US4563500A
Expired / Lapsed
US
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Polyphenylene ether compositions with high impact strength and improved moldability
Assignee: General Electric Co
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Filing: 1984-01-11
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Granted: 1986-01-07
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Expires: 2004-01-11
Abstract
Abstract There are provided thermoplastic compositions comprising a polyphenylene ether resin, a styrene resin and an impact modifying combination comprising (i) an elastomeric block copolymer of a vinyl aromatic compound and a conjugated diene and (ii) a hydrogenated derivative of (i). The compositions are moldable to articles having impact strength and mold flow properties unexpectedly superior to those expected in view of compositions prepared, respectively, with (c) (i) and (c) (ii) as the sole impact modifiers.
Inventors
- 👤 William R. Haaf
- 👤 Gim F. Lee, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 05:19
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08K; C08K5/00; C08K5/49; C08L25/06; C08L53/00; C08L53/02; C08L57/00; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L2205/00; C08L2205/02; C08L51/00; C08L51/04; C08L69/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
102 words
A thermoplastic composition comprising: (a) a polyphenylene ether resin; (b) a styrene resin; and (c) an Izod impact modifier comprising in combination (i) from 99 to 1 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 , and (ii) from 1 to 99 parts by weight of a hydrogenated elastomeric A-B-A 1 block copolymer.
Claim 2
Dependent Claim
102 words
A thermoplastic composition comprising: (a) a polyphenylene ether resin; (b) a styrene resin; and (c) an Izod impact modifier comprising in combination (i) from 99 to 1 parts by weight of an elastomeric block copolymer of the A-B-A 1 type, wherein terminal blocks A and A 1 are the same or different and are polymerized vinyl aromatic hydrocarbons and center block B is a polymerized conjugated diene, the molecular weight of B being higher than the combined molecular weights of A and A 1 , and (ii) from 1 to 99 parts by weight of a hydrogenated elastomeric A-B-A 1 block copolymer.
Claim 3
Dependent Claim
108 words
A composition as defined in claim 1 wherein the polyphenylene ether resin (a) is comprised of structural units of the formula: ##STR5## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and phenyl nucleus.
Claim 4
Dependent Claim
19 words
A composition as defined in claim 2 wherein each Q is alkyl having from 1 to 4 carbon atoms.
Claim 5
Dependent Claim
13 words
A composition as defined in claim 3 wherein said polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene)ether.
Claim 6
Dependent Claim
16 words
A composition as defined in claim 1 wherein the styrene resin (b) is a homopolystyrene resin.
Claim 7
Dependent Claim
20 words
A composition as defined in claim 1 wherein the styrene resin (b) is a rubber modified high impact polystyrene resin.
Claim 8
Dependent Claim
55 words
A composition as defined in claim 1 wherein in A-B-A 1 block copolymer components (c) (i) and (c) (ii), each of terminal blocks A and A 1 has an average molecular weight of from about 2,000 to about 150,000 and center block B has an average molecular weight of from about 25,000 to about 1,000,000.
Claim 9
Dependent Claim
30 words
A composition as defined in claim 1 wherein component (c) (ii), there average of unsaturation of center block B has been reduced to less than 20% of its original value.
Claim 10
Dependent Claim
56 words
A composition as defined in claim 7 wherein in said A-B-A 1 block copolymer components (c) (i) and (c) (ii), each of terminal blocks A and A 1 has an average molecular weight of from about 4,000 to about 115,000 and center block B has an average molecular weight of from about 20,000 to about 450,000.
Claim 11
Dependent Claim
65 words
A composition as defined in claim 1 wherein in the A-B-A 1 block copolymer component (c) (i), the vinyl aromatic hydrocarbon of terminal blocks A and A 1 are selected from the group consisting of styrene, α-methyl styrene, vinyl toluene, vinyl xylene and vinyl naphthalene and the conjugated diene of center block B is selected from the group consisting of butadiene, isoprene, 1,3-pentadiene and 2,3-dimethylbutadiene.
Claim 12
Dependent Claim
68 words
A composition as defined in claim 1, which comprises from about 10 to about 90 parts by weight of polyphenylene ether resin (a), from about 90 to about 10 parts by weight of styrene resin (b), from about 0.5 to about 20 parts by weight of A-B-A 1 block copolymer (c)(i) and from about 0.5 to about 20 parts by weight of hydrogenated A-B-A 1 block copolymer (c)(ii).
Claim 13
Dependent Claim
16 words
A composition as defined in claim 1 which includes a reinforcing amount of a reinforcing agent.
Claim 14
Dependent Claim
18 words
A composition as defined in claim 1 which includes a flame retardant amount of a flame retardant agent.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-01-06 | 1989-07-08 | 1990-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-06 | 1993-07-08 | 1994-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-06 | 1997-07-08 | 1998-01-07 | $7700.00 | Window Closed / Lapsed |