Patent US4756353A successfully refreshed from Google Patents.
US4756353A
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Low rolling resistance tire tread
Assignee: Huels AG
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Filing: 1987-02-20
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Granted: 1988-07-12
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Expires: 2007-02-20
Abstract
Abstract Tire treads having (a) low heat buildup under dynamic stress and a low frictional resistance to rolling, (b) adequate damping and accordingly a high wet skid resistance, (c) high abrasion resistance and accordingly high wearing efficiency, are produced from vulcanizable compositions based on an elastomer component containing an isoprene polymer characterized by a high content of recurring units obtained by 1,2- and 3,4-polymerization of isoprene.
Inventors
- 👤 Karl-Heinz Nordsiek
- 👤 Helmut Schwesig
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 19:36
CPC Classifications
B; B60; B60C; B60C1/00; B60C1/0016; B29; B29D; B29D30/00; B29D30/06; B29D30/52; C; C08; C08L; C08L21/00; Y; Y02; Y02T; Y02T10/00; Y02T10/80; Y02T10/86; Y10; Y10S; Y10S152/00; Y10S152/905
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
389 words
Heat-vulcanizable tread strips for the production of pneumatic tire treads for motor vehicles, obtained from vulcanizable compositions consisting essentially of: an amorphous elastomer component which exhibits a Mooney viscosity of 30-130; 40-60% by weight of active, reinforcing filler which comprises one or more tread carbon blacks or a mixture of 80-95% by weight of one or several tread carbon blacks and 5-20% by weight of one or several active silicic acids treated with silane adhesion promoters; 0-20% by weight of plasticizer oil which comprises conventional aromatic, aliphatic and naphthenic hydrocarbons, based on the elastomer component, and an effective amount of a vulcanizing agent, wherein a. the elastomer component consists essentially of a mixture of blend components, said mixture of blend components consisting essentially of in percent by weight based on the total mixture, a.1.1 20-40% by weight of a polyisoprene I, a.1.2 20-80% by weight of a polybutadiene I, wherein the polyisoprene I and the polybutadiene I are present as a mixture of homopolymers or as blocks in a block copolymer, a.2.1 0-30% by weight of a polybutadiene II, a.2.2 0-50% by weight of an elastomer selected from the group consisting of 1,4-cis-IR and NR (polyisoprene II), and a.2.3 0-60% by weight of SBR with 10-25% by weight recurring units, obtained by polymerization of styrene, excluding styrene blocks; b. the elastomer component has a defo elasticity of 12-45 and a nonuniformity (U =Mw/Mn-1) of 0.8-5.5; c.1 the polyisoprene I, the polybutadiene I, and the block copolymer have been obtained by polymerization in an inert, organic solvent in the presence of an organolithium catalyst and a Lewis base from the group of the ethers, tertiary amines, and their mixtures as the cocatalyst; c.2 the polyisoprene I and the corresponding block in the block copolymer consist essentially of 55-85% by weight of recurring units obtained by 1,2- and 3,4-polymerization, and 15-45% by weight of recurring units obtained by 1,4-polymerization of isoprene; c.3 the polybutadiene I and the corresponding block in the block copolymer consist essentially of 40-70% by weight of recurring units obtained by 1,2-polymerization, and 30-60% by weight of recurring units obtained by 1,4-polymerization of 1,3-butadiene, c.4 the polybutadiene II is obtained by Ziegler polymerization; it consists essentially of ≦10% by weight of recurring units obtained by 1,2-polymerization and ≧90% by weight of recurring units obtained by 1,4-polymerization of 1,3-butadiene.
