US4759210A — Apparatus for gas-monitoring and method of conduc…

Claim 1

Independent Claim 149 words

Apparatus for monitoring a gas, which comprises a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity to trapping of gaseous species differs from such selectivity of the other means in said plurality, said plurality of trapping means being disposed for flow of said gas through each of said means simultaneously; in operative association with each of the trapping means, means for selectively effecting the release of trapped gaseous species therefrom; and a plurality of means for sensing any of said gaseous species released from said means for trapping, each of said sensing means being adapted so that its selectivity to sensing said gaseous species differs from such selectivity of the other sensing means, each of said sensing means in said plurality being disposed for contact with said gas issuing from each of the plurality of said means for trapping.

Claim 2

Dependent Claim 149 words

Apparatus for monitoring a gas, which comprises a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity to trapping of gaseous species differs from such selectivity of the other means in said plurality, said plurality of trapping means being disposed for flow of said gas through each of said means simultaneously; in operative association with each of the trapping means, means for selectively effecting the release of trapped gaseous species therefrom; and a plurality of means for sensing any of said gaseous species released from said means for trapping, each of said sensing means being adapted so that its selectivity to sensing said gaseous species differs from such selectivity of the other sensing means, each of said sensing means in said plurality being disposed for contact with said gas issuing from each of the plurality of said means for trapping.

Claim 3

Dependent Claim 36 words

Apparatus as defined in claim 1, wherein said means for trapping gaseous species comprises a sorbent mass which selectively traps and concentrates said gaseous species under normal operating conditions and desorbs said gaseous species when heated.

Claim 4

Dependent Claim 27 words

Apparatus as defined in claim 2, wherein the sorbent mass is activated charcoal, alumina, a zeolite molecular sieve, a metal, a silica gel, or a polymeric sorbent.

Claim 5

Dependent Claim 44 words

Apparatus as defined in claim 3, wherein the polymeric sorbent is a derivative of 2,6-diphenyl-p-phenylene oxide, a styrene divinyl benzene polymer, an ethyl vinyl or divinyl benzene polymer, a vinyl pyrrolidone polymer, a vinyl pyridine polymer, cross-linked polystyrene, polyacrylonitrile or a cross-linked acrylic ester.

Claim 6

Dependent Claim 20 words

Apparatus as defined in claim 1, wherein the means for trapping gaseous species is a tube containing a sorbent material.

Claim 7

Dependent Claim 14 words

Apparatus as defined in claim 5, wherein said tube is formed of fused silica.

Claim 8

Dependent Claim 51 words

Apparatus as defined in claim 1, wherein said means for selectively effecting the release of trapped gaseous species is a heater disposed sufficiently proximately of said means for trapping gaseous species so that when said heater is operative it causes release of said gaseous species from said means for trapping same.

Claim 9

Dependent Claim 45 words

Apparatus as defined in claim 1, wherein the means for trapping gaseous species comprises a tube and the means for selectively effecting release of trapped gaseous species is a thin film resistance heater coverirg at least a portion of the outer wall of said tube.

Claim 10

Dependent Claim 27 words

Apparatus as defined in claim 8, wherein said resistance heater includes a resistive ink coated on at least a portion of the outer wall of said tube.

Claim 11

Dependent Claim 36 words

Apparatus as defined in claim 1, wherein said means for sensing said gaseous species is a piezoelectric sensor, an organic semiconductor chemiresistor, a chemically sensitive field effect transistor, a metal oxide semiconductor, or an electrochemical cell.

Claim 12

Dependent Claim 22 words

Apparatus as defined in claim 10, wherein said piezoelectric sensor is a bulk wave piezoelectric sensor or a surface acoustic wave sensor.

Claim 13

Independent Claim 131 words

A method of monitoring a gas, which comprises simultaneously flowing said gas through a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity in trapping of gaseous species differs from such selectivity of the other means in said plurality; selectively subjecting each means of said plurality to conditions effecting release of any gaseous species trapped thereby while maintaining the other means of said plurality in a condition suitable for said selective trapping of gaseous species; contacting the gas issuing from each of said plurality of trapping means with each of a plurality of means for sensing said gaseous species, said sensing means being adapted so that its selectivity of sensing said gaseous species differs from such selectivity of the other sensing means.

Claim 14

Independent Claim 131 words

A method of monitoring a gas, which comprises simultaneously flowing said gas through a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity in trapping of gaseous species differs from such selectivity of the other means in said plurality; selectively subjecting each means of said plurality to conditions effecting release of any gaseous species trapped thereby while maintaining the other means of said plurality in a condition suitable for said selective trapping of gaseous species; contacting the gas issuing from each of said plurality of trapping means with each of a plurality of means for sensing said gaseous species, said sensing means being adapted so that its selectivity of sensing said gaseous species differs from such selectivity of the other sensing means.

Claim 15

Dependent Claim 44 words

A method as defined in claim 12, which further comprises contacting said gas with a sorbent mass included in each said means for trapping gaseous species, thereby to sorb in each said mass any gaseous species as to which the sorbent mass is selective.

Claim 16

Dependent Claim 28 words

A method as defined in claim 13, wherein the sorbent mass is activated charcoal, alumina, a zeolite molecular sieve, a metal, a silica gel, or a polymeric sorbent.

