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US4783278A Expired / Lapsed US ⏱️ 0.0 years remaining

Concentrated liquid compositions containing a peroxygen compound

Assignee: Solvay Interox Ltd
•
Filing: 1987-02-04
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Granted: 1988-11-08
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Expires: 2007-02-04
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Abstract

Abstract In general, inorganic or organic peroxyacids are unstable in the presence of a nonionic surfactant, so that it was not feasible to contemplate storing liquid compositions containing both components. It has now been discovered that storable compositions containing both components can be obtained by the use of particulate potassium-4-sulphoperoxybenzoic acid dispersed in the liquid nonionic surfactant containing phase. Additionally, the compositions can also include a dispersed particulate water-insoluble builder such as zeolite or water-soluble builder such as STPP. It is preferable to include a small amount of a chelating peroxidic stabilizer such as dipicolinic acid or 1,1,1-hydroxyethylidene diphosphonic acid.

Inventors

  • 👤 William R. Sanderson
  • 👤 John D. Wharne

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 20:22
CPC Classifications
C; C11; C11D; C11D17/00; C11D17/0004; A; A01; A01N; A01N41/00; A01N41/02; A01N41/04; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D3/36; C11D3/361; C11D3/39; C11D3/3947; C11D3/43

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 48 words
Storable concentrated liquid washing, bleaching or disinfectant compositions in which particulate potassium-4-sulphoperoxybenzoic acid (KSPB) is dispersed in an organic liquid carrier phase which comprises a nonionic surfactant, said organic liquid carrier phase comprising at least 50% by weight of the composition based on the weight of the composition.
Claim 2
Dependent Claim 48 words
Storable concentrated liquid washing, bleaching or disinfectant compositions in which particulate potassium-4-sulphoperoxybenzoic acid (KSPB) is dispersed in an organic liquid carrier phase which comprises a nonionic surfactant, said organic liquid carrier phase comprising at least 50% by weight of the composition based on the weight of the composition.
Claim 3
Dependent Claim 36 words
A composition according to claim 1 in which the nonionic surfactant is a condensation product of higher aliphatic alcohols or alkyl phenols or higher aliphatic acids with at least one of polyethylene oxide and polypropylene oxide.
Claim 4
Dependent Claim 25 words
A composition according to claim 1 in which the nonionic surfactant contains a mean of from 3 to 21 ethylene oxide and/or propylene oxide units.
Claim 5
Dependent Claim 32 words
A composition according to claim 2 in which the alkyl residue of the alcohol or acid moiety in the surfactant has an average carbon chain length of 9 to 15 carbon atoms.
Claim 6
Dependent Claim 42 words
A composition according to claim 1 in which the liquid carrier phase contains a solvent selected from C 2 to C 6 aliphatic alcohols, low molecular weight ethylene glycol ethers or esters or propylene glycol ethers or esters and a glycerol esters.
Claim 7
Dependent Claim 29 words
A composition according to claim 5 in which the solvent is ethylene glycol mono- or di- acetate, t-butanol, diethylene glycol mono or dimethyl ether or ethylene glycol monobutyl ether.
Claim 8
Dependent Claim 22 words
A composition according to either of claims 5 or 6 in which the weight ratio of solvent:surfactant is not greater than 4:1.
Claim 9
Dependent Claim 18 words
A composition according to claim 1 in which the KSPB particles have a diameter of below 0.5 mm.
Claim 10
Dependent Claim 17 words
A composition according to claim 1 or 8 which contains from 5 to 20% by weight KSPB.
Claim 11
Dependent Claim 17 words
A composition according to claim 1 or 5 which contains an effective amount of a complexing stabiliser.
Claim 12
Dependent Claim 24 words
A composition according to claim 10 in which the stabiliser is selected from the group consisting of aromatic hydroxy carboxylic acids and polyphosphonic acids.
Claim 13
Dependent Claim 46 words
A composition according to claim 11 in which the stabiliser is selected from the group consisting of dipicolinic acid, quinolinic acid, and a compound having the formula NX 3 in which X represents a methylene phosphonic acid or an ethylene amino bis methylene phosphonic acid group.
Claim 14
Dependent Claim 19 words
A composition according to claim 1 or 5 which contains up to 15% by weight of an anionic surfactant.
Claim 15
Dependent Claim 18 words
A composition according to claim 1 which contains additionally a low alkaline builder dispersed in the liquid phase.
Claim 16
Dependent Claim 42 words
A composition according to claim 14 in which the builder is selected from the group consisting of an alkali metal tripolyphosphate, an alkali metal hydrogen phosphate, a zeolite, a calcined zeolote, an amine carboxylate complexing builder, and an hydroxy carboxylate complexing builder.
Claim 17
Dependent Claim 22 words
A composition according to claim 14 or 15 characterised in that the amount of builder is from 10 to 35% by weight.
Claim 18
Dependent Claim 149 words
A composition according to claim 1 which comprises from 5 to 20% by weight KSPB and 10 to 35% by weight of a builder selected from the group consisting of alkali metal tripolyphosphates, alkali metal hydrogen phosphates and a zeolite dispersed in a liquid phase which comprises a nonionic surfactant which is selected from the group consisting of liquid condensation products of higher aliphatic alcohols or alkyl phenols or higher aliphatic acids with at least one of polyethylene oxide and polypropylene oxide and which phase includes 0 to 15% by weight of an anionic surfactant and 0 to 4 parts by weight of a solvent per part by weight of surfactant, said solvent being selected from C 2 to C 6 aliphatic alcohols, low molecular weight ethylene glycol ethers or esters or propylene glycol ethers or esters and glycerol esters, % by weight being based on the composition weight.
Claim 19
Dependent Claim 23 words
A composition according to claim 17 in which the solid suspended particles have a mean particle diameter of from 0.02 to 0.1 mm.

References Cited (Backward Citations)

US4100095A Cited
EP0124968A1 Cited
US4536313A Cited
US4704404A Cited
US4615820A Cited
US4537708A Cited
US4483781A Cited
US4606838A Cited
US4738794A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-11-08 1992-05-09 1992-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-11-08 1996-05-09 1996-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-11-08 2000-05-09 2000-11-08 $7700.00 Window Closed / Lapsed

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