US4767697A
Expired / Lapsed
US
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Silver halide color photographic material
Assignee: Fujifilm Corp
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Filing: 1986-01-21
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Granted: 1988-08-30
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Expires: 2006-01-21
Abstract
Abstract Photographic coupler solvents which are solid at ordinary temperature are described for incorporation in photographic emulsions and elements. The solvents are employed in combination with a cyan dye forming coupler of the specific phenol type and a discoloration inhibitor of the dihydroxybenzene ether type to improve long-term preservability of the developed cyan dye particularly by exposure to mild heat and humidity.
Inventors
- 👤 Makoto Umemoto
- 👤 Yoshio Seoka
- 👤 Masakazu Morigaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 04:57
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/3003; G03C7/3005; G03C7/3006
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
370 words
A color photographic material which comprises a support having thereon at least one silver halide emulsion layer having associated therewith at least one cyan dye forming coupler represented by formula [I], at least one coupler solvent having a melting point higher than 25° C., and at least one compound represented by formula [VI]: ##STR13## wherein: R 1 represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; R 2 represents a substituted or unsubstituted aliphatic group; R 3 represents a hydrogen atom, a halogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted acylamino group; Y 1 represents a hydrogen atom, or a group or atom capable of being eliminated by a coupling reaction with an oxidized developing agent; said compound represented by formula (I) may form a dimeric, oligomeric or polymeric coupler by means of groups R 2 , R 3 and Y 1 ; R 13 , R 14 and R 15 , which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylamino group or an acylamino group, a halogen atom, an acyl group, an alkoxy-carbonyl group, an aryloxycarbonyl group, an acyloxy group, a sulfonyl group, a sulfamoyl group, a sulfonamide group or a heterocyclic group, and two groups located at an adjacent position to each other among the groups R 13 , R 14 and R 15 may be connected to each other to form a 5 to 7 membered cycloaliphatic, aromatic, heterocyclic or heteroaromatic ring; R 16 , R 17 , R 18 , R 19 , R 22 , R 23 , R 24 , and R 25 , which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxy-carbonyl group, an amide group, a hydroxyl group, or a halogen atom and any two groups selected from R 16 through R 19 may form a 5 or 6 membered ring.
Claim 2
Dependent Claim
370 words
A color photographic material which comprises a support having thereon at least one silver halide emulsion layer having associated therewith at least one cyan dye forming coupler represented by formula [I], at least one coupler solvent having a melting point higher than 25° C., and at least one compound represented by formula [VI]: ##STR13## wherein: R 1 represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; R 2 represents a substituted or unsubstituted aliphatic group; R 3 represents a hydrogen atom, a halogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted acylamino group; Y 1 represents a hydrogen atom, or a group or atom capable of being eliminated by a coupling reaction with an oxidized developing agent; said compound represented by formula (I) may form a dimeric, oligomeric or polymeric coupler by means of groups R 2 , R 3 and Y 1 ; R 13 , R 14 and R 15 , which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylamino group or an acylamino group, a halogen atom, an acyl group, an alkoxy-carbonyl group, an aryloxycarbonyl group, an acyloxy group, a sulfonyl group, a sulfamoyl group, a sulfonamide group or a heterocyclic group, and two groups located at an adjacent position to each other among the groups R 13 , R 14 and R 15 may be connected to each other to form a 5 to 7 membered cycloaliphatic, aromatic, heterocyclic or heteroaromatic ring; R 16 , R 17 , R 18 , R 19 , R 22 , R 23 , R 24 , and R 25 , which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxy-carbonyl group, an amide group, a hydroxyl group, or a halogen atom and any two groups selected from R 16 through R 19 may form a 5 or 6 membered ring.
Claim 3
Dependent Claim
70 words
The color photographic material as described in claim 1 wherein, in formula [I], R 1 is selected from a substituted or unsubstituted alkyl or aryl group, R 2 is selected from an unsubstituted alkyl group containing 2 to 15 carbon atoms or a methyl group substituted by one or more substituents containing at least one carbon atom, and R 3 is selected from a hydrogen atom or a halogen atom.
