Patent US4774166A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4774166A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the formation of color images using a color developer not substantially containing benzyl alcohol

Assignee: Fujifilm Holdings Corp
•
Filing: 1987-01-28
•
Granted: 1988-09-27
•
Expires: 2007-01-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method for the formation of a color image is described, wherein a silver halide color photographic material comprising a photographic layer provided on a reflective support is imagewise exposed and then subjected to development for a period of time within 2 minutes and 30 seconds with a color developer which contains an aromatic primary amine developing agent but does not substantially contain benzyl alcohol, wherein said photographic layer contains at lesat one specific non-coloring coloration accelerator selected from the group consisting of compounds represented by formulae (I) through (VII) defined in the specification.

Inventors

  • 👤 Minoru Sasaki
  • 👤 Tadahisa Sato
  • 👤 Nobuo Furutachi
  • 👤 Takeshi Hirose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:18
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/392; G03C7/39208

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 373 words
A method for the formation of a color image wherein a silver halide color photographic material comprising a photographic layer provided on a reflective support is imagewise exposed and then subjected to development for a period of time within 2 minutes and 30 seconds with a color developer which contains am aromatic primary amine developing agent but containing benzyl alcohol in an amount of 0.5 m/l or less, wherein said photographic layer contains at least one non-coloring compound selected from the group consisting of compounds represented by formulae (I), (III) and (IV). ##STR17## wherein A represents a divalent electron attractive group; R 1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylamino group, a substituted or unsubstituted anilino group or a substituted or unsubstituted heterocyclic group; l represents an integer of 1 or 2; R 2 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a hydroxyl group or a halogen atom; m represents an integer of 1 to 4; Q represents a benzene ring or hetero ring which may be condensed with the phenol ring in the formula; Y 1 represents a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted heterocyclic group, or ##STR18## wherein R 10 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aryloxy group; R 4 ' represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group or a substituted or unsubstituted aralkylene group; R 4 represents a substituted or unsubstituted alkyl group or substituted or unsubstituted aryl group; provided that Y 1 and R 4 are not both alkyl groups; n represents an integer of 1 to 5; R 5 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl or arylsulfonyl group or a substituted or unsubstituted acyl group; R 6 represents the same substituent as R 4 ; or R 5 and R 6 together represent a 5- or 7-membered ring.
Claim 2
Independent Claim 373 words
A method for the formation of a color image wherein a silver halide color photographic material comprising a photographic layer provided on a reflective support is imagewise exposed and then subjected to development for a period of time within 2 minutes and 30 seconds with a color developer which contains am aromatic primary amine developing agent but containing benzyl alcohol in an amount of 0.5 m/l or less, wherein said photographic layer contains at least one non-coloring compound selected from the group consisting of compounds represented by formulae (I), (III) and (IV). ##STR17## wherein A represents a divalent electron attractive group; R 1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylamino group, a substituted or unsubstituted anilino group or a substituted or unsubstituted heterocyclic group; l represents an integer of 1 or 2; R 2 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a hydroxyl group or a halogen atom; m represents an integer of 1 to 4; Q represents a benzene ring or hetero ring which may be condensed with the phenol ring in the formula; Y 1 represents a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted heterocyclic group, or ##STR18## wherein R 10 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxy group or a substituted or unsubstituted aryloxy group; R 4 ' represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group or a substituted or unsubstituted aralkylene group; R 4 represents a substituted or unsubstituted alkyl group or substituted or unsubstituted aryl group; provided that Y 1 and R 4 are not both alkyl groups; n represents an integer of 1 to 5; R 5 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl or arylsulfonyl group or a substituted or unsubstituted acyl group; R 6 represents the same substituent as R 4 ; or R 5 and R 6 together represent a 5- or 7-membered ring.
Claim 3
Dependent Claim 25 words
A method for the formation of a color image as in claim 1, wherein said photographic layer contains a non-coloring compound represented by formula (I).
Claim 4
Dependent Claim 24 words
A method for the formation of a color image as in claim 1, wherein said non-coloring compound is co-dispersed together with an oil-soluble coupler.
Claim 5
Dependent Claim 24 words
