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Process for making a polymer matrix containing non-centrosymmetric crystals

Assignee: BP PLC
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Filing: 1987-05-19
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Granted: 1988-07-26
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Expires: 2007-05-19
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Abstract

Abstract A polymer matrix has grown therein in vitro and in situ non-centrosymmetric crystals of organic or inorganic compounds. The crystals are preferably orientated and may be used in electro-optical systems.

Inventors

  • 👤 Paul D. Calvert
  • 👤 Raymond M. Ellul
  • 👤 Brian D. Moyle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:52
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K3/00; C08K3/01; C08K5/16; C08K5/32; G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3615; Y; Y10; Y10S; Y10S117/00; Y10S117/903; Y10S117/904; Y10S117/918; Y10S117/919; Y10S359/00; Y10S359/90; Y10T; Y10T428/00; Y10T428/25

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 74 words
A process for producing a polymer matrix having grown therein in situ oriented, non-centrosymmetric crystals of organic or inorganic compounds, said process comprising dissolving the compound to be crystallised and the matrix polymer in a common solvent, then casting the solution into the desired shape on a substrate thereby allowing the compound to crystallise in situ in the matrix upon gradual evaporation of the solvent and finally subjecting the composite so formed to orientation.
Claim 2
Dependent Claim 74 words
A process for producing a polymer matrix having grown therein in situ oriented, non-centrosymmetric crystals of organic or inorganic compounds, said process comprising dissolving the compound to be crystallised and the matrix polymer in a common solvent, then casting the solution into the desired shape on a substrate thereby allowing the compound to crystallise in situ in the matrix upon gradual evaporation of the solvent and finally subjecting the composite so formed to orientation.
Claim 3
Dependent Claim 124 words
A process for producing a polymer matrix having grown therein in situ oriented, non-centrosymmetric crystals of organic or inorganic compounds, said process comprising dissolving a first compound and the matrix polymer in a common solvent, casting the solution into the desired shape on a substrate thereby allowing the first compound to crystallise in situ in the matrix, dipping the shape so formed into a solution of a second compound, which is also capable of forming non-centrosymmetric crystals thereby allowing crystals of said second compound to be formed in situ in the matrix polymer either by a reaction between the first and second compounds or by the displacement of the first compound by the second compound and finally subjecting the composite so formed to orientation.
Claim 4
Dependent Claim 124 words
A process for producing a polymer matrix having grown therein in situ oriented, non-centrosymmetric crystals of organic or inorganic compounds, said process comprising dissolving a first compound and the matrix polymer in a common solvent, casting the solution into the desired shape on a substrate thereby allowing the first compound to crystallise in situ in the matrix, dipping the shape so formed into a solution of a second compound, which is also capable of forming non-centrosymmetric crystals thereby allowing crystals of said second compound to be formed in situ in the matrix polymer either by a reaction between the first and second compounds or by the displacement of the first compound by the second compound and finally subjecting the composite so formed to orientation.
Claim 5
Dependent Claim 33 words
A process according to claim 1 wherein the crystals of the organic or inorganic compounds formed in situ are oriented in such a manner that all the crystals are substantially in parallel alignment.
Claim 6
Dependent Claim 77 words
A process according to claim 3 wherein the orientation of the crystals is achieved by (a) stretching the composite during cooling after formation thereof, or (b) cold-drawing the formed composite, (c) subjecting the formed composite to an appropriate electrical field optionally accompanied by or preceded by drawing, (d) crystallisation of the composite in a stationary or mobile temperature gradient, or (e) swelling oriented matrix polymers with a solution of the compound which is then allowed to crystallise.
Claim 7
Dependent Claim 33 words
A process according to claim 2 wherein the crystals of the organic or inorganic compounds formed in situ are oriented in such a manner that all the crystals are substantially in parallel alignment.

References Cited (Backward Citations)

US3764807A Cited
US4175152A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-26 1992-01-25 1992-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-26 1996-01-25 1996-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-26 2000-01-25 2000-07-26 $7700.00 Window Closed / Lapsed

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