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US4766170A
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Heat curing organopolysiloxane composition
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1987-02-11
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Granted: 1988-08-23
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Expires: 2007-02-11
Abstract
Abstract A silicone elastomer having improved fatigue resistance is obtained by heat-curing a composition consists essentially of an organopolysiloxane gum having vinyl endblocking, an organopolysiloxane gum having from 0.1 to 2.0 percent of the organic radicals present as alkenyl radicals, an organopolysiloxane fluid having from 10 to 75 percent of the radicals present as alkenyl radicals, an organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen radicals in each molecule, a specific silica filler, and an organoperoxide.
Inventors
- 👤 Hiroshi Honma
- 👤 Mitsuo Hamada
- 👤 Hideki Kobayashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 06:00
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K3/36; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08G77/20
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
265 words
Heat-curing organopolysiloxane composition consisting essentially of (A) 100 parts by weight of organopolysiloxane gum with the general formula ##STR2## in which R 1 and R 2 are selected from the group consisting of monovalent hydrocarbon groups excluding alkenyl groups, and cyanoalkyl groups, and n is equal to or greater than 3,000, (B) 50 to 150 parts by weight of organopolysiloxane gum with the general formula R.sup.3.sub.3 SiO[R.sup.4.sub.2 SiO].sub.m SiR.sup.3.sub.3 in which R 3 is selected from the group consisting of monovalent hydrocarbon group, cyanoalkyl group, and the hydroxyl group; R 4 is selected from the group consisting of monovalent hydrocarbon group, and cyanoalkyl group, of which 0.1 to 0.2 percent of the radicals attached to the silicon atoms are alkenyl group; and m is equal to or greater than 3,000. (C) 0.5 to 10 parts by weight of organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms in each molecule, having a viscosity ranging from 10 to 1000 centipoise at 25° C. surface area of at least 250 m 2 /g, at the rate of 20 to 50 parts by weight per 100 parts by weight of the total quantity of components (A) plus (B), (E) 0.1 to 5 parts by weight of organoperoxide, and (F) 1 to 50 parts by weight of organopolysiloxane oil with the general formula (CH.sub.3).sub.2 R.sup.5 Si[R.sup.6.sub.2 SiO].sub.p SiR.sup.5 (CH.sub.3).sub.2 in which R 5 is a hydroxyl group or methyl group; R 6 is a monovalent hydrocarbon group, of which 10 to 75 percent of the radicals attached to the silicon atoms are alkenyl group; and p is 5 to 100.
Claim 2
Dependent Claim
265 words
Heat-curing organopolysiloxane composition consisting essentially of (A) 100 parts by weight of organopolysiloxane gum with the general formula ##STR2## in which R 1 and R 2 are selected from the group consisting of monovalent hydrocarbon groups excluding alkenyl groups, and cyanoalkyl groups, and n is equal to or greater than 3,000, (B) 50 to 150 parts by weight of organopolysiloxane gum with the general formula R.sup.3.sub.3 SiO[R.sup.4.sub.2 SiO].sub.m SiR.sup.3.sub.3 in which R 3 is selected from the group consisting of monovalent hydrocarbon group, cyanoalkyl group, and the hydroxyl group; R 4 is selected from the group consisting of monovalent hydrocarbon group, and cyanoalkyl group, of which 0.1 to 0.2 percent of the radicals attached to the silicon atoms are alkenyl group; and m is equal to or greater than 3,000. (C) 0.5 to 10 parts by weight of organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms in each molecule, having a viscosity ranging from 10 to 1000 centipoise at 25° C. surface area of at least 250 m 2 /g, at the rate of 20 to 50 parts by weight per 100 parts by weight of the total quantity of components (A) plus (B), (E) 0.1 to 5 parts by weight of organoperoxide, and (F) 1 to 50 parts by weight of organopolysiloxane oil with the general formula (CH.sub.3).sub.2 R.sup.5 Si[R.sup.6.sub.2 SiO].sub.p SiR.sup.5 (CH.sub.3).sub.2 in which R 5 is a hydroxyl group or methyl group; R 6 is a monovalent hydrocarbon group, of which 10 to 75 percent of the radicals attached to the silicon atoms are alkenyl group; and p is 5 to 100.
Claim 3
Dependent Claim
18 words
Heat-curing silicone rubber composition described in claim 1, characterized in that the ultrafine silica powder is fumed silica.
Claim 4
Dependent Claim
12 words
Composition described in claim 1, wherein R 5 is the hydroxyl group.
Claim 5
Dependent Claim
17 words
Composition described in claim 1, wherein the alkenyl group of (B) and of (F) is a vinyl.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-08-23 | 1992-02-22 | 1992-08-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-08-23 | 1996-02-22 | 1996-08-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-08-23 | 2000-02-22 | 2000-08-23 | $7700.00 | Window Closed / Lapsed |