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US4773741A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochromic display device having auxiliary electrode

Assignee: Central Glass Co Ltd
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Filing: 1987-04-09
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Granted: 1988-09-27
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Expires: 2007-04-09
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Abstract

Abstract The invention relates to an electrochromic (EC) display device having a transparent electrode layer coated with a first EC material which takes on color in its electrochemically oxidized state, such as Prussian blue, and an opposite transparent electrode layer coated with a second EC material which takes on color in its reduced state, such as WO 3 . For use in initial bleaching or coloration of one of the two EC layers, an auxiliary electrode is disposed in a marginal region of the space between the two opposite electrodes, and an electrolyte occupies the remaining space. An insulating covering permeable to ions intervenes between the electrolyte and the body of the auxiliary electrode, and an insulating layer substantially impermeable to ions intervenes between the auxiliary electrode body and each transparent electrode layer or the overlying EC layer to prevent leakage current. This manner of insulation of the auxiliary electrode is effective in shortening the length of time required for the initial bleaching or coloration treatment and extending memory time of the display device in actual operation.

Inventors

  • 👤 Hiroshi Inaba
  • 👤 Kiyoshi Nakase
  • 👤 Yukitoshi Yanagida
  • 👤 Hiroyuki Nishii

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:01
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/153; G02F1/155; G02F1/1514; G02F1/1523; G02F1/1524; G02F1/1516; G02F2001/1517

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 264 words
An electrochromic display device comprising: two transparent substrates which are held opposite to and spaced from each other and each of which is laid with a transparent electrode film on the side facing the other substrate; a first electrochromic layer which is formed on the transparent electrode film on one of the two substrates and is formed of a first electrochromic material which takes on color in its electrochemically oxidized state; a second electrochromic layer which is formed on the transparent electrode film on the other of the two substrates and is formed of a second electrochromic material which takes on color in its electrochemically reduced state; an electrolyte which occupies the space between the two substrates; an auxiliary electrode disposed in a marginal region of the space between the two substrates for use in initial reduction of one of the first and second electrochromic layers, the auxiliary electrode comprising an electrode body comprising an electroconductive material and an electrochemically oxidizable and reducible substance, two insulating layers laid directly on opposite surfaces of said electrode body to intervene between said electrode body and the transparent electrode films on the two substrates and to insulate said electrode body from the two transparent electrode films, each of said two insulating layers being an organic polymer sheet which is substantially impermeable to ions, and an insulating covering which is permeable to ions and at least partially covers said electrode body such that said insulating covering intervenes between said electrolyte and said electrode body, said insulating covering being wrapped around said electrode body and said two insulating layers.
Claim 2
Dependent Claim 264 words
An electrochromic display device comprising: two transparent substrates which are held opposite to and spaced from each other and each of which is laid with a transparent electrode film on the side facing the other substrate; a first electrochromic layer which is formed on the transparent electrode film on one of the two substrates and is formed of a first electrochromic material which takes on color in its electrochemically oxidized state; a second electrochromic layer which is formed on the transparent electrode film on the other of the two substrates and is formed of a second electrochromic material which takes on color in its electrochemically reduced state; an electrolyte which occupies the space between the two substrates; an auxiliary electrode disposed in a marginal region of the space between the two substrates for use in initial reduction of one of the first and second electrochromic layers, the auxiliary electrode comprising an electrode body comprising an electroconductive material and an electrochemically oxidizable and reducible substance, two insulating layers laid directly on opposite surfaces of said electrode body to intervene between said electrode body and the transparent electrode films on the two substrates and to insulate said electrode body from the two transparent electrode films, each of said two insulating layers being an organic polymer sheet which is substantially impermeable to ions, and an insulating covering which is permeable to ions and at least partially covers said electrode body such that said insulating covering intervenes between said electrolyte and said electrode body, said insulating covering being wrapped around said electrode body and said two insulating layers.
Claim 3
Dependent Claim 36 words
A device according to claim 1, wherein said first and second electrochromic layers are absent in said marginal region, and said insulating covering makes contact with the transparent electrode film on each of the two substrates.
Claim 4
Dependent Claim 28 words
A device according to claim 1, wherein said first and second electrochromic layers intervene between said insulating covering and the transparent electrode films on the two substrates, respectively.
Claim 5
Dependent Claim 20 words
A device according to claim 1, wherein the material of said insulating covering permeable to ions is an insulating paper.
Claim 6
Dependent Claim 15 words
A device according to claim 1, wherein the material of said insulating covering permeable to
Claim 7
Dependent Claim 26 words
A device according to claim 1, wherein said electrochemically oxidizable and reducible substance is a polymer selected from the group consisting of polytriphenylamine, polypyrrole and polythiophene.
Claim 8
Dependent Claim 28 words
A device according to claim 1, wherein said first electrochromic material is selected from the group consisting of Prussian blue, iridium oxide, nickel oxyhydroxide, cuprous oxide and polytriphenylamine.
Claim 9
Dependent Claim 37 words
A device according to claim 7, wherein said second electrochromic material is selected from the group consisting of WO 3 , MoO 3 , V 2 O 3 , Nb 2 O 3 and TiO 2 .
Claim 10
Dependent Claim 12 words
A device according to claim 1, wherein said electrolyte is a solution.
Claim 11
Dependent Claim 17 words
A device according to claim 1, wherein said electrolyte is a gelled solution comprising an organic polymer.
Claim 12
Dependent Claim 13 words
A device according to claim 1, wherein said electrolyte is a solid electrolyte.

References Cited (Backward Citations)

US4371236A Cited
US4229080A Cited
US4502934A Cited
JPS59159134A Cited
JPS6238625A Cited
JPH0415175A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-27 1992-03-28 1992-09-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-27 1996-03-28 1996-09-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-27 2000-03-28 2000-09-27 $7700.00 Window Closed / Lapsed

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