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Process for preparing anionic acrylic latex compositions

Assignee: PPG Industries Ohio Inc
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Filing: 1987-04-06
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Granted: 1988-07-26
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Expires: 2007-04-06
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Abstract

Abstract Disclosed herein is an improved process for preparing anionic acrylic latex composition which contains copolymers containing effective amounts of acid groups and amino groups.

Inventors

  • 👤 Suryya K. Das

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:54
CPC Classifications
C; C08; C08F; C08F285/00

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 135 words
In an improved process for preparing an anionic acrylic latex composition by copolymerizing ethylenically unsaturated monomers which contain an acid group and an amino group under conditions of free-radical initiated addition polymerization in an aqueous medium in the presence of an anionic emulsifier, the improvement comprising: i. copolymerizing in an aqueous medium in the presence of a surfactant the monomer containing the acid group with another monomer which is substantially free of an amino group, followed by ii. raising the pH of the resultant copolymer by adding a base thereto in an amount sufficient to avoid coagulation of the latex composition in the presence of the amino group-containing monomer, followed by iii. copolymerizing in the same aqueous medium the monomer containing amino group with another copolymerizable monomer which is substantially free of a carboxyl group.
Claim 2
Dependent Claim 135 words
In an improved process for preparing an anionic acrylic latex composition by copolymerizing ethylenically unsaturated monomers which contain an acid group and an amino group under conditions of free-radical initiated addition polymerization in an aqueous medium in the presence of an anionic emulsifier, the improvement comprising: i. copolymerizing in an aqueous medium in the presence of a surfactant the monomer containing the acid group with another monomer which is substantially free of an amino group, followed by ii. raising the pH of the resultant copolymer by adding a base thereto in an amount sufficient to avoid coagulation of the latex composition in the presence of the amino group-containing monomer, followed by iii. copolymerizing in the same aqueous medium the monomer containing amino group with another copolymerizable monomer which is substantially free of a carboxyl group.
Claim 3
Dependent Claim 18 words
The proces of claim 1 wherein the acid group containing monomer is an acrylic acid or methacrylic acid.
Claim 4
Dependent Claim 17 words
The process of claim 1 wherein the base is ammonia, alkylamine, alkanolamine or an alkali metal hydroxide.
Claim 5
Dependent Claim 32 words
The process claim 1 wherein the amino group containing monomer is a water-soluble or a water-insoluble amino group containing monomer selected from the group consisting of tertiary-butylaminoethyl methacrylate, diethylaminoethyl methacrylate, dimethylaminoethyl methacrylate.

References Cited (Backward Citations)

US3356627A Cited
US3853803A Cited
US3957710A Cited
US4172177A Cited
US4339365A Cited
US4357440A Cited
US4440897A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-26 1992-01-25 1992-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-26 1996-01-25 1996-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-26 2000-01-25 2000-07-26 $7700.00 Window Closed / Lapsed

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