Hydrolysis of diorganodichlorosilanes

Claim 2

A process for the preparation of admixture of cyclic and linear diorganopolysiloxanes, comprising hydrolyzing a diorganodichlorosilane in the presence of an amount of at least one amphoteric surface-active agent effective to increase the relative content of cyclic siloxanes in the resulting admixture of hydrolysis.

Claim 3

The process as defined by claim 1, wherein the medium of hydrolysis comprises an aqueous solution of hydrochloric acid.

Claim 4

The process as defined by claim 2, said amphoteric surface-active agent comprising at least one compound of the formula: ##STR7## in which R and R', which may be identical or different, are each an alkylaminoalkyl radical, a linear or branched chain C 1 -C 20 alkyl radical, or a hydrogen atom, with the proviso that R and R' may form, together with the nitrogen atom from which they depend, a saturated or unsaturated heterocyclic radical containing 1 or 2 nuclei, wherein each nucleus contains from 4 to 6 nuclear atoms, inclusive; X is COO - or SO - 3 ; M is a hydrogen atom, an alkali metal, or a tetraalkylammonium group wherein the alkyl radicals are C 1 -C 20 alkyl radicals; and Y is a linear or branched chain C 1 -C 20 alkylene radical, with the further proviso that at least one of the groups R, R' and Y contains at least 7 carbon atoms.

Claim 5

The process as defined by claim 3, wherein the concentration of said at least one amphoteric surface-active agent ranges from 0.01 to 5% by weight of the aqueous hydrochloric acid medium.

Claim 6

The process as defined by claim 3, said amphoteric surface-active agent comprising at least one compound of the formula: ##STR8## or admixture of compounds of the formula ##STR9## wherein R is a C 7 -C 16 alkyl radical.

Claim 7

The process as defined by claim 3, said medium of hydrolysis comprising a saturated aqueous solution of hydrochloric acid.

Claim 8

The process as defined by claim 3, said medium of hydrolysis comprising a 20 to 32% by weight concentration of hydrochloric acid in water.

Claim 9

The process as defined by claim 3, carried out continuously.

Claim 10

The process as defined by claim 3, carried out discontinuously.

Claim 11

The process as defined by claim 4, said concentration ranging from 0.05 to 3% by weight.

Claim 12

The process as defined by claim 3, said medium of hydrolysis comprising at least 2 moles of water per mole of silane.

Claim 13

The process as defined by claim 11, said medium of hydrolysis comprising from 10 to 50 moles of water per mole of silane.