Claim 17

Dependent Claim 45 words

A method as defined in claim 14, wherein the polymeric sorbent is a derivative of 2,6-diphenyl-p-phenylene oxide, a styrene divinyl benzene polymer, an ethyl vinyl or divinyl benzene polymer, a vinyl pyrrolidone polymer, a vinyl pyridine polymer, cross-linked polystyrene, polyacrylonitrile or a cross-linked acrylic ester.

Claim 18

Dependent Claim 44 words

A method as defined in claim 12, which further comprises passing said gas through a plurality of means for trapping a gaseous species wherein each such means comprises a tube having at least a part of its inner wall coated with a sorbent mass.

Claim 19

Dependent Claim 15 words

A method as defined in claim 16, wherein said tube is formed of fused silica.

Claim 20

Dependent Claim 55 words

A method as defined in claim 12, which comprises subjecting each means for trapping gaseous species to an amount of heating sufficient to release said trapped gaseous species, the heating of said means being effected with a thin-film resistance heater disposed sufficiently proximately of said means for trapping gaseous substances as to effect said release.

Claim 21

Dependent Claim 39 words

A method as defined in claim 12, wherein said plurality of means for sensing said gaseous species comprises an array of sensors the selectivity of each sensor to said gaseous species differing from such selectivity of the other sensors.

Claim 22

Dependent Claim 33 words

A method as defined in claim 19, wherein each said sensor comprises a piezoelectric sensor, an organic semiconductor chemirestor, a chemically sensitive field effect transistor, a metal oxide semiconductor, or an electrochemical cell.

Claim 23

Dependent Claim 23 words

A method as defined in claim 20, wherein said piezoelectric sensor is a bulk wave piezoelectric sensor or a surface acoustic wave sensor.

Claim 24

Dependent Claim 24 words

Apparatus as defined in claim 1, which further comprises means for measuring a signal emitted by each of the plurality of said sensing means.

Claim 25

Dependent Claim 91 words

Apparatus as defined in claim 1, which further comprises means for measuring a signal emitted by each of the plurality of said sensing means, and control means which causes said measuring means to measure said signal just prior to contacting the sensing means with gas containing the output of one of said trapping means which has been subjected to conditions effecting release of any gaseous species trapped therein, and again causing said measuring means to measure the corresponding signal when the sensing means is contacted with said gas containing said output.

Claim 26

Dependent Claim 50 words

A method as defined in claim 12, which further comprises measuring a signal emitted by each of the plurality of said sensing means when the sensing means is contacted with the output of said trapping means which has been subjected to conditions effecting release of any gaseous species trapped therein.

Claim 27

Dependent Claim 68 words

A method as defined in claim 12, which further comprises, just prior to contacting said gas containing the output of one of said trapping means subjected to conditions effecting release of any trapped gaseous species, measuring a signal emitted by each of said sensing means, and then comparing the corresponding signal emitted by each of said sensing means when it is contacted with said gas containing said output.

Claim 28

Dependent Claim 147 words

Apparatus for monitoring a gas, which comprises an array of tubes containing a sorbent mass the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectively of the sorbent mass in each of the other tubes in said array, said array of tubes being disposed in substantially parallel relationship such that there is flow of said gas through each of said tubes simultaneously; a portion of the exterior of each of said tubes being coateed with a thin film resistance heater formed of a resistive ink; and an array of piezoelectric sensors, each of said sensors being adapted so that its selectively to sensing said gaseous species differs from such selectivity of the other sensors, each of said sensors in said array being disposed for contact with said gas issuing from each of the array of said tubes.

Claim 29

Dependent Claim 147 words

Apparatus for monitoring a gas, which comprises an array of tubes containing a sorbent mass the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectively of the sorbent mass in each of the other tubes in said array, said array of tubes being disposed in substantially parallel relationship such that there is flow of said gas through each of said tubes simultaneously; a portion of the exterior of each of said tubes being coateed with a thin film resistance heater formed of a resistive ink; and an array of piezoelectric sensors, each of said sensors being adapted so that its selectively to sensing said gaseous species differs from such selectivity of the other sensors, each of said sensors in said array being disposed for contact with said gas issuing from each of the array of said tubes.

Claim 30

Independent Claim 133 words

A method of monitoring a gas, which comprises simultaneously flowing said gas through an array of tubes containing sorbent mass, the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectivity of the sorbent mass in each of the other of said tubes; successively subjecting each of the tubes of said array to conditions effecting release of any gaseous species trapped thereby while maintaining the other tubes of said array in a condition suitable for said selective trapping of gaseous species; contacting the gas issuing from each of said array of tubes with each of an array of piezoelectric sensors, the selectivity of each said sensor to sensing said gaseous species differing from such selectivity of each of the other sensors in said array.

Claim 31

Independent Claim 133 words

A method of monitoring a gas, which comprises simultaneously flowing said gas through an array of tubes containing sorbent mass, the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectivity of the sorbent mass in each of the other of said tubes; successively subjecting each of the tubes of said array to conditions effecting release of any gaseous species trapped thereby while maintaining the other tubes of said array in a condition suitable for said selective trapping of gaseous species; contacting the gas issuing from each of said array of tubes with each of an array of piezoelectric sensors, the selectivity of each said sensor to sensing said gaseous species differing from such selectivity of each of the other sensors in said array.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1991-07-26	1992-01-25	1992-07-26	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1995-07-26	1996-01-25	1996-07-26	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1999-07-26	2000-01-25	2000-07-26	$7700.00	Window Closed / Lapsed

Apparatus for gas-monitoring and method of conducting same

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