Lubricant additive comprising mixed hydroxyester or diol/phosphorodithioate-derived borates

Claim 2

The reaction product produced by: (a) reacting a phosphorodithioic acid and an epoxide, hydroxyester, or diol resulting in an intermediate product; and (b) reacting the intermediate product with a borating compound and a hydroxy-bearing compound to produce the desired reaction product, each reaction being conducted at a temperature between about 10° C. and about 150° C. for a period of between about 1 and about 48 hours in a proportion of reactants of about 1 mole of each.

Claim 3

The reaction product of claim 1 wherein the phosphorodithioic acid has the formula: (RO).sub.2 PSSH where R is a C 3 to C 30 hydrocarbyl or oxyhydrocarbylene group, or mixtures thereof.

Claim 4

The reaction product of claim 1 wherein the epoxide has the structural formula: ##STR3## where R 1 , R 2 , R 3 , and R 4 are hydrogen or a C 1 to C 30 hydrocarbyl group optionally containing sulfur, nitrogen, or oxygen atoms.

Claim 5

The reaction product of claim 1 wherein the hydroxy-bearing compound has the structural formula: (HO).sub.x R.sup.5 where R 5 is hydrogen or C 1 to C 30 hydrocarbyl group and optionally contains ester, amide, oxygen, nitrogen and/or sulfur groups, and x is 1 to 10.

Claim 6

The reaction product of claim 1 wherein the borating agent is selected from the group consisting of boric acid, methaborates and trialkylborates.

Claim 7

The product produced by reacting: (a) a phosphorodithioic acid of the formula: (RO).sub.2 PSSH where R is a C 3 to C 30 hydrocarbyl or oxyhydrocarbylene group, or mixtures thereof with an epoxide of the formula: ##STR4## where R 1 , R 2 , R 3 , and R 4 are hydrogen or a C 1 to C 30 hydrocarbyl group optionally containing sulfur, nitrogen, or oxygen atoms, to obtain the intermediate product or mixture: ##STR5## where a is an integer from 1 to 10, (b) reacting the intermediate product from (a) with a borating compound and a hydroxy bearing compound of the formula: (HO).sub.x R.sup.5 to produce the compound of the structural formula: ##STR6## where R 5 is hydrogen or a C 1 to C 30 hydrocarbyl group and optionally contains ester, amide or oxygen, nitrogen and/or sulfur groups, x is 0 to 10, y and z are integers and y+z=3, each reaction being conducted at a temperature between about -10° C. and about 250° C. for a period of between about 1 and about 48 hours in a proportion of reactants of about 1 mole each.

Claim 8

The product produced by reacting: (a) a phosphorodithioic acid of the formula: (RO).sub.2 PSSH where R is a C 3 to C 30 hydrocarbyl or oxyhydrocarbylene group, or mixtures thereof with an epoxide of the formula: ##STR4## where R 1 , R 2 , R 3 , and R 4 are hydrogen or a C 1 to C 30 hydrocarbyl group optionally containing sulfur, nitrogen, or oxygen atoms, to obtain the intermediate product or mixture: ##STR5## where a is an integer from 1 to 10, (b) reacting the intermediate product from (a) with a borating compound and a hydroxy bearing compound of the formula: (HO).sub.x R.sup.5 to produce the compound of the structural formula: ##STR6## where R 5 is hydrogen or a C 1 to C 30 hydrocarbyl group and optionally contains ester, amide or oxygen, nitrogen and/or sulfur groups, x is 0 to 10, y and z are integers and y+z=3, each reaction being conducted at a temperature between about -10° C. and about 250° C. for a period of between about 1 and about 48 hours in a proportion of reactants of about 1 mole each.

Claim 9

The reaction product of claim 5 where the reaction in (a) is carried out at a temperature between about -10° C. and about 60° C. and the reaction of (b) is carried out at a temperature of about 50° C. and about 250° C.

Claim 10

The reaction product of claim 5 wherein the borating compound is boric acid (H 3 BO 3 ).

Claim 11

The reaction product of claim 5 wherein the borating compound is selected from the group consisting of metaborates and trialkylborates.

Claim 12

The reaction product of claim 5 wherein R 1 , R 2 , R 3 , and R 4 are selected from the group consisting of hydrogen and C 1 to C 30 hydrocarbyl groups.

Claim 13

The reaction product of claim 5 wherein R 5 is selected from the group consisting of C 1 to C 30 hydrocarbyl groups.

Claim 14

The reaction product of claim 5 wherein the phosphorodithioic acid is made by reacting di-2-ethhylhexylphosphorodithioic acid and propylene oxide.

Claim 15

The reaction product of claim 5 wherein the epoxide is propylene oxide.

Claim 16

The reaction product of claim 5 wherein the hydroxy-bearing compound of (b) is glycerol monooleate.

Claim 17

The reaction product of claim 5 wherein the intermediate product of (a) is the reaction product of di-2-ethylhexylphosphorodithioic acid and propylene oxide.

Claim 18

The reaction product of claim 5 wherein the intermediate product of (a) is the reaction product of di-2-ethylhexyl-phosphorodithioic acid, and propylene oxide and the hydroxy-bearing compound of (b) is glycerol monooleate.

