US4786327A
Expired / Lapsed
US
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Dye preparation for thermal ink-jet printheads using ion exchange
Assignee: HP Inc
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Filing: 1986-09-29
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Granted: 1988-11-22
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Expires: 2006-09-29
Abstract
Abstract A process is provided for reducing the crusting propensity of dyes, complexed with sodium or other cations, used in ink-jet print heads and for improving other properties of such dyes. The process comprises replacing at least a portion of the cations on such dyes with preselected cations, such as those of the alkali metals lithium, potassium, ammonium, and amines. A two-step process may be used, in which the sodium cations first are at least partially replaced with hydrogen cations by passing an aqueous solution of the dye through the hydrogen form of a strong acid ion exchange resin and the hydrogen cations subsequently are at least partially replaced with the preselected cations by neutralizing the hydrogen-containing dye solution with a base which contains the preselected cation species. Alternately, a one-step process, comprising passing the aqueous solution of the dye through an ion-exchange resin pre-loaded with the preselected cations may be employed.
Inventors
- 👤 Donald E. Wenzel
- 👤 Loren E. Johnson
- 👤 Hiang P. Lauw
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 08:14
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09D11/328; C09B; C09B67/00; C09B67/0096
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
109 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which a first cation species is associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) replacing at least a portion of said first cation species on said dye with a preselected second cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quaternary amines, protonated primary, secondary and tertiary amines and ammonium, employing an ion exchange resin, to form an ion-exchanged dye; and (b) admixing said ion-exchanged dye with said vehicle to form said ink.
Claim 2
Dependent Claim
109 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which a first cation species is associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) replacing at least a portion of said first cation species on said dye with a preselected second cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quaternary amines, protonated primary, secondary and tertiary amines and ammonium, employing an ion exchange resin, to form an ion-exchanged dye; and (b) admixing said ion-exchanged dye with said vehicle to form said ink.
Claim 3
Dependent Claim
19 words
The process of claim 1 wherein said dye containing said first cation species is purified prior to said cation-replacing.
Claim 4
Dependent Claim
13 words
The process of claim 2 wherein said dye is purified by reverse osmosis.
Claim 5
Dependent Claim
14 words
The process of claim 1 wherein said first cation species consists essentially of sodium.
Claim 6
Dependent Claim
42 words
The process of claim 1 wherein at least a portion of said first cation species on said dye is replaced with hydrogen cations by passing an aqueous solution of said dye through the hydrogen form of a strong acid ion exchange resin.
Claim 7
Dependent Claim
41 words
The process of claim 5 wherein at least a portion of said hydrogen cations on said dye are subsequently replaced by said preselected second cation species by neutralizing said dye in a base comprising said preselected cation species and hydroxide anions.
Claim 8
Dependent Claim
20 words
The process of claim 6 wherein said hydrogencontaining dye is neutralized to a pH ranging from about 4 to 10.
Claim 9
Dependent Claim
46 words
The process of claim 1 wherein at least a portion of said first cation species on said dye are replaced with said preselected second cation species by passing an aqueous solution of said dye through an ion exchange resin loaded with said preselected second cation species.
Claim 10
Dependent Claim
32 words
The process of claim 1 wherein said preselected second cation species comprises at least one member selected from the group consisting of lithium, potassium, tetramethyl amine, triethanol amine, diethylene amine, and ammonium.
Claim 11
Dependent Claim
19 words
The process of claim 1 wherein following said ion exchange, said dye solution is concentrated to a desired concentration.
Claim 12
Dependent Claim
14 words
The process of claim 10 wherein said dye solution is concentrated using reverse osmosis.
Claim 13
Dependent Claim
37 words
The process of claim 1 wherein said vehicle comprises at least one component selected from the group consisting of glycols, glycerol, half ethers and ethers of propylene glycols, ethers of glyceryl, alcohols, esters, polymeric glycols, and water.
Claim 14
Dependent Claim
127 words
The process of claim 12 wherein said at least one component comprises a member selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,5-hexanediol, hexylene glycol, propylene glycol monomethyl ether, propylene glycol isopropyl ether, propylene glycol n-butyl ether, propylene glycol ethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol ethyl ether, dipropylene glycol n-butyl ether, dipropylene glycol iso-propyl ether, tripropylene glycol monomethyl ether, tripropylene glycol ethyl ether, tripropylene glycol n-butyl ether, tripropylene glycol, glyceryl α-monmethyl ether, glyceryl α,γ-dimethyl ether, glyceryl α-mono-n-butyl ether, secbutyl alcohol, tert-amyl alcohol, cyclohexyl alcohol, secoctyl alcohol, diacetone alcohol, benzyl alcohol, isopropanol, n-propanol, methanol, ethanol, butyl lactate, ethyl lactate, n-butyl propionate, PEG 200, PEG 300, PEG 400, and PPG 400.
