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US4756874A Expired / Lapsed US ⏱️ 0.0 years remaining

Minimization of radioactive material deposition in water-cooled nuclear reactors

Assignee: General Electric Co
•
Filing: 1986-12-22
•
Granted: 1988-07-12
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Expires: 2006-12-22
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Abstract

Abstract In water-cooled nuclear reactors where zinc is added to the water to remove or lessen the accumulation of radioactive cobalt, radioactivity arising from the zinc itself as a result of neutron capture is lessened or eliminated entirely by modifying the isotopic composition of the zinc prior to its injection into the system. The modification of the isotopic composition consists of lowering the proportion of 64 Zn or removing this isotope entirely.

Inventors

  • 👤 Carl P. Ruiz
  • 👤 David M. Blaies

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 19:49
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/001; G21C; G21C19/00; G21C19/28; G21D; G21D1/00; G21D1/003; Y; Y02; Y02E; Y02E30/00; Y02E30/30; Y10; Y10S; Y10S376/00; Y10S376/90; Y10S376/904

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 51 words
In the method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor which comprises adding zinc ion to water entering said water-bearing vessel, the improvement in which said zinc ion contains a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 2
Dependent Claim 51 words
In the method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor which comprises adding zinc ion to water entering said water-bearing vessel, the improvement in which said zinc ion contains a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 3
Dependent Claim 23 words
A method in accordance with claim 1 in which the proportion of 64 Zn in said zinc ion is less than about 10%.
Claim 4
Dependent Claim 23 words
A method in accordance with claim 1 in which the proportion of 64 Zn in said zinc ion is less than about 1%.
Claim 5
Dependent Claim 18 words
A method in accordance with claim 1 in which said zinc ion is substantially devoid of 64 Zn.
Claim 6
Dependent Claim 21 words
A method in accordance with claim 1 in which said zinc ion is added by dissolving zinc oxide in said water.
Claim 7
Dependent Claim 33 words
A method in accordance with claim 5 in which the amount of zinc oxide dissolved is selected to achieve a concentration of about 1 to about 1,000 ppb zinc in said water-bearing vessel.
Claim 8
Dependent Claim 33 words
A method in accordance with claim 5 in which the amount of zinc oxide dissolved is selected to achieve a concentration of about 3 to about 100 ppb zinc in said water-bearing vessel.
Claim 9
Dependent Claim 33 words
A method in accordance with claim 5 in which said zinc oxide is dissolved from a member selected from the group consisting of a water-based slurry, a water-based paste and a water-based solution.
Claim 10
Independent Claim 52 words
A method for inhibiting the deposition of radioactive material in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a water-based zinc oxide paste to water entering said water-bearing vessel, the zinc in said paste containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 11
Independent Claim 52 words
A method for inhibiting the deposition of radioactive material in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a water-based zinc oxide paste to water entering said water-bearing vessel, the zinc in said paste containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 12
Dependent Claim 26 words
A method in accordance with claim 9 in which the amount of zinc oxide in said paste is from about 25% to about 95% by weight.
Claim 13
Dependent Claim 26 words
A method in accordance with claim 9 in which the amount of zinc oxide in said paste is from about 40% to about 80% by weight.
Claim 14
Independent Claim 54 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding an aqueous solution of zinc oxide to water entering said water-bearing vessel, the zinc in said zinc oxide containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 15
Independent Claim 54 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding an aqueous solution of zinc oxide to water entering said water-bearing vessel, the zinc in said zinc oxide containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 16
Dependent Claim 37 words
A method in accordance with claim 12 in which said aqueous solution is formed by passing a stream of water drawn from said water entering said water-bearing vessel through a receptacle containing solid zinc oxide retained therein.
Claim 17
Dependent Claim 20 words
A method in accordance with claim 13 in which said solid zinc oxide is a bed of zinc oxide particles.
Claim 18
Dependent Claim 17 words
A method in accordance with claim 14 in which said zinc oxide particles are sintered zinc oxide.
Claim 19
Independent Claim 55 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a slurry of zinc oxide in water to water entering said water-bearing vessel, the zinc in said zinc oxide containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 20
Independent Claim 55 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a slurry of zinc oxide in water to water entering said water-bearing vessel, the zinc in said zinc oxide containing a substantially lower proportion of the 64 Zn isotope than naturally occurring zinc.
Claim 21
Dependent Claim 25 words
A method in accordance with claim 16 in which the zinc oxide content of said slurry is from about 0.1% to about 20% by weight.
Claim 22
Dependent Claim 25 words
A method in accordance with claim 16 in which the zinc oxide content of said slurry is from about 1% to about 5% by weight.
Claim 23
Dependent Claim 19 words
A method in accordance with claim 16 in which said zinc oxide in said slurry is fumed zinc oxide.
Claim 24
Dependent Claim 40 words
A method in accordance with claim 16 in which the rate of addition of said slurry to said water is selected to produce a zinc content in the water of said water-bearing vessel of about 1 to about 1,000 ppb.
Claim 25
Dependent Claim 40 words
A method in accordance with claim 16 in which the rate of addition of said slurry to said water is selected to produce a zinc content in the water of said water-bearing vessel of about 3 to about 100 ppb.

References Cited (Backward Citations)

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US3699052A Cited
US3580934A Cited
US3755117A Cited
US3766023A Cited
DE2050152A1 Cited
US3839096A Cited
US3850767A Cited
US3804730A Cited
JPS5879196A Cited
JPH1093996A Cited
JPH1095290A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-12 1992-01-11 1992-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-12 1996-01-11 1996-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-12 2000-01-11 2000-07-12 $7700.00 Window Closed / Lapsed

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