A method for the formation of a color image as in claim 1, wherein said non-coloring compound is co-dispersed together with an oil-soluble coupler.
Claim 6
Dependent Claim 24 words
A method for the formation of a color image as in claim 2, wherein said non-coloring compound is co-dispersed together with an oil-soluble coupler.
Claim 7
Dependent Claim 37 words
A method for the formation of a color image as in claim 3, wherein said non-coloring compound is used in an amount of from 20 to 300 mol% with respect to the amount of the oil-soluble coupler.
Claim 8
Dependent Claim 37 words
A method for the formation of a color image as in claim 4, wherein said non-coloring compound is used in an amount of from 20 to 300 mol% with respect to the amount of the oil-soluble coupler.
Claim 9
Dependent Claim 37 words
A method for the formation of a color image as in claim 6, wherein said non-coloring compound is used in an amount of from 20 to 300 mol% with respect to the amount of the oil-soluble coupler.
Claim 10
Dependent Claim 37 words
A method for the formation of a color image as in claim 3, wherein said non-coloring compound is used in an amount of from 40 to 150 mol% with respect to the amount of the oil-soluble coupler.
Claim 11
Dependent Claim 37 words
A method for the formation of a color image as in claim 4, wherein said non-coloring compound is used in an amount of from 40 to 150 mol% with respect to the amount of the oil-soluble coupler.
Claim 12
Dependent Claim 37 words
A method for the formation of a color image as in claim 5, wherein said non-coloring compound is used in an amount of from 40 to 150 mol% with respect to the amount of the oil-soluble coupler.
Claim 13
Dependent Claim 383 words
A method for the formation of a color image as in claim 3, wherein the oil-soluble coupler is at least one coupler selected from the group consisting of compounds represented by formulae (A) through (E) ##STR19## wherein R 12 , R 15 , and R 16 each represents an aliphatic group, an aromatic group, a heterocyclic group, an aromatic amino group, or a heterocyclic amino group; R 13 represents an aliphatic group; R 14 and R 17 each represents a hydrogen atom, a halogen atom, an aliphatic group, an aliphaticoxy group, or an acylamino group; R 18 and R 20 each represents a substituted or unsubstituted phenyl group; R 19 represents a hydrogen atom, an aliphatic or aromatic acyl group, or an aliphatic or aromatic sulfonyl group; R 21 represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an aliphatic oxy group, an acylamino group, an aromatic amino group, an ureido group, an aliphatic thio group, an aromatic thio group, an alkoxycarbonylamino group, a sulfonamido group, an carbamoyl group, a sulfamoyl group, an aliphatic sulfonyl group, an aromatic sulfonyl group, an aliphatic or aromatic acyl group, or an alkoxycarbonyl group; X represents a substituted or unsubstituted N-phenylcarbamoyl group; Za and Zb each represents a methine group, a substituted methine group, or ═N--; Y 2 , Y 3 , and Y 5 each represents a halogen atom or a group capable of being removed in the coupling reactin with an oxidation product of a developing agent; Y 4 represents a hydrogen atom or a coupling off group; Y 6 represents a coupling off group; or R 13 and R 14 , and R 16 and R 17 in the formulae (A) and (B), respectively, form a 5-, 6-, or 7-membered ring; or R 13 and R 14 , and R 16 and R 17 , in the formulae (A) and (B), respectively, form a 5-, 6-, or 7-membered ring; or R 12 , R 13 , R 14 , or Y 2 ; R 15 , R 16 , R 17 , or Y 3 ; R 18 , R 19 , R 20 , or Y 4 ; R 21 , Za, and Zb, or Y 5 ; and X or Y 6 form a dimer or higher polymer.
Claim 14
Dependent Claim 37 words
A method for the formation of a color image as in claim 12, wherein said non-coloring compound is used in an amount of from 20 to 300 mol% with respect to the amount of the oil-soluble coupler.
Claim 15
Dependent Claim 39 words
A method for the formation of a color image as in claim 1, wherein the silver halide color photographic material is subjected to development for a period of time of from 1 minute to 2 minutes and 10 seconds.
Claim 16
Dependent Claim 39 words
A method for the formation of a color image as in claim 3, wherein the silver halide color photographic material is subjected to development for a period of time of from 1 minute to 2 minutes and 10 seconds.
Claim 17
Dependent Claim 39 words
A method for the formation of a color image as in claim 5, wherein the silver halide color photographic material is subjected to development for a period of time of from 1 minute to 2 minutes and 10 seconds.
Claim 18
Dependent Claim 34 words
A method for the formation of a color image as in claim 1, wherein the silver halide color photographic material is subjected to said development at a temperature of from 30° to 50° C.
Claim 19
Dependent Claim 34 words
A method for the formation of a color image as in claim 3, wherein said silver halide color photographic material is subjected to said development at a temperature of from 35° to 45° C.

References Cited (Backward Citations)

US2322027A Cited
US3996054A Cited
US4464464A Cited
JPS60158446A Cited
US4622287A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-27 1992-03-28 1992-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-27 1996-03-28 1996-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-27 2000-03-28 2000-09-27 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag