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US4789610A
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Solid-electrolyte secondary cell
Assignee: Panasonic Holdings Corp
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Filing: 1987-09-11
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Granted: 1988-12-06
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Expires: 2007-09-11
Abstract
Abstract A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu x Mo 6 S 8 ), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm 2 , can stand high temperatures of up to 100° C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K q Rb 1-q Cu 4 I 2-p Cl 3+3 (0≦q≦0.5, 0.25≦p≦1.0) for both positive and negative electrodes.
Inventors
- 👤 Shigeo Kondo
- 👤 Tadashi Sotomura
- 👤 Teruhisa Kanbara
- 👤 Satoshi Sekido
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:44
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/056; H01M10/0561; H01M10/0562; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/581; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
30 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are mainly composed of a copper chevrel compound, and a copper ion conductive solid electrolyte.
Claim 2
Dependent Claim
30 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are mainly composed of a copper chevrel compound, and a copper ion conductive solid electrolyte.
Claim 3
Dependent Claim
62 words
A solid-electrolyte secondary cell according to claim 1, characterized by using a copper chevrel compound represented by the chemical formula Cu x Mo 6 S 8 , wherein the sum "a" of the value of x of the copper chevrel compound of the positive electrode and that of the copper chevrel compound of the negative electrode falls in the range of 1<a<10.
Claim 4
Dependent Claim
16 words
A solid-electrolyte secondary cell according to claim 2, wherein "a" is in the range of 5≦a<10.
Claim 5
Dependent Claim
26 words
A solid-electrolyte secondary cell according to claim 3, wherein the value of x of the copper chevrel compound used for positive and negative electrodes is 4.
Claim 6
Dependent Claim
40 words
A solid-electrolyte secondary cell according to claim 3, wherein the value of x of the copper chevrel compound used for positive electrode is 4, and the value of x of the copper chevrel compound used for negative electrode is 2.
Claim 7
Dependent Claim
40 words
A solid-electrolyte secondary cell according to claim 3, wherein the value of x of the copper chevrel compound used for positive electrode is 2, and the value of x of the copper chevrel compound used for negative electrode is 4.
Claim 8
Dependent Claim
80 words
A solid-electrolyte secondary cell according to claim 2, wherein the sum "a" of the value of x of the copper chevrel compound of positive electrode and that of the copper chevrel compound of negative electrode is in the range of 1<a≦5, and the amount of the copper chevrel compound used for negative electrode, as calculated in terms of gram equivalent based on monovalent Cu, is smaller than the similarly calculated amount of the copper chevrel compound used for positive electrode.
Claim 9
Dependent Claim
47 words
A solid-electrolyte secondary cell according to claim 7, wherein the amount of the copper chevrel compound of negative electrode, as calculated in terms of gram equivalent based on monovalent Cu, is (a-1)/4 or less of the similarly calculated amount of the copper chevrel compound of positive electrode.
Claim 10
Dependent Claim
26 words
A solid-electrolyte secondary cell according to claim 7 wherein the value of x of the copper chevrel compound used for positive and negative electrodes is 2.
Claim 11
Dependent Claim
31 words
A solid-electrolyte secondary cell according to claim 1, wherein the positive and negative electrodes are made of a mixture of a copper chevrel compound and a copper ion conductive solid electrolyte.
Claim 12
Dependent Claim
46 words
A solid-electrolyte secondary cell according to claim 10, wherein the positive and negative electrodes are made of a mixture of a copper chevrel compound and a copper ion conductive solid electrolyte, said mixture having been heat treated in an inert gas atmosphere or under reduced pressure.
Claim 13
Dependent Claim
35 words
A solid-electrolyte secondary cell according to claim 1, wherein the copper ion conductive solid electrolyte used is the one represented by the formula K q Rb 1-q Cu 4 I 2-p Cl 3+p (0≦q≦0.5, 0.25≦p≦1.0).