Claim 2
Dependent Claim
389 words
Heat-vulcanizable tread strips for the production of pneumatic tire treads for motor vehicles, obtained from vulcanizable compositions consisting essentially of: an amorphous elastomer component which exhibits a Mooney viscosity of 30-130; 40-60% by weight of active, reinforcing filler which comprises one or more tread carbon blacks or a mixture of 80-95% by weight of one or several tread carbon blacks and 5-20% by weight of one or several active silicic acids treated with silane adhesion promoters; 0-20% by weight of plasticizer oil which comprises conventional aromatic, aliphatic and naphthenic hydrocarbons, based on the elastomer component, and an effective amount of a vulcanizing agent, wherein a. the elastomer component consists essentially of a mixture of blend components, said mixture of blend components consisting essentially of in percent by weight based on the total mixture, a.1.1 20-40% by weight of a polyisoprene I, a.1.2 20-80% by weight of a polybutadiene I, wherein the polyisoprene I and the polybutadiene I are present as a mixture of homopolymers or as blocks in a block copolymer, a.2.1 0-30% by weight of a polybutadiene II, a.2.2 0-50% by weight of an elastomer selected from the group consisting of 1,4-cis-IR and NR (polyisoprene II), and a.2.3 0-60% by weight of SBR with 10-25% by weight recurring units, obtained by polymerization of styrene, excluding styrene blocks; b. the elastomer component has a defo elasticity of 12-45 and a nonuniformity (U =Mw/Mn-1) of 0.8-5.5; c.1 the polyisoprene I, the polybutadiene I, and the block copolymer have been obtained by polymerization in an inert, organic solvent in the presence of an organolithium catalyst and a Lewis base from the group of the ethers, tertiary amines, and their mixtures as the cocatalyst; c.2 the polyisoprene I and the corresponding block in the block copolymer consist essentially of 55-85% by weight of recurring units obtained by 1,2- and 3,4-polymerization, and 15-45% by weight of recurring units obtained by 1,4-polymerization of isoprene; c.3 the polybutadiene I and the corresponding block in the block copolymer consist essentially of 40-70% by weight of recurring units obtained by 1,2-polymerization, and 30-60% by weight of recurring units obtained by 1,4-polymerization of 1,3-butadiene, c.4 the polybutadiene II is obtained by Ziegler polymerization; it consists essentially of ≦10% by weight of recurring units obtained by 1,2-polymerization and ≧90% by weight of recurring units obtained by 1,4-polymerization of 1,3-butadiene.
Claim 3
Dependent Claim
81 words
Tread strip according to claim 1, wherein: d.1 the polyisoprene I and the corresponding block in the block copolymer consist essentially of 65-75% by weight of recurring units obtained by 1,2- and 3,4-polymerization, and 25-35% by weight of recurring units obtained by 1,4-polymerization of isoprene; d.2 the polybutadiene I and the corresponding block in the block copolymer consist essentially of 50-60% by weight of recurring units obtained by 1,2-polymerization, and 40-50% by weight of recurring units obtained by 1,4-polymerization of 1,3-butadiene.
Claim 4
Dependent Claim
13 words
A vulcanized tread obtained by vulcanizing a tread strip according to claim 1.
Claim 5
Dependent Claim
13 words
A vulcanized tread obtained by vulcanizing a tread strip according to claim 2.
Claim 6
Dependent Claim
24 words
A tread strip as defined by claim 1, wherein the elastomer component consists essentially of 66.7 parts polybutadiene I and 33.3 parts polyisoprene I.
Claim 7
Dependent Claim
23 words
A tire tread according to claim 1, wherein the elastomer component consists essentially of 75 parts polybutadiene I and 25 parts polyisoprene I.
Claim 8
Dependent Claim
21 words
A tread strip according to claim 1, wherein polyisoprene I and polybutadiene I are present as blocks in a block copolymer.
Claim 9
Dependent Claim
20 words
A tread strip according to claim 1, wherein polyisoprene I and polybutadiene I are present as a mixture of homopolymers.
Claim 10
Dependent Claim
19 words
A tread strip according to claim 8, wherein the polyisoprene I blend component has a Mooney viscosity of 60-110.
Claim 11
Dependent Claim
19 words
A tread strip according to claim 8, wherein the polybutadiene I blend component has a Mooney viscosity of 35-70.
Claim 12
Dependent Claim
19 words
A tread strip according to claim 7, wherein the block copolymer blend component has a Mooney viscosity of 40-100.
Claim 13
Dependent Claim
19 words
A tread strip according to claim 1, wherein the polyisoprene II blend component has a Mooney viscosity of 60-110.
Claim 14
Dependent Claim
20 words
A tread strip according to claim 1, wherein said elastomer component consists essentially of no more than four blend components.
Claim 15
Dependent Claim
20 words
A tread strip according to claim 1, wherein said elastomer component consists essentially of no more than three blend components.
Claim 16
Dependent Claim
26 words
A tread strip according to claim 1, wherein said elastomer component consists essentially of 33.3 parts polybutadiene I, 33.3 parts polyisoprene I and 33.3 parts NR.
Claim 17
Dependent Claim
26 words
A tread strip according to claim 1, wherein said elastomer component consists essentially of 50 parts polybutadiene I, 25 parts polyisoprene I and 25 parts NR.
Claim 18
Dependent Claim
23 words
A tread strip according to claim 1, wherein said elastomer component consists essentially of 60 parts polybutadiene I and 40 parts polyisoprene I.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-07-12 | 1992-01-11 | 1992-07-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-07-12 | 1996-01-11 | 1996-07-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-07-12 | 2000-01-11 | 2000-07-12 | $7700.00 | Window Closed / Lapsed |