US4772657A
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Hydrogenated block copolymer compositions
Assignee: Asahi Kasei Corp
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Filing: 1986-07-18
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Granted: 1988-09-20
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Expires: 2006-07-18
Abstract
Abstract A composition having a composition containing substantially no other engineering thermoplastic resin and a compression set (JIS K 6301; 100° C.×22 hours; and compressibility, 25%) of 65% or less as rubber which comprises: (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene, (b) 11 to 233 parts by weight of a homopolymeric and/or copolymeric polyphenylene ether resin comprising a binding unit represented by the general formula, ##STR1## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent substituents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30° C. in a 0.5 g/dl chloroform solution, (c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and (d) 5 to 150 parts by weight of a polyolefin resin and/or a polystyrene resin.
Inventors
- 👤 Yoshikuni Akiyama
- 👤 Yasushi Kishimoto
- 👤 Ken Mizushiro
- 👤 Hideo Morita
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 20:02
CPC Classifications
C; C08; C08L; C08L53/00; C08L53/02; C08L53/025; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L65/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
207 words
A composition having a compression set (JIS K 6301; 100° C.×22 hours; and compressibility, 25%) of 65% or less as rubber, consisting essentially of: (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene, (b) 11 to 233 parts by weight of a polymer selected from the group consisting of a homopolymeric polyphenylene ether resin, a copolymeric polyphenylene ether resin and combinations thereof, comprising a binding unit represented by the general formula, ##STR4## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent substituents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30° C. in a 0.5 g/dl chloroform solution, (c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and (d) 5 to 150 parts by weight of a resin selected from the group consisting of a polyolefin resin, a polystyrene resin and a combination thereof.
Claim 2
Dependent Claim
207 words
A composition having a compression set (JIS K 6301; 100° C.×22 hours; and compressibility, 25%) of 65% or less as rubber, consisting essentially of: (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene, (b) 11 to 233 parts by weight of a polymer selected from the group consisting of a homopolymeric polyphenylene ether resin, a copolymeric polyphenylene ether resin and combinations thereof, comprising a binding unit represented by the general formula, ##STR4## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent substituents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30° C. in a 0.5 g/dl chloroform solution, (c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and (d) 5 to 150 parts by weight of a resin selected from the group consisting of a polyolefin resin, a polystyrene resin and a combination thereof.
Claim 3
Dependent Claim
111 words
The composition according to claim 1, wherein the hydrogenated block copolymer (a) is one produced by hydrogenating a block copolymer which comprises two or more polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and two or more polymer blocks B composed mainly of a conjugated diene and in which at least one polymer block B is arranged at the end of the polymer chains and the content of the vinyl-substituted aromatic hydrocarbon bonded is 10 to 50 wt. %, thereby reducing the content of the unsaturated bond of the polymer block B after hydrogenation to 20 mole % or less of that of the polymer block B before hydrogenation.
Claim 4
Dependent Claim
24 words
The composition according to claim 2, wherein the hydrogenated block copolymer (a) is a hydrogenated product of a block copolymer having a B-A-B-A structure.
Claim 5
Dependent Claim
94 words
The composition according to claim 1, wherein the hydrogenated block copolymer (a) is one produced by hydrogenating a block copolymer which comprises at least two terminal blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one mid-block B composed mainly of a conjugated diene and in which the content of the vinyl-substituted aromatic hydrocarbon bonded is 10 to 50 wt. %, thereby reducing the content of the unsaturated bond of the polymer block B after hydrogenation to 20 mole % or less of that of the polymer block B before hydrogenation.
Claim 6
Dependent Claim
24 words
The composition according to claim 4, wherein the hydrogenated block copolymer (a) is a hydrogenated product of a block copolymer having an A-B-A structure.
Claim 7
Dependent Claim
105 words
The composition according to claim 1, wherein the hydrogenated block copolymer (a) is one produced by hydrogenating a block copolymer which has a structure of (A-B) m X, (B-A-B) m X or mixture thereof wherein X represents a coupling agent having two or more functional groups or a polyfunctional initiator residue and m represents an integer of 2 or more, and in which the content of the vinyl-substituted aromatic hydrocarbon bonded is 10 to 50 wt. %, thereby reducing the content of the unsaturated bond of the polymer block B after hydrogenation to 20 mole % of less of the polymer block B before hydrogenation.
Claim 8
Dependent Claim
54 words
The composition according to claim 1, wherein the hydrogenated block copolymer (a) is a hydrogenated product of a block copolymer comprising a polymer block A composed mainly of a vinly-substituted aromatic hydrocarbon and a polymer block B composed mainly of a material selected from the group consisting of butadiene, isoprene and a combination thereof.
