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US4783221A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions and process for preserving wood

Assignee: Borchers Americas Inc
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Filing: 1986-12-12
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Granted: 1988-11-08
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Expires: 2006-12-12
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Abstract

Abstract Novel compositions of matter and processes for utilizing such compositions in preserving wood are described. More particularly, the novel compositions comprise (A) at least one metal salt of an organic carboxylic acid containing at least about 6 carbon atoms wherein the metal is selected from the group consisting of transition metals, zinc, mercury, antimony and lead, (B) at least one isothiazolone compound represented by the structural formula ##STR1## wherein R 1 is an alkyl, alkenyl or alkynyl group of 1 to about 18 carbon atoms; a cycloalkyl group having a 3 to 6 carbon atom ring and up to about 12 carbon atoms; an aralkyl or aryl group of up to about 10 carbon atoms; R 2 is hydrogen, halogen or a lower alkyl group; and R 3 is hydrogen, halogen or a lower alkyl group, and p0 (C) at least one solvent/diluent. The solvent/diluent may be water or one or more hydrocarbon solvents. The novel compositions of the invention are useful in preserving wood, and when so used, the compositions also may include flame retardants, water repellents, odorants, insecticides, etc.

Inventors

  • 👤 Scott L. Grove

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 22:56
CPC Classifications
A; A01; A01N; A01N43/00; A01N43/72; A01N43/80; B; B27; B27K; B27K3/00; B27K3/16; B27K3/22; B27K3/34; B27K3/343; B27K3/50; B27K3/52; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31971; Y10T428/31989

