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US4789426A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for performing variable selectivity polysilicon etch

Assignee: Intersil Corp
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Filing: 1987-01-06
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Granted: 1988-12-06
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Expires: 2007-01-06
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Abstract

Abstract A method for controllably varying the selectivity of reactive etching process for etching a polysilicon film, involves the addition of an adjustable amount of oxygen (O2) to a chlorine based chemistry (e.g. Cl2, HCl) during the etching process. The adjustable amount of oxygen permits the selectivity to be varied from a low to moderate rate at the beginning of the etch and through most of the film thickness to as high a selectivity as is required for overetch, to allow anisotropic removal of polysilicon without penetrating thin oxide. Selectivity is effectively proportional to the oxygen concentration and may be varied from a low to moderate selectivity value (e.g. 20:1) to a high selective value (e.g. 100:1) of polysilicon oxide etch rate in a controlled manner.

Inventors

  • 👤 Mark A. Pipkin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:39
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 61 words
A method of controllably enhancing the etch rate of a layer of polysilicon relative to the etch rate of an oxide layer each of which layers is to be simultaneously exposed to a prescribed chlorine chemistry-based etch system, comprising the step of controllably modifying the composition of said chlorine chemistry-based etch system by controllably introducing thereinto an adjustable amount of oxygen.
Claim 2
Independent Claim 61 words
A method of controllably enhancing the etch rate of a layer of polysilicon relative to the etch rate of an oxide layer each of which layers is to be simultaneously exposed to a prescribed chlorine chemistry-based etch system, comprising the step of controllably modifying the composition of said chlorine chemistry-based etch system by controllably introducing thereinto an adjustable amount of oxygen.
Claim 3
Dependent Claim 46 words
A method according to claim 1, wherein the amount of oxygen in said system is adjusted over a range of oxygen concentration of an amount up to 7 percent sufficient to provide a selectivity of etch of polysilicon:oxide over a range of from 20 to 160.
Claim 4
Dependent Claim 16 words
a method according to claim 1, wherein said etch system comprises a reactive ion etch system.
Claim 5
Dependent Claim 31 words
A method according to claim 3, wherein said chlorine-based reactive ion etch system comprises a gas selected from the group consisting of Cl 2 , HCl, BCl 3 and mixtures thereof.
Claim 6
Dependent Claim 33 words
A method according to claim 3, further including the step of introducing a relatively high atomic mass inert gas into said system so as to further enhance the etch of said polysilicon layer.
Claim 7
Dependent Claim 25 words
A method according to claim 5, wherein said high atomic mass inert gas includes one selected from the group consisting of argon, krypton and xenon.
Claim 8
Independent Claim 143 words
A method of manufacturing a semiconductor device comprising the steps of: (a) selectively forming an insulator layer on a surface of semiconductor substrate so as to expose said surface through an aperture in said insulator layer; (b) forming a thin oxide layer on said exposed surface of said substrate: (c) forming a layer of polysilicon on said insulator layer and on said thin oxide layer; (d) exposing a selected portion of the polysilicon layer and thin oxide layer resulting from step (c) to an anisotropic chlorine chemistry-based etch system; and (e) during step (d) controllably introducing oxygen into said anisotropic etch system so as to increase the ratio of the etch rate of said system for polysilicon to the etch rate of said system for oxide and thereby remove said selected portion of the polysilicon layer without effectively removing said thin oxide layer.
Claim 9
Independent Claim 143 words
A method of manufacturing a semiconductor device comprising the steps of: (a) selectively forming an insulator layer on a surface of semiconductor substrate so as to expose said surface through an aperture in said insulator layer; (b) forming a thin oxide layer on said exposed surface of said substrate: (c) forming a layer of polysilicon on said insulator layer and on said thin oxide layer; (d) exposing a selected portion of the polysilicon layer and thin oxide layer resulting from step (c) to an anisotropic chlorine chemistry-based etch system; and (e) during step (d) controllably introducing oxygen into said anisotropic etch system so as to increase the ratio of the etch rate of said system for polysilicon to the etch rate of said system for oxide and thereby remove said selected portion of the polysilicon layer without effectively removing said thin oxide layer.
Claim 10
Dependent Claim 19 words
A method according to claim 7, wherein said anisotropic chlorine chemistry-based etch system comprises a reactive ion etch system.
Claim 11
Dependent Claim 33 words
A method according to claim 7, wherein said anisotropic chlorine chemistry-based reactive ion etch system comprises a gas selected from the group consisting of Cl 2 , HCl, BCl 3 and mixtures thereof.
Claim 12
Dependent Claim 40 words
A method according to claim 7, further including the step of (f) during step (d), introducing a relatively high atomic mass inert gas into said system so as to enhance the removal of said selected portion of said polysilicon layer.
Claim 13
Dependent Claim 40 words
A method according to claim 7, wherein step (d) comprises masking a portion of said polysilicon layer other than said selected portion thereof and exposing said selected portion and said thin oxide layer to said chlorine chemistry-based anisotropic etch system.
Claim 14
Dependent Claim 17 words
A method according to claim 11, wherein said anisotropic etch system comprises a reactive ion etch system.
Claim 15
Dependent Claim 51 words
A method according to claim 12, further including the step of (f) during step (d), introducing a relatively high atomic mass inert gas into said system so as to enhance the removal of said selected portion of said polysilicon layer without substantially side etching the masked portion of said polysilicon layer.
Claim 16
Dependent Claim 27 words
A method according to claim 13, wherein said polysilicon layer is a highly doped N-type polysilicon layer having a sheet resistance less than 30 ohms per square.

References Cited (Backward Citations)

US4543597A Cited
US4615764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-12-06 1992-06-06 1992-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-12-06 1996-06-06 1996-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-12-06 2000-06-06 2000-12-06 $7700.00 Window Closed / Lapsed

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