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Silver halide color photographic materials

Assignee: Fujifilm Holdings Corp
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Filing: 1986-11-28
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Granted: 1988-09-27
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Expires: 2006-11-28
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Abstract

Abstract Silver halide color photographic materials are described, which comprise at least one silver halide emulsion layer coated on a support and which are characterized by the incorporation of a pyrazoloazole type coupler of the following general formula (I) into the silver halide emulsion layer(s) or the adjacent layer(s) thereto: ##STR1## wherein Za and Zb each may represent ##STR2## R 1 and R 2 each may represent a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being removed upon a coupling reaction with an oxidized form of an aromatic primary amine type developing agent; when Za═Zb is a carbon-carbon double bond, this may be a part of the aromatic ring in the formula: with the proviso that at least one of R 1 and R 2 is a group represented by general formulae (II) or (III): ##STR3## wherein R 3 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R 4 represents a hydrogen atom or a substituent; R 5 represents a halogen atom, a substituted or unsubstituted alkoxy, aryloxy, amino, alkylthio or arylthio group; Ar represents an aryl group; Y represents an alkylene group or an arylene group; l' is an integer of 0 or 1; n is an integer of 0 or 1; and m is an integer of 1 to 3; and that when R 1 represents an alkyl group or Y represents an alkylene group, the alkyl or alkylene group is a group of which the carbon atom directly bonded to the pyrazoloazole nucleus is a primary carbon. The pyrazoloazole type magenta couplers of general formula (I) may form azomethine dyes with improved color reproducibility and high light fastness. The present silver halide color photographic materials containing the coupler of general formula (I) have excellent colorability and excellent light fastness.

Inventors

  • 👤 Toshio Kawagishi
  • 👤 Takayoshi Kamio
  • 👤 Keizo Kimura
  • 👤 Tadahisa Sato
  • 👤 Nobuo Furutachi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 06:29
CPC Classifications
C; C07; C07D; C07D487/00; C07D487/02; C07D487/04; G; G03; G03C; G03C7/00; G03C7/30; G03C7/32; G03C7/36; G03C7/38; G03C7/381; G03C7/382; G03C7/3825

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 268 words
A silver halide color photographic material comprising a support having at least one silver halide emulsion layer coated thereon, wherein a pyrazoloazole type coupler of general formula (I) is present in said at least one silver halide emulsion layer or an adjacent layer thereto: ##STR20## wherein Za and Zb each may represent ##STR21## R 1 and R 2 each may represent a hydrogen atom or a substituent; X represents a hydrogen atom; a group bonded via a nitrogen atom or a group bonded via a sulfur atom, each of which is removed upon a coupling reaction with an oxidized form of an aromatic primary amine type developing agent; when Za═Zb is a carbon-carbon double bond, this may be a part of the aromatic ring in the formula; with the proviso that at least one of R 1 and R 2 is a group represented by general formulae (II) or (III): ##STR22## wherein R 3 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R 4 represents a hydrogen atom or a substituent; R 5 represents a halogen atom, a substituted or unsubstituted alkoxy, aryloxy, amino, alkylthio or arylthio group; Ar represents an aryl group; Y represents an alkylene group or an arylene group; l' is an integer of 0 or 1; n is an integer of 0 or 1; and m is an integer of 1 to 3; and that when R 1 represents an alkyl group or Y represents an alkylene group, the alkyl or alkylene group is a group of which the carbon atom directly bonded to the pyrazoloazole nucleus is a primary carbon.
Claim 2
Dependent Claim 268 words
A silver halide color photographic material comprising a support having at least one silver halide emulsion layer coated thereon, wherein a pyrazoloazole type coupler of general formula (I) is present in said at least one silver halide emulsion layer or an adjacent layer thereto: ##STR20## wherein Za and Zb each may represent ##STR21## R 1 and R 2 each may represent a hydrogen atom or a substituent; X represents a hydrogen atom; a group bonded via a nitrogen atom or a group bonded via a sulfur atom, each of which is removed upon a coupling reaction with an oxidized form of an aromatic primary amine type developing agent; when Za═Zb is a carbon-carbon double bond, this may be a part of the aromatic ring in the formula; with the proviso that at least one of R 1 and R 2 is a group represented by general formulae (II) or (III): ##STR22## wherein R 3 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R 4 represents a hydrogen atom or a substituent; R 5 represents a halogen atom, a substituted or unsubstituted alkoxy, aryloxy, amino, alkylthio or arylthio group; Ar represents an aryl group; Y represents an alkylene group or an arylene group; l' is an integer of 0 or 1; n is an integer of 0 or 1; and m is an integer of 1 to 3; and that when R 1 represents an alkyl group or Y represents an alkylene group, the alkyl or alkylene group is a group of which the carbon atom directly bonded to the pyrazoloazole nucleus is a primary carbon.
Claim 3
Dependent Claim 68 words
The silver halide color photographic material as claimed in claim 1, wherein the pyrazoloazole type coupler is represented by general formulae (IV), (V), (VI), (VII) or (VIII): ##STR23## wherein R 1 and X have the same meanings as defined in claim 1; R 21 and R 22 have the same meanings as R 2 as defined in claim 1; and l is an integer of 1 to 4.
Claim 4
Dependent Claim 143 words
The silver halide color photographic material as claimed in claim 2, wherein R 1 , R 21 and R 22 each may represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxyl group, a substituted or unsubstituted alkoxy group, an aryloxy group, a heterocyclic oxy group, an acyloxy group, a carbamoyloxy group, a silyloxy group, a sulfonyloxy group, an acylamino group, an anilino group, an amino group, a ureido group, an imido group, a sulfamoylamino group, a substituted or unsubstituted alkylthio group, an arylthio group, a heterocyclic thio group, a substituted or unsubstituted alkoxycarbonylamino group, an aryloxycarbonylamino group, a sulfonamido group, a carboxyl group, a carbamoyl group, an acyl group, a sulfamoyl group, a sulfonyl group, a sulfinyl group, a substituted or unsubstituted alkoxycarbonyl group or an aryloxycarbonyl group.
Claim 5
Dependent Claim 21 words
The silver halide color photographic material as claimed in claim 1, wherein X represents said group bonded via a sulfur atom.
Claim 6
Dependent Claim 24 words
The silver halide color photographic material as claimed in claim 1, wherein R 3 in general formulae (II) or (III) is a hydrogen atom.
Claim 7
Dependent Claim 58 words
The silver halide color photographic material as claimed in claim 2, wherein the pyrazoloazole type coupler is represented by general formulae (IV), (V) or (VI): ##STR24## wherein R 1 and X have the same meanings as defined in claim 1, and R 21 and R 22 have the same meanings as R 2 as defined in claim 1.
Claim 8
Dependent Claim 52 words
The silver halide color photographic material as claimed in claim 6, wherein the pyrazoloazole type coupler is represented by general formula (VI): ##STR25## wherein R 1 and X have the same meanings as defined in claim 1, and R 21 has the same meaning as R 2 as defined in claim 1.
Claim 9
Dependent Claim 17 words
The silver halide color photographic material as claimed in claim 1, wherein X represents said hydrogen atom.
Claim 10
Dependent Claim 21 words
The silver halide color photographic material as claimed in claim 1, wherein X represents said group bonded via a nitrogen atom.

References Cited (Backward Citations)

US4548899A Cited
US4659652A Cited
US4639415A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-27 1992-03-28 1992-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-27 1996-03-28 1996-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-27 2000-03-28 2000-09-27 $7700.00 Window Closed / Lapsed

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