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Single-component, storage-stable diorganopolysiloxane CVE compositions

Assignee: Rhodia Chimie SAS
•
Filing: 1987-04-28
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Granted: 1988-08-09
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Expires: 2007-04-28
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Abstract

Abstract Single-component diorganopolysiloxane compositions which are storage-stable in the absence of atmospheric moisture and which crosslink into silicone elastomeric state in the presence of moisture, are comprised of an alkoxy-terminated diorganopolysiloxane, a functionalization catalyst containing a primary or secondary amine group, a tin condensation catalyst, a filler material, and an effective stabilizing amount of an isocyanurate of the formula: ##STR1## wherein W is --CH 2 ) n N═C═O and n ranges from 1 to 12.

Inventors

  • 👤 Michel Letoffe
  • 👤 Pierre-Michel Peccoux

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 19:06
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 336 words
A single-component, storage-stable organopolysiloxane cold vulcanizable elastomeric composition of matter, comprising: (i) 100 parts of at least one diorganopolysiloxane polymer of the formula: R.sup.2.sub.3-a R.sup.1.sub.a Si(OSiR.sub.2).sub.r SiR.sup.1.sub.a R.sup.2.sub.3-a (II) in which each R, which may be identical or different, is a hydrocarbon radical containing from 1 to 10 carbon atoms, or a substituted such hydrocarbon radical bearing at least one halogen atom or cyano group substituent, each R 1 , which may be identical or different, is a C 1 -C 10 hydrocarbon radical, each R 2 , which may be identical or different, is an alkoxy or polyalkoxy radical of the formulae ZO or ZOEO, in which Z is a C 1 -C 4 alkyl radical, E is a straight or branched chain C 2 -C 4 alkylene radical, a is zero or 1 and the symbol r is a number such that the polymer of the formula (II) has a viscosity of from 500 to 1,000,000 mPa.s at 25° C.; (ii) 0 to 15 parts of at least one polyalkoxysilane of the formula: R.sup.1.sub.a SiR.sup.2.sub.3-a (III) in which R 1 , R 2 and a are as defined above; (iii) 0 to 250 parts of inorganic filler material; (iv) 0.001 to 3 parts of a condensation catalyst; (v) 0.001 to 15 parts of at least one amino compound bearing at least one primary or secondary amine group comprising an organic amine having a pKb of less than 5 in aqueous media, or an aminoorganosilane or aminoorganopolysiloxane, said aminoorganosilane or aminoorganopolysiloxane bearing, per molecule: (a) at least one C 3 -C 15 organic radical bonded to the silicon atom by an SiC bond and bearing at least one amino group, and (b) at least one C 1 -C 5 alkoxy radical or a C 3 -C 6 alkoxyalkyleneoxy radical; and (vi) an effective stabilizing amount of at least one isocyanurate of the formula: ##STR15## in which W is a radical (CH 2 ) n --N═C═O and n is an integer of from 1 to 12.
Claim 2
Dependent Claim 336 words
A single-component, storage-stable organopolysiloxane cold vulcanizable elastomeric composition of matter, comprising: (i) 100 parts of at least one diorganopolysiloxane polymer of the formula: R.sup.2.sub.3-a R.sup.1.sub.a Si(OSiR.sub.2).sub.r SiR.sup.1.sub.a R.sup.2.sub.3-a (II) in which each R, which may be identical or different, is a hydrocarbon radical containing from 1 to 10 carbon atoms, or a substituted such hydrocarbon radical bearing at least one halogen atom or cyano group substituent, each R 1 , which may be identical or different, is a C 1 -C 10 hydrocarbon radical, each R 2 , which may be identical or different, is an alkoxy or polyalkoxy radical of the formulae ZO or ZOEO, in which Z is a C 1 -C 4 alkyl radical, E is a straight or branched chain C 2 -C 4 alkylene radical, a is zero or 1 and the symbol r is a number such that the polymer of the formula (II) has a viscosity of from 500 to 1,000,000 mPa.s at 25° C.; (ii) 0 to 15 parts of at least one polyalkoxysilane of the formula: R.sup.1.sub.a SiR.sup.2.sub.3-a (III) in which R 1 , R 2 and a are as defined above; (iii) 0 to 250 parts of inorganic filler material; (iv) 0.001 to 3 parts of a condensation catalyst; (v) 0.001 to 15 parts of at least one amino compound bearing at least one primary or secondary amine group comprising an organic amine having a pKb of less than 5 in aqueous media, or an aminoorganosilane or aminoorganopolysiloxane, said aminoorganosilane or aminoorganopolysiloxane bearing, per molecule: (a) at least one C 3 -C 15 organic radical bonded to the silicon atom by an SiC bond and bearing at least one amino group, and (b) at least one C 1 -C 5 alkoxy radical or a C 3 -C 6 alkoxyalkyleneoxy radical; and (vi) an effective stabilizing amount of at least one isocyanurate of the formula: ##STR15## in which W is a radical (CH 2 ) n --N═C═O and n is an integer of from 1 to 12.
Claim 3
Dependent Claim 23 words
The composition of matter as defined by claim 1, wherein said compound (vi) having the formula (I), n ranges from 4 to 8.
Claim 4
Dependent Claim 13 words
The composition of matter as defined by claim 2, wherein n is 6.
Claim 5
Dependent Claim 19 words
The composition of matter as defined by claim 1, comprising from 0.01 to 5 parts of said compound (vi).
Claim 6
Dependent Claim 18 words
The composition of matter as defined by claim 1, wherein said condensation catalyst (iv) comprises a tin catalyst.
Claim 7
Dependent Claim 74 words
The composition of matter as defined by claim 1, further comprising from 0.5 to 10 parts of at least one aminoorganosilane or aminoorganopolysiloxane compound (vii) bearing, per molecule, at least one C 3 -C 15 organic radical linked by an SiC bond to the silicon atom and substituted by at least one tertiary amine and/or quanidino radical and at least one C 1 -C 5 alkoxy group or C 3 -C 6 alkoxyalkyleneoxy radical.
Claim 8
Dependent Claim 87 words
The composition of matter as defined by claim 6, wherein said compound (vii) has the formula: ##STR16## in which the radicals Y, which may be identical or different, are each an alkyl or alkoxy radical containing from 1 to 4 carbon atoms, at least two of which radicals Y being alkoxy radicals, the radicals Y', which may be identical or different, are each a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms, and s is an integer of from 3 to 10.
Claim 9
Dependent Claim 79 words
The composition of matter as defined by claim 1, wherein said condensation catalyst (iv) comprises a diorganotin bis(β-diketonate) with an organotin compound, also of valency (IV), but devoid of β-diketonato group, and including at least one tin atom, each such tin atom bearing two organic radicals linked by a Sn--C bond, the remaining two valencies being satisfied by organic or inorganic radicals linked by an SnO or SnS bond, by halogen atoms, by hydroxyl groups, or by oxygen atoms.
Claim 10
Dependent Claim 19 words
The composition of matter as defined by claim 1, comprising from 2.5 to 10 parts of said polyalkoxysilane (ii).
Claim 11
Dependent Claim 13 words
The composition of matter as defined by claim 1, in cured elastomeric state.
Claim 12
Dependent Claim 12 words
A shaped article comprising the cured elastomer as defined by claim 10.

References Cited (Backward Citations)

FR2132797A1 Cited
US4100129A Cited
US4417042A Cited
US4528353A Cited
US4672003A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-09 1992-02-08 1992-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-09 1996-02-08 1996-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-09 2000-02-08 2000-08-09 $7700.00 Window Closed / Lapsed

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