Patent US4777632A successfully refreshed from Google Patents.
US4777632A
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Data storage disk
Assignee: Roehm GmbH Darmstadt
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Filing: 1987-07-30
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Granted: 1988-10-11
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Expires: 2007-07-30
Abstract
Abstract Data storage disks containing optically readable information made from a copolymer having low water absorption and good optical and mechanical properties, said copolymer being at least ternary and comprising (A) methyl methacrylate, and further comonomers selected from at least two of the groups (B) ##STR1## where R' is hydrogen or methyl and R" is hydrogen or alkyl, and (C) ##STR2## where R'" is aliphatic or alicyclic hydrocarbon, and (D) styrene and/or alpha-methyl styrene.
Inventors
- 👤 Franz Wenzel
- 👤 Peter J. Arndt
- 👤 Werner Siol
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 06:20
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/26; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08F220/14
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) at least 10 percent of a monomer of the formula ##STR5## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 10 percent of a monomer of the formula ##STR6## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) 0 to 40 percent or styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alpha-olefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methylacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 2
Dependent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) at least 10 percent of a monomer of the formula ##STR5## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 10 percent of a monomer of the formula ##STR6## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) 0 to 40 percent or styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alpha-olefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methylacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 3
Dependent Claim
26 words
A storage disk as in claim 1 wherein monomer (B) is selected from the group consisting of 2-phenoxyethyl methacrylate, benzyl methacrylate, 2-phenylethyl methacrylate, and 3-phenylpropyl methacrylate.
Claim 4
Dependent Claim
13 words
A storage disk as in claim 1 wherein monomer (C) is cyclohexyl methacrylate.
Claim 5
Dependent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) 0 to 50 percent of a monomer of the formula ##STR7## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 10 percent of a monomer of the formula ##STR8## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) at least 5 percent of styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alpha-olefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 6
Dependent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) 0 to 50 percent of a monomer of the formula ##STR7## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 10 percent of a monomer of the formula ##STR8## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) at least 5 percent of styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alpha-olefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 7
Dependent Claim
26 words
A storage disk as in claim 4 wherein monomer (B) is selected from the group consisting of 2-phenoxyethyl methacrylate, benzyl methacrylate, 2-phenylethyl methacrylate, and 3-phenylpropyl methacrylate.
Claim 8
Dependent Claim
13 words
A storage disk as in claim 4 wherein monomer (C) is cyclohexyl methacrylate.
Claim 9
Dependent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) at least 5 percent of a monomer of the formula ##STR9## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 5 percent of a monomer of the formula ##STR10## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) at least 5 percent of styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alphaolefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 10
Dependent Claim
255 words
A storage disk for information that is to be read optically comprising a transparent data storage medium which is an at least ternary acrylic copolymer exhibiting low water absorption and consisting essentially of (A) 20 to 85 percent of methyl methacrylate; (B) at least 5 percent of a monomer of the formula ##STR9## wherein R' is hydrogen or methyl, R" is hydrogen or alkyl having from 1 to 7 carbon atoms, Ar is phenyl or phenyl substituted with alkyl having from 1 to 7 carbon atoms, n is an integer from 1 to 6, and m is 0 or 1, but n and m are not both 1; (C) at least 5 percent of a monomer of the formula ##STR10## wherein R'" is linear or branched hydrocarbon having from 2 to 20 carbon atoms, or alicyclic hydrocarbon having up to 12 carbon atoms and at least 5 ring carbon atoms; (D) at least 5 percent of styrene or alphamethyl styrene; (E) 0 to 9.9 percent of 4-methylstyrene; (F) 0 to 10 percent of a copolymerizable monomer, different from (A)-(E) whose solubility in water is less than 50 g per liter at 25° C. and which is an alphaolefin, a halogenated olefin, an ester of an unsaturated dicarboxylic acid, or a vinyl ester of a C 3 -C 8 carboxylic acid; and (G) 0 to 10 percent of acrylonitrile, methacrylonitrile, or a crosslinking monomer having in its molecule more than one group capable of free radical polymerization, all said percentages being by weight of said copolymer.
Claim 11
Dependent Claim
26 words
A storage disk as in claim 7 wherein monomer (B) is selected from the group consisting of 2-phenoxyethyl methacrylate, benzyl methacrylate, 2-phenylethyl methacrylate, and 3-phenylpropyl methacrylate.
Claim 12
Dependent Claim
13 words
A storage disk as in claim 7 wherein monomer (C) is cyclohexyl methacrylate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-10-11 | 1992-04-11 | 1992-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-10-11 | 1996-04-11 | 1996-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-10-11 | 2000-04-11 | 2000-10-11 | $7700.00 | Window Closed / Lapsed |