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US4771110A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric materials having controlled physical properties and processes for obtaining these

Assignee: Air Products and Chemicals Inc
•
Filing: 1986-02-04
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Granted: 1988-09-13
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Expires: 2006-02-04
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Abstract

Abstract Ground polymer elastomer or other polymeric plastic, particularly from recovered scrap, is surface modified by treatment with a gaseous mixture containing a minor amount of fluorine and a larger amount of at least one reactive gas in an inert gaseous carrier. By the treatment the ground material is made more compatible for admixture with polyfunctional polymer-forming liquids, thereby obtaining novel composites of controlled physical properties. The other reactive gas is preferably oxygen or one of the gases from the group consisting of: chlorine and SO 2 with or without added oxygen.

Inventors

  • 👤 Bernard D. Bauman
  • 👤 Patricia E. Burdick
  • 👤 Rajendra K. Mehta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:47
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C08C; C08C19/00; C08C19/12; C08C19/14; C08F; C08F8/00; C08F8/18; C08F8/20; C08F8/22; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/69; C08G85/00; C08J11/00; C08J11/04; C08J2375/00; C08J2375/04; Y; Y02; Y02P; Y02P20/00; Y02P20/141; Y02P20/143; Y02W; Y02W30/00; Y02W30/50; Y02W30/62

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 77 words
A method which comprises subjecting polymeric particles, selected from the group consisting of natural rubber, styrene-butadiene rubber, polymers of ethylene-propylene diene monomers, polyethylene terephthalate and polypropylene, in finely divided form to contact with a gaseous medium comprising elemental fluorine and at least one other reactive gas for a time sufficient to effect chemical modification of the surface layer of the particles by formation therein of reactive functional groups, and incorporating the treated particles in a polyurethane-forming liquid.
Claim 2
Independent Claim 77 words
A method which comprises subjecting polymeric particles, selected from the group consisting of natural rubber, styrene-butadiene rubber, polymers of ethylene-propylene diene monomers, polyethylene terephthalate and polypropylene, in finely divided form to contact with a gaseous medium comprising elemental fluorine and at least one other reactive gas for a time sufficient to effect chemical modification of the surface layer of the particles by formation therein of reactive functional groups, and incorporating the treated particles in a polyurethane-forming liquid.
Claim 3
Dependent Claim 19 words
The method as defined in claim 1 wherein said gaseous medium includes elemental oxygen and an inert diluent gas.
Claim 4
Dependent Claim 13 words
The method as defined in claim 2 wherein said polymeric particles are elastomeric.
Claim 5
Dependent Claim 39 words
The method as defined in claim 3 wherein said gaseous medium comprises 1×10 -4 to 25 percent by volume elemental fluorine and 1×10 -3 to 25 percent by volume elemental oxygen, the rest consisting essentially of inert gaseous diluent.
Claim 6
Dependent Claim 19 words
The method as defined in claim 1 wherein said gaseous medium includes SO 2 and an inert diluent gas.
Claim 7
Dependent Claim 13 words
The method as defined in claim 5 wherein said polymeric particles are elastomeric.
Claim 8
Dependent Claim 39 words
The method as defined in claim 5 wherein said gaseous medium comprises 1×10 -4 to 25% by volume of elemental fluorine and 1% to 50% by volume of SO 2 , the rest consisting essentially of inert gaseous diluent.
Claim 9
Dependent Claim 36 words
The method as defined in claim 2 wherein said gaseous medium further includes a reactive gas from the group consisting of Cl 2 , SO 2 , Br 2 , BrCl 3 , BrCl, and CO.
Claim 10
Dependent Claim 12 words
The method as defined in claim 8 wherein said particles are elastomeric.
Claim 11
Dependent Claim 40 words
The method as defined in claim 1 wherein said gaseous medium includes at least one reactive gas from the group consisting of O 2 , Cl 2 , SO 2 , Br 2 , BrCl 3 , BrCl, and CO.
Claim 12
Dependent Claim 12 words
The method as defined in claim 10 wherein said particles are elastomeric.
Claim 13
Dependent Claim 17 words
The method as defined in claim 1 wherein said polymeric particles are composed of a non-elastomeric thermoplastic.
Claim 14
Dependent Claim 22 words
The method as defined in claim 12 wherein said polymeric particles are selected from the group consisting of polyethylene terephthalate and polypropylene.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-13 1992-03-14 1992-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-13 1996-03-14 1996-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-13 2000-03-14 2000-09-13 $7700.00 Window Closed / Lapsed

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