Claim 15
Dependent Claim
162 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which sodium cations are associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) replacing at least a portion of said sodium cations on said dye with hydrogen cations to form a dye containing hydrogen cations by passing an aqueous solution of said dye through the hydrogen form of a strong acid ion exchange resin; (b) neutralizing said dye containing said hydrogen cations by adding a base comprising a preselected cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quaternary amines, protonated primary, secondary and tertiary amines and ammonium and an anion species comprising hydroxide to form a dye solution containing said preselected cations and having a pH ranging from about 4 to 10; and (c) admixing said neutralized dye solution with said vehicle to form said ink.
Claim 16
Dependent Claim
162 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which sodium cations are associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) replacing at least a portion of said sodium cations on said dye with hydrogen cations to form a dye containing hydrogen cations by passing an aqueous solution of said dye through the hydrogen form of a strong acid ion exchange resin; (b) neutralizing said dye containing said hydrogen cations by adding a base comprising a preselected cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quaternary amines, protonated primary, secondary and tertiary amines and ammonium and an anion species comprising hydroxide to form a dye solution containing said preselected cations and having a pH ranging from about 4 to 10; and (c) admixing said neutralized dye solution with said vehicle to form said ink.
Claim 17
Dependent Claim
18 words
The process of claim 14 wherein said dye containing said sodium cations is purified prior to said cationreplacing.
Claim 18
Dependent Claim
13 words
The process of claim 15 wherein said dye is purified by reverse osmosis.
Claim 19
Dependent Claim
26 words
The process of claim 14 wherein said amine comprises at least one member selected from the group consisting of tetramethyl amine, triethanol amine, and diethylene amine.
Claim 20
Dependent Claim
19 words
The process of claim 14 wherein said following said neutralizing, said dye solution is concentrated to a desired concentration.
Claim 21
Dependent Claim
14 words
The process of claim 18 wherein said dye solution is concentrated using reverse osmosis.
Claim 22
Dependent Claim
13 words
The process of claim 14 wherein said vehicle comprises at least one glycol.
Claim 23
Dependent Claim
24 words
The process of claim 20 wherein said glycol comprises a member selected from the group consisting of diethylene glycol, triethylene glycol, and polyethylene glycol.
Claim 24
Dependent Claim
201 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which sodium cations are associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) forming an aqueous dye solution of said dye; (b) purifying said dye solution to remove chloride ions, excess sodium ions and impurities; (c) replacing at least a portion of said sodium cations on said dye with hydrogen cations to form a dye containing hydrogen cations by passing said aqueous solution of said dye through the hydrogen form of a strong acid ion exchange resin; (d) neutralizing said dye containing said hydrogen cations by adding a base comprising a preselected cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quarternary amines, protonated primary, secondary and tertiary amines and ammonium and an anion species comprising hydroxide to form a dye solution containing said preselected cations and having a pH ranging from about 6 to 7; (e) concentrating said dye solution to achieve a desired concentration; and (f) admixing said ion-exchanged dye with said vehicle to form said ink, said vehicle comprising at least one glycol.
Claim 25
Dependent Claim
201 words
A process for preparing an ink composition comprising a vehicle and a dye having associated therewith at least one sulfonate group with which sodium cations are associated, said ink composition suitable for use in ink-jet printing, said process comprising: (a) forming an aqueous dye solution of said dye; (b) purifying said dye solution to remove chloride ions, excess sodium ions and impurities; (c) replacing at least a portion of said sodium cations on said dye with hydrogen cations to form a dye containing hydrogen cations by passing said aqueous solution of said dye through the hydrogen form of a strong acid ion exchange resin; (d) neutralizing said dye containing said hydrogen cations by adding a base comprising a preselected cation species comprising at least one member selected from the group consisting of alkali metals, alkaline-earth metals, quarternary amines, protonated primary, secondary and tertiary amines and ammonium and an anion species comprising hydroxide to form a dye solution containing said preselected cations and having a pH ranging from about 6 to 7; (e) concentrating said dye solution to achieve a desired concentration; and (f) admixing said ion-exchanged dye with said vehicle to form said ink, said vehicle comprising at least one glycol.
Claim 26
Dependent Claim
26 words
The process of claim 22 wherein said amine comprises at least one member selected from the group consisting of tetramethyl amine, triethanol amine, and diethylene amine.
Claim 27
Dependent Claim
24 words
The process of claim 20 wherein said glycol comprises a member selected from the group consisting of diethylene glycol, triethylene glycol, and polyethylene glycol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-11-22 | 1992-05-23 | 1992-11-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-11-22 | 1996-05-23 | 1996-11-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-11-22 | 2000-05-23 | 2000-11-22 | $7700.00 | Window Closed / Lapsed |