Patent US4594537A successfully refreshed from Google Patents.
Patent US4752552A successfully refreshed from Google Patents.
US4752552A
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Photosolubilizable composition
Assignee: Fujifilm Holdings Corp
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Filing: 1987-08-12
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Granted: 1988-06-21
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Expires: 2007-08-12
Abstract
Abstract A photosolubilizable composition contains both a compound capable of producing an acid by irradiation with actinic rays and a compound which has at least one silyl ether or silyl ester group capable of being decomposed by an acid; optionally, a compound having at least one silyl ether group has at least one hydrophilic group, providing for increased solubility in a developing solution under the action of an acid, thus enhancing the photosensitivity and the development latitude of the composition.
Inventors
- 👤 Toshiaki Aoai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 16:38
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; G03F7/0755; G03F7/0758; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/115; Y10S430/117; Y10S430/12; Y10S430/121; Y10S430/126
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
300 words
A photosolubilizable composition containing a first compound capable of producing an acid by irradiation in admixture with a second compound having at least one silyl ether or silyl ester group capable of being decomposed by an acid, said second compound being selected from a Compound (a) and Compound (b), said first compound being present in an amount sufficient to increase the solubility in a developing solution of said second compound upon producing said acid, with the ratio of said first compound to the second compound being from 0.001/1 to 2/1, wherein said Compound (a) is a compound including at least one silyl ether group represented by formula (Ib): ##STR11## wherein R 12 , R 13 and R 14 each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, a halogen atom, or --OR 16 ; R 15 represents a divalent aliphatic or aromatic hydrocarbon residue; R 16 represents an alkyl group, an aryl group, or an aralkyl group; or R 15 and R 16 may combine with each other to form a part of an aliphatic or aromatic ring; n 1 represents a positive integer; and a 1 and b 1 each represents 0 to 1, and said Compound (b) is a compound including at least one silyl ester group represented by formula (IIb): ##STR12## wherein R 22 , R 23 and R 24 each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, or ##STR13## R 25 and R 26 each represents a divalent aliphatic or aromatic hydrocarbon residue; R 27 represents an alkyl group, an aryl group, or an aralkyl group; n 2 represents a positive integer; and a 2 and b 2 each represents 0 or 1.
Claim 2
Dependent Claim
300 words
A photosolubilizable composition containing a first compound capable of producing an acid by irradiation in admixture with a second compound having at least one silyl ether or silyl ester group capable of being decomposed by an acid, said second compound being selected from a Compound (a) and Compound (b), said first compound being present in an amount sufficient to increase the solubility in a developing solution of said second compound upon producing said acid, with the ratio of said first compound to the second compound being from 0.001/1 to 2/1, wherein said Compound (a) is a compound including at least one silyl ether group represented by formula (Ib): ##STR11## wherein R 12 , R 13 and R 14 each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, a halogen atom, or --OR 16 ; R 15 represents a divalent aliphatic or aromatic hydrocarbon residue; R 16 represents an alkyl group, an aryl group, or an aralkyl group; or R 15 and R 16 may combine with each other to form a part of an aliphatic or aromatic ring; n 1 represents a positive integer; and a 1 and b 1 each represents 0 to 1, and said Compound (b) is a compound including at least one silyl ester group represented by formula (IIb): ##STR12## wherein R 22 , R 23 and R 24 each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, or ##STR13## R 25 and R 26 each represents a divalent aliphatic or aromatic hydrocarbon residue; R 27 represents an alkyl group, an aryl group, or an aralkyl group; n 2 represents a positive integer; and a 2 and b 2 each represents 0 or 1.
Claim 3
Dependent Claim
32 words
A photosolubilizable composition as in claim 1, wherein said Compound (a) is a Compound (c) having at least one silyl ether group of said formula (Ib) and at least one hydrophilic group.
Claim 4
Dependent Claim
57 words
A photosolubilizable composition as in claim 2, wherein said at least one hydrophilic group is represented by one of the following formulae: ##STR14## wherein l 3 represents an integer of 1 to 4; m 3 and n 3 each represents an integer of 0 or more; and R 31 represents an alkyl group or a phenyl group.
Claim 5
Dependent Claim
24 words
A photosolubilizable composition as in claim 3, wherein Compound (c) includes the group --CH 2 CH 2 --O-- n .sbsb.3 as the hydrophilic group.
Claim 6
Dependent Claim
36 words
A photosolubilizable composition as in claim 1, wherein said first compound capable of producing an acid is orthoquinonediazidosulfonyl chloride, an s-triazine derivative substituted by a halomethyl group, or an oxadiazole derivative substituted by a halomethyl group.
Claim 7
Dependent Claim
36 words
A photosolubilizable composition as in claim 2, wherein said first compound capable of producing an acid is orthoquinonediazidosulfonyl chloride, an s-triazine derivative substituted by a halomethyl group, or an oxadiazole derivative substituted by a halomethyl group.
Claim 8
Dependent Claim
36 words
A photosolubilizable composition as in claim 3, wherein said first compound capable of producing an acid is orthoquinonediazidosulfonyl chloride, an s-triazine derivative substituted by a halomethyl group, or an oxadiazole derivative substituted by a halomethyl group.
Claim 9
Dependent Claim
36 words
A photosolubilizable composition as in claim 4, wherein said first compound capable of producing an acid is orthoquinonediazidosulfonyl chloride, an s-triazine derivative substituted by a halomethyl group, or an oxadiazole derivative substituted by a halomethyl group.
Claim 10
Dependent Claim
23 words
A photosolubilizable composition as in claim 1, wherein the ratio of the first compound to the second compound is from 0.02/1 to 0.8/1.
Claim 11
Dependent Claim
23 words
A photosolubilizable composition as in claim 2, wherein the ratio of the first compound to the second compound is from 0.02/1 to 0.8/1.
Claim 12
Dependent Claim
23 words
A photosolubilizable composition as in claim 5, wherein the ratio of the first compound to the second compound is from 0.02/1 to 0.8/1.
Claim 13
Dependent Claim
23 words
A photosolubilizable composition as in claim 6, wherein the ratio of the first compound to the second compound is from 0.02/1 to 0.8/1.
Claim 14
Dependent Claim
27 words
A photosolubilizable composition as in claim 1, wherein said second compound is a compound I including at least one silyl ether group represented by formula (I)-6: ##STR15##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-06-21 | 1991-12-21 | 1992-06-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-21 | 1995-12-21 | 1996-06-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-21 | 1999-12-21 | 2000-06-21 | $7700.00 | Window Closed / Lapsed |