus source is more than 60° C. when introduced into said reaction chamber.
Claim 7
Dependent Claim 21 words
A method according to claim 1 wherein said reactants are introduced into said reaction chamber by means of a carrier gas.
Claim 8
Dependent Claim 12 words
A method according to claim 6 wherein said carrier gas is nitrogen.
Claim 9
Dependent Claim 12 words
A method according to claim 6 wherein said carrier gas is oxygen.

References Cited (Backward Citations)

US3571914A Cited
US3481781A Cited
US4217375A Cited
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US4324576A Cited
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US4546016A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-13 1992-06-13 1992-12-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-13 1996-06-13 1996-12-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-13 2000-06-13 2000-12-13 $7700.00 Window Closed / Lapsed

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