Claim 14
Dependent Claim
71 words
A solid-electrolyte secondary cell according to claim 11, wherein the positive and negative electrodes are made of a mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K q Rb 1-q Cu 4 I 2-p Cl 3+p (0≦q≦0.5, 0.25≦p≦1.0), said mixture having been heat treated in an inert gas atmosphere or under reduced pressure at a temperature of 130° C. to 240° C.
Claim 15
Dependent Claim
39 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are composed of a copper chevrel compound alone, and a copper ion conductive solid electrolyte, the whole being constructed as an integral solid structure.
Claim 16
Dependent Claim
39 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are composed of a copper chevrel compound alone, and a copper ion conductive solid electrolyte, the whole being constructed as an integral solid structure.
Claim 17
Dependent Claim
81 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are mainly composed of a copper chevrel compound represented by the formula Cu x Mo 6 S 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes, wherein the sum "a" of the value of x of the copper chevrel compound of positive electrode and that of the copper chervel compound of negative electrode falls within the range of 1<a<10.
Claim 18
Dependent Claim
81 words
A solid-electrolyte secondary cell comprising a positive electrode and a negative electrode both of which are mainly composed of a copper chevrel compound represented by the formula Cu x Mo 6 S 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes, wherein the sum "a" of the value of x of the copper chevrel compound of positive electrode and that of the copper chervel compound of negative electrode falls within the range of 1<a<10.
Claim 19
Dependent Claim
59 words
A solid-electrolyte secondary cell comprising a positive electrode mainly composed of a copper chevrel compound represented by the formula Cu 4 Mo 6 S 8 , a negative electrode mainly composed of a copper chevrel compound represented by the formula Cu 2 MoS 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes.
Claim 20
Dependent Claim
59 words
A solid-electrolyte secondary cell comprising a positive electrode mainly composed of a copper chevrel compound represented by the formula Cu 4 Mo 6 S 8 , a negative electrode mainly composed of a copper chevrel compound represented by the formula Cu 2 MoS 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes.
Claim 21
Dependent Claim
59 words
A solid-electrolyte secondary cell comprising a positive electrode mainly composed of a copper chevrel compound represented by the formula Cu 2 Mo 6 S 8 , a negative electrode mainly composed of a copper chevrel compound represented by the formula Cu 4 MoS 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes.
Claim 22
Dependent Claim
59 words
A solid-electrolyte secondary cell comprising a positive electrode mainly composed of a copper chevrel compound represented by the formula Cu 2 Mo 6 S 8 , a negative electrode mainly composed of a copper chevrel compound represented by the formula Cu 4 MoS 8 , and a copper ion conductive solid electrolyte disposed between said positive and negative electrodes.
Claim 23
Dependent Claim
90 words
A solid-electrolyte secondary cell comprising a negative electrode made of a mixture of a copper chevrel compound represented by the formula Cu x Mo 6 S 8-y (2<x<4, 0<y<0.2) and a solid electrolyte, a positive electrode made of a mixture of a copper chevrel compound represented by the formula Cu x Mo 6 S 8-y (0<x<2, 0<y<0.2) and said solid electrolyte, and an electrolyte of the formula K x Rb 1`x Cu 4 l 1 .5 Cl 3 .5 (0<x<0.2) which is the same in composition as said solid electrolyte.
Claim 24
Dependent Claim
90 words
A solid-electrolyte secondary cell comprising a negative electrode made of a mixture of a copper chevrel compound represented by the formula Cu x Mo 6 S 8-y (2<x<4, 0<y<0.2) and a solid electrolyte, a positive electrode made of a mixture of a copper chevrel compound represented by the formula Cu x Mo 6 S 8-y (0<x<2, 0<y<0.2) and said solid electrolyte, and an electrolyte of the formula K x Rb 1`x Cu 4 l 1 .5 Cl 3 .5 (0<x<0.2) which is the same in composition as said solid electrolyte.
Claim 25
Dependent Claim
26 words
A solid-electrolyte secondary cell according to claim 8, wherein the value of x of the copper chevrel compound used for positive and negative electrodes is 2.
References Cited (Backward Citations)
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