Claim 19

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of claim 1.

Claim 20

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of claim 2.

Claim 21

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of claim 3.

Claim 22

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of claim 4.

Claim 23

A lubricant composition comprising a lubricant and between about 0.001% and about 10% of the composition of claim 5.

Claim 24

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of claim 6.

Claim 25

A lubricant composition comprising a lubricant and between about 0.001% and about 10% weight of the composition of claim 7.

Claim 26

A lubricant composition comprising a lubricant and between about 0.001% and about 10% weight of the composition of claim 10.

Claim 27

A lubricant composition comprising as lubricant selected from the group consisting of mineral oil, synthetic oils, and greases, and between about 0.001% and about 10% by weight of the composition of claim 5.

Claim 28

A lubricant composition comprising a major proportion of a lubricant and between about 0.001% and about 1% by weight of the composition of claim 5.

Claim 29

The reaction product of claim 5 wherein the mole ratio of borating agent to the other reactants is greater than 1.

Claim 30

The lubricant composition of claim 22 where the reaction in (a) is carried out at a temperature between about -10° C. and about 60° C. and the reaction of (b) is carried out at a temperature of about 50° C. and about 250° C.

Claim 31

The lubricant composition of claim 22 wherein the borating compound is boric acid (H 3 BO 3 ).

Claim 32

The lubricant composition of claim 22 wherein the borating compound is selected from the group consisting of metaborates and trialkylborates.

Claim 33

The lubricant composition of claim 22 wherein R 1 , R 2 , R 3 , and R 4 are selected from the group consisting of hydrogen, and C 1 to C 20 hydrocarbyl groups.

Claim 34

The lubricant composition of claim 22 wherein R 5 is selected from the group consisting of C 1 to C 30 hydrocarbyl groups.

Claim 35

The lubricant composition of claim 22 wherein the phosphorodithioic acid is made by reacting di-2-ethylhexylphosphorodithioic acid and propylene oxide.

Claim 36

The lubricant composition of claim 22 wherein the epoxide is propylene oxide.

Claim 37

The lubricant composition of claim 22 wherein the hydroxy-bearing compound of (b) is glycerol monooleate.

Claim 38

The lubricant composition of claim 22 wherein the intermediate product of (a) is the reaction product of di-2-ethylhexylphosphorodithioic acid, and propylene oxide.

Claim 39

The lubricant composition of claim 22 wherein the intermediate product of (a) is the reaction product of di-2-ethylhexylphosphorodithioic acid and propylene oxide and the hydroxy-bearing compound of (b) is glycerol monooleate.

Claim 40

The lubricant composition of claim 22 wherein the lubricant is a grease.

Claim 41

The lubricant composition of claim 22 containing additional phosphorus and sulfur moities.

Claim 42

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of an additive for increasing the resistance to oxidation of the lubricant and increasing its wear reducing characteristics said additive comprising the product produced by reacting: (a) a phosphorodithioic acid of the formula: (RO).sub.2 PSSH where R is a C 3 to C 30 hydrocarbyl or oxyhydrocarbylene, or mixtures thereof with an epoxide of the formula: ##STR7## where R 1 , R 2 , R 3 , and R 4 are hydrogen or C 1 to C 30 hydrocarbyl groups, to obtain the intermediate product: ##STR8## where a is an integer from 1 to 10, (b) reacting the intermediate product from (a) with a borating compound and a hydroxy-bearing compound of the formula: (HO).sub.x R.sup.5 where R 5 is hydrogen or C 1 to C 30 hydrocarbyl groupand optionally contains ester, amide, oxygen, nitrogen and/or sulfur groups, and x is 0 to 10 to produce the compound of the structural formula: ##STR9## where y and z are integers and z+z=3 each reaction being conducted at a temperature between about -10° C. and about 250° C. for a period of between about 1 and about 48 hours in a ratio of reactants of about 1 mole of each.

Claim 43

A lubricant composition comprising a lubricant and between about 0.001% and about 10% by weight of the composition of an additive for increasing the resistance to oxidation of the lubricant and increasing its wear reducing characteristics said additive comprising the product produced by reacting: (a) a phosphorodithioic acid of the formula: (RO).sub.2 PSSH where R is a C 3 to C 30 hydrocarbyl or oxyhydrocarbylene, or mixtures thereof with an epoxide of the formula: ##STR7## where R 1 , R 2 , R 3 , and R 4 are hydrogen or C 1 to C 30 hydrocarbyl groups, to obtain the intermediate product: ##STR8## where a is an integer from 1 to 10, (b) reacting the intermediate product from (a) with a borating compound and a hydroxy-bearing compound of the formula: (HO).sub.x R.sup.5 where R 5 is hydrogen or C 1 to C 30 hydrocarbyl groupand optionally contains ester, amide, oxygen, nitrogen and/or sulfur groups, and x is 0 to 10 to produce the compound of the structural formula: ##STR9## where y and z are integers and z+z=3 each reaction being conducted at a temperature between about -10° C. and about 250° C. for a period of between about 1 and about 48 hours in a ratio of reactants of about 1 mole of each.