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 125 words
A novel composition comprising (A) at least one metal salt of an organic carboxylic acid containing at least about 6 carbon atoms wherein the metal is selected from the group consisting of transition metals, zinc, mercury, antimony and lead, (B) at least one isothiazolone compound represented by the structural formula ##STR4## wherein R 1 is an alkyl, alkenyl or alkynyl group of 1 to about 18 carbon atoms; a cycloalkyl group having a 3 to 6 carbon atom ring and up to about 12 carbon atoms; an aralkyl or aryl group of up to about 10 carbon atoms; R 2 is hydrogen, halogen or a lower alkyl group; and R 3 is hydrogen, halogen or a lower alkyl group, and (C) at least one solvent/diluent.
Claim 2
Dependent Claim 125 words
A novel composition comprising (A) at least one metal salt of an organic carboxylic acid containing at least about 6 carbon atoms wherein the metal is selected from the group consisting of transition metals, zinc, mercury, antimony and lead, (B) at least one isothiazolone compound represented by the structural formula ##STR4## wherein R 1 is an alkyl, alkenyl or alkynyl group of 1 to about 18 carbon atoms; a cycloalkyl group having a 3 to 6 carbon atom ring and up to about 12 carbon atoms; an aralkyl or aryl group of up to about 10 carbon atoms; R 2 is hydrogen, halogen or a lower alkyl group; and R 3 is hydrogen, halogen or a lower alkyl group, and (C) at least one solvent/diluent.
Claim 3
Dependent Claim 21 words
The composition of claim 1 wherein the metal is zinc, copper, chromium, iron zirconium, mercury, antimony, lead, or a mixture thereof.
Claim 4
Dependent Claim 28 words
The composition of claim 1 wherein the organic carboxylic acid is at least one aliphatic or alicyclic monocarboxylic acid containing from about 6 to about 30 carbon atoms.
Claim 5
Dependent Claim 30 words
The composition of claim 1 wherein R 1 is an alkyl group containing from 1 to about 18 carbon atoms, and R 2 and R 3 are hydrogen or halogen.
Claim 6
Dependent Claim 10 words
The composition of claim 4 wherein the halogen is chlorine.
Claim 7
Dependent Claim 24 words
The composition of claim 1 wherein the weight ratio of metal in (A) to isothiazolone compound (B) is from about 0.1:1 to about 50:1.
Claim 8
Dependent Claim 14 words
The composition of claim 1 wherein the solvent/diluent is water or a hydrocarbon solvent.
Claim 9
Dependent Claim 12 words
The composition of claim 1 also containing (D) at least one surfactant.
Claim 10
Dependent Claim 18 words
The composition of claim 8 wherein the surfactant is an anionic or nonionic surfactant or a mixture thereof.
Claim 11
Dependent Claim 20 words
The composition of claim 1 also containing effective amounts of at least one odorant, insecticide, flame-retardant, or a mixture thereof.
Claim 12
Dependent Claim 138 words
A novel composition useful for preserving wood comprising (A) at least one metal salt of an aliphatic or alicyclic monocarboxylic acid containing from about 6 to about 30 carbons atoms wherein the metal is selected from the group consisting of transition metals, zinc, mercury, antimony and lead, (B) at least one isothiazolone compound represented by the structural formula ##STR5## wherein R 1 is an alkyl, alkenyl or alkynyl group of 1 to about 18 carbon atoms; a cycloalkyl group having a 3 to 6 carbon atom ring and up to about 12 carbons atoms; an aralkyl or aryl group of up to about 10 carbon atoms; R 2 is hydrogen, halogen or a lower alkyl group; and R 3 is hydrogen, or a lower alkyl group; (C) water and/or a hydrocarbon solvent, and (D) at least one surfactant.
Claim 13
Dependent Claim 138 words
A novel composition useful for preserving wood comprising (A) at least one metal salt of an aliphatic or alicyclic monocarboxylic acid containing from about 6 to about 30 carbons atoms wherein the metal is selected from the group consisting of transition metals, zinc, mercury, antimony and lead, (B) at least one isothiazolone compound represented by the structural formula ##STR5## wherein R 1 is an alkyl, alkenyl or alkynyl group of 1 to about 18 carbon atoms; a cycloalkyl group having a 3 to 6 carbon atom ring and up to about 12 carbons atoms; an aralkyl or aryl group of up to about 10 carbon atoms; R 2 is hydrogen, halogen or a lower alkyl group; and R 3 is hydrogen, or a lower alkyl group; (C) water and/or a hydrocarbon solvent, and (D) at least one surfactant.
Claim 14
Dependent Claim 26 words
The composition of claim 11 wherein the metal of the metal salt is at least one of zinc, copper, chromium, zirconium, iron, antimony, lead or mercury.
Claim 15
Dependent Claim 16 words
The composition of claim 12 wherein the metal is zinc or copper or a mixture thereof.
Claim 16
Dependent Claim 33 words
The composition of claim 11 wherein R 2 in Formula I is an alkyl group containing from about 4 to about 18 carbon atoms, and the halogen, if present, is chlorine or bromine.
Claim 17
Dependent Claim 24 words
The composition of claim 11 wherein the weight ratio of metal salt (A) to isothiazolone compound (B) is from about 0.1:1 to about 50:1.
Claim 18
Dependent Claim 21 words
The composition of claim 11 wherein the metal content of the composition is from about 0.001 to about 10% by weight.
Claim 19
Dependent Claim 31 words
The composition of claim 11 wherein the isothiazolone compound is present in an amount of from about 0.01 to about 5% by weight based on the total weight of the composition.
Claim 20
Dependent Claim 13 words
The composition of claim 11 wherein the metal salt (A) is a fungicide.
Claim 21
Dependent Claim 19 words
The composition of claim 11 also containing effective amounts of at least one odorant, insecticide, flame-retardant, or mixtures thereof.
Claim 22
Dependent Claim 117 words
A composition useful for preserving wood comprising (A) from about 0.001 to about 10% by weight of a metal salt of an organic carboxylic acid wherein the metal is zinc, copper, chromium, iron, antimony, zirconium, lead or mercury, (B) from about 0.01 to about 5% of at least one isothiazolone compound of the formula ##STR6## wherein R 1 is an alkyl group of from 1 to about 18 carbon atoms, and R 2 and R 3 are each independently H or a halogen, (C) from 60 to about 99% by weight of water, (D) from about 0.1 to about 20% of at least one surfactant, and (E) less than about 30% by weight of a hydrocarbon solvent.
Claim 23
Dependent Claim 117 words
A composition useful for preserving wood comprising (A) from about 0.001 to about 10% by weight of a metal salt of an organic carboxylic acid wherein the metal is zinc, copper, chromium, iron, antimony, zirconium, lead or mercury, (B) from about 0.01 to about 5% of at least one isothiazolone compound of the formula ##STR6## wherein R 1 is an alkyl group of from 1 to about 18 carbon atoms, and R 2 and R 3 are each independently H or a halogen, (C) from 60 to about 99% by weight of water, (D) from about 0.1 to about 20% of at least one surfactant, and (E) less than about 30% by weight of a hydrocarbon solvent.
Claim 24
Dependent Claim 16 words
A method of preserving wood which comprises contacting the wood with the composition of claim 11.
Claim 25
Dependent Claim 16 words
A method of preserving wood which comprises contacting the wood with the composition of claim 20.
Claim 26
Dependent Claim 10 words
Wood treated in accordance with the method of claim 21.
Claim 27
Dependent Claim 10 words
Wood treated in accordance with the method of claim 22.

References Cited (Backward Citations)

US2951789A Cited
US3761488A Cited
US4001400A Cited
US4150026A Cited
US4396413A Cited
US4193993A Cited
GB2049430A Cited
US4507152A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-11-08 1992-05-09 1992-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-11-08 1996-05-09 1996-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-11-08 2000-05-09 2000-11-08 $7700.00 Window Closed / Lapsed

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