Claim 4
Dependent Claim
32 words
The color photographic material as described in claim 2 wherein, in formula [I], R 2 is an alkyl group containing 2 to 15 carbon atoms and R 3 is a chlorine atom.
Claim 5
Dependent Claim
40 words
The color photographic material as described in claim 1, wherein R 1 represents an aliphatic hydrocarbon group containing 1 to 31 carbon atoms, an aryl group containing 6 to 31 carbon atoms or a heterocyclic group containing 1-31 carbon atoms.
Claim 6
Dependent Claim
35 words
The color photographic material as described in claim 1 wherein, in formulae [I], Y 1 and is selected from a hydrogen atom, a halogen atom and a substituted or unsubstituted alkoxy, aryloxy or sulfonamido group.
Claim 7
Dependent Claim
20 words
The color photographic material as described in claim 5 wherein, in formula [I], Y 1 and is a halogen atom.
Claim 8
Dependent Claim
35 words
The color photographic material as described in claim 1 wherein said compound selected from the compound represented by formula [VI] is included in the same silver halide emulsion layer as said cyan dye forming coupler.
Claim 9
Dependent Claim
39 words
The color photographic material as described in claim 1 wherein said coupler solvent is selected from the group consisting of phthalic acid esters, esters of phosphoric or phosphonic acids, benzoic acid esters, aliphatic carboxylic acid esters and aromatic esters.
Claim 10
Dependent Claim
22 words
The color photographic material as described in claim 8 wherein said coupler solvent is selected from esters of phosphoric or phosphonic acids.
Claim 11
Dependent Claim
31 words
The color photographic material as described in claim 1 wherein said coupler solvents are used in a range up to 150 weight % based on the amount of said cyan couplers.
Claim 12
Dependent Claim
39 words
The color photographic material as described in claim 1 wherein said compounds represented by formula [VI] may be added to a silver halide emulsion layer in an amount of 0.005 to 2.0 moles per mol of said cyan couplers.
Claim 13
Dependent Claim
21 words
The color photographic material as described in claim 1 wherein in combination with said cyan couplers other color couplers are employed.
Claim 14
Dependent Claim
95 words
The color photographic material as described in claim 1, wherein the substituted aliphatic group, the substituted aromatic group and the substituted heterocyclic group have substituents selected from the group consisting of an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an acyl group, an ester group, an amido group, a carbamoyl group, a sulfamoyl group, an imido group, a ureido group, a sulfonyl group, an aliphatic or aromatic thio group, a hydroxyl group, a cyano group, a carboxyl group, a nitro group, a sulfo group and a halogen atom.
Claim 15
Dependent Claim
21 words
The color photographic material as described in claim 1, wherein R 1 is an alkyl group substituted with an aryloxy group.
Claim 16
Dependent Claim
61 words
The color photographic material as described in claim 1, wherein R 2 is an unsubstituted alkyl group containing 2 to 15 carbon atoms or a methyl group substituted by one or more substituents containing at least one carbon atom selected from the group consisting of an arylthio group, an alkylthio group, an acylamino group, an aryloxy group and an alkyloxy group.
Claim 17
Dependent Claim
20 words
The color photographic material as described in claim 1, wherein R 2 is an ethyl group or a propyl group.
Claim 18
Dependent Claim
16 words
The color photographic material as described in claim 1, wherein R 3 is chlorine or fluorine.
Claim 19
Dependent Claim
32 words
The color photographic material as described in claim 1, wherein R 2 is selected from the group consisting of methyl, ethyl, propyl, butyl, pentadecyl, tert-butyl, cyclohexyl, cyclohexylmethyl, phenylthiomethyl, dodecyloxyphenylthiomethyl, butaneamidomethyl or methoxymethyl.
Claim 20
Dependent Claim
30 words
The color photographic material as described in claim 1, wherein R 3 is a lower alkyl group containing 1 to 5 carbon atoms, an aryl group or an acylamino group.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-08-30 | 1992-02-29 | 1992-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-08-30 | 1996-02-29 | 1996-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-08-30 | 2000-02-29 | 2000-08-30 | $7700.00 | Window Closed / Lapsed |