Claim 9
Dependent Claim
34 words
The composition according to claim 7, wherein the polymer block A composed mainly of a vinyl-substituted aromatic hydrocarbon, which is one component of the hydrogenated block copolymer (a), is one composed mainly of styrene.
Claim 10
Dependent Claim
52 words
The composition according to claim 8, wherein the hydrogenated block copolymer (a) is a hydrogenated product of a block copolymer in which the number average molecular weight is 70,000 to 500,000 and the amount of 1,2-vinyl bond in the polymer block B composed mainly of butadiene is 25 to 45 mole %.
Claim 11
Dependent Claim
24 words
The composition according to claim 1, wherein the polyphenylene ether resin (b) is poly(2,6-dimethyl-1,4-phenylene) ether, a copolymer of 2,6-dimethylphenol with 2,3,6-trimethylphenol or mixture thereof.
Claim 12
Dependent Claim
19 words
The composition according to claim 1, wherein the non-aromatic softening agent for rubber (c) is a paraffin type oil.
Claim 13
Dependent Claim
39 words
The composition according to claim 11, wherein the non-aromatic softening agent for rubber (c) is a paraffin type oil in which the content of aromatic components is substantially 0.3% or less as analyzed by the method of ASTM 2140-63T.
Claim 14
Dependent Claim
14 words
The composition according to claim 1, wherein the polyolefin resin (d) is isotactic polypropylene.
Claim 15
Dependent Claim
14 words
The composition according to claim 1, wherein the polyolefin resin (d) is high-density polyethylene.
Claim 16
Dependent Claim
25 words
The composition according to claim 1, wherein the polyolefin resin (d) is super-high-molecular-weight high-density polyethylene having a viscosity average molecular weight of 1,000,000 or more.
Claim 17
Dependent Claim
18 words
The composition according to claim 1, wherein the polystyrene resin (d) is one of polystyrene, poly(α-methylstyrene) and poly(p-methylstyrene).
Claim 18
Dependent Claim
35 words
The composition according to claim 1, wherein said composition contains 100 to 500 parts by weight of the non-aromatic softening agent for rubber (c) per 100 parts by weight of the hydrogenated block copolymer (a).
Claim 19
Dependent Claim
29 words
The composition according to claim 1, further comprising inorganic fillers, flame retardants, glass fibers, carbon fibers, antioxidants, ultraviolet absorbers, hindered amine type light stabilizers, electroconductive fillers or coloring agents.
Claim 20
Dependent Claim
206 words
An composition having a compression set (JIS K 6301; 100° C.×22 hours; and compressiblity, 25%) of 65% or less as rubber, which comprises: (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene, (b) 11 to 233 parts by weight of a polymer selected from the group consisting of a homopolymeric polyphenylene ether resin, a copolymeric polyphenylene ether resin and combinations thereof, comprising a binding unit represented by the general formula, ##STR5## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent substitutents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30° C. in a 0.5 g/dl chloroform solution, (c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and (d) 5 to 150 parts by weight of a resin selected from the group consisting of a polyolefin resin, a polystyrene resin and a combination thereof.
Claim 21
Dependent Claim
206 words
An composition having a compression set (JIS K 6301; 100° C.×22 hours; and compressiblity, 25%) of 65% or less as rubber, which comprises: (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two polymer blocks A composed mainly of a vinyl-substituted aromatic hydrocarbon and at least one polymer block B composed mainly of a conjugated diene, (b) 11 to 233 parts by weight of a polymer selected from the group consisting of a homopolymeric polyphenylene ether resin, a copolymeric polyphenylene ether resin and combinations thereof, comprising a binding unit represented by the general formula, ##STR5## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent substitutents selected from the group consisting of hydrogen, halogen, hydrocarbon groups and substituted hydrocarbon groups, and having a reduced viscosity in a range of from 0.15 to 0.70 as measured at 30° C. in a 0.5 g/dl chloroform solution, (c) 10 to 500 parts by weight of a non-aromatic softening agent for rubber, and (d) 5 to 150 parts by weight of a resin selected from the group consisting of a polyolefin resin, a polystyrene resin and a combination thereof.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-09-20 | 1992-03-21 | 1992-09-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-09-20 | 1996-03-21 | 1996-09-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-09-20 | 2000-03-21 | 2000-09-20 | $7700.00 | Window Closed / Lapsed |