Curable resin from bis maleimide and alkenyl phenyl hydroxy ether

Claim 2

Curable resin comprising a mixture of (a) at least one bisimide of the general formula I ##STR17## in which B represents a divalent radical containing a carbon-carbon double bond and A is a divalent radical containing at least two carbon atoms and (b) at least one alkenyl compound of formula IIg G[OCH.sub.2 CH(OH)CH.sub.2 O]E[OCH.sub.2 CH(OH)CH.sub.2 O]G (IIg) in which E is a m-phenylene group or a group of formula IIh ##STR18## and G represents a group of formula IIj or IIk ##STR19## or of formula IIm or IIn ##STR20##

Claim 3

Curable bisimide resin according to claim 1 in which the bisimide of the general formula I is characterised in that A is a member selected from the groups consisting of (a) an alkylene group with up to 12 carbon atoms, (b) a cycloalkylene group with 5 or 6 carbon atoms, (c) a heterocyclic group with 4 to 5 carbn atoms and at least one nitrogen, oxygen or sulphur atom in the ring, (d) a mono or dicarbocyclic group, (e) at least two mono or dicarbocyclic aromatic or cycloalkylene groups which are connected to one another by a direct carbon-carbon bond or by a bivalent group chosen from oxygen, sulphur, alkylene with one to three carbon atoms, or a group of formulae IIIa to IIIj ##STR21## the radicals R 1 , R 2 , R 3 , R 4 , being alkyl groups with one to five carbon atoms, R 5 being an alkylene group or an arylene group and B is a group which is capable of addition polymerization selected from a group of formula IV, V, VI or VII ##STR22##

Claim 4

Curable bisimide resin as claimed in claim 2 in which the bisimide of formula I is selected from the group consisting of 1,2-bismaleimidoethane, 1,6-bismaleimidohexane, 1,12-bismaleimidododecane, 1,6-bismaleimido(2,2,4-trimethyl)hexane, 1,3-bismaleimidobenzene, 1,4-bismaleimidobenzene, 4,4'-bismaleimidodiphenylmethane, 4,4'-bismaleimidodiphenylether, 4,4'-bismaleimidodiphenylsulphide, 3,3'-bismaleimidodiphenylsulphone, 4,4'-bismaleimidodiphenylsulphone, 4,4'-bismaleimidodicyclohexylmethane, 2,4-bismaleimidotoluene, 2,6-bismaleimidotoluene, 2,4-bismaleimidoanisole, N,N'-m-xylylenebismaleimide, N,N'-p-xylylenebismaleimide and mixtures thereof.

Claim 5

Curable bisimide resin as claimed in claim 3 in which the bisimide of formula I comprises (i) eutectic mixtures containing 4,4'-bismaleimidodiphenylmethane and 2,4-bismaleimidotoluene, (ii) eutectic mixtures containing 4,4'-bismaleimidodiphenylmethane, 2,4-bismaleimidotoluene and 1,6-bismaleimido(2,2,4-trimethyl)hexane and (iii) eutectic mixtures of 4,4'-bismaleimidodiphenylmethane and 2,4-bismaleimidoanisole.

Claim 6

Curable bisimide resin as claimed in claim 1 wherein the ratio of the number of moles of bisimide present to the number of moles of alkenyl compound present lies in the range 1:1 to 50:1.

Claim 7

Curable resin as claimed in claim 1 in which a catalyst is present in an amount of 0.01 to 10% by weight based on the total weight of the curable bisimide resin.

Claim 8

Prepolymer obtained by heating the curable resin as claimed in claim 1 to temperatures of between 80° and 200° C. for a time sufficient to obtain a still formable product.

Claim 9

Solution of curable resin as claimed in claim 1 in an inert organic solvent selected from dimethylformamide, dimethylacetamide, N-methyl pyrrolidone, tetramethyl urea, acetone, methylethyl ketone, methylisobutyl ketone, cyclohexanone, methylene chloride, ethyl chloride, 1,2-dichloroethane, dioxane, tetrahydrofuran, ethyl glycol, ethyl acetate, ethyl glycol acetate, methyl glycol acetate, diethyleneglycol diethyl ether, diethyleneglycol monoethyl ether acetate and mixtures thereof in which the resin is present in a concentration of 25 to 65% of the solution by weight.

Claim 10

Crosslinked polymer derived by heating the curable resin mixture of claim 1 or the prepolymers of claim 7 to temperatures of between 80° and 400° C. for a time sufficient to complete cure.

Claim 11

Fibrous material impregnated with curable resin as claimed in claim 1, prepolymer as claimed in claim 7 or solution as claimed in claim 8.

Claim 12

Film cast from solution of curable resin as claimed in claim 8.

Claim 13

Moulding composition comprising a curable resin as claimed in any one of claims 1 to 6 or prepolymer as claimed in claim 7 and additives selected from fillers, colourants, softeners or flameproofing agents.