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US4749773A
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Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
Assignee: Eastman Chemical Co
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Filing: 1987-07-27
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Granted: 1988-06-07
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Expires: 2007-07-27
Abstract
Abstract A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein a total of from 100 to about 800 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein R 1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical; A 1 is an unsubstituted or substituted phenylene radical; A 2 is an unsubstituted or substituted 1,4-phenylene radical; R 2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; R 3 is cyano or ##STR2## and R 4 is one of the substituents which R 3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals. The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
Inventors
- 👤 Max A. Weaver
- 👤 Wayne P. Pruett
- 👤 Samuel D. Hilbert
- 👤 Clarence A. Coates, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 19:20
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/06; C08G64/08; C08G64/12; C07; C07C; C07C255/00; C07C317/00; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/54; C08G63/68; C08G63/685; C08G63/6854; C08G63/6858; C08G64/045
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
124 words
A composition comprising molding grade condensation polymer having copolymerized therein a total of about 100 to 800 parts by weight per million parts by weight polymer of the residue of a methine compound or mixture of methine compounds having the formula ##STR28## wherein R 1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical; A 1 is an unsubstituted or substituted phenylene radical; A 2 is an unsubstituted or substituted 1,4-phenylene radical; R 2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; R 3 is cyano or ##STR29## and R 4 is one of the substituents which R 3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals.
Claim 2
Dependent Claim
124 words
A composition comprising molding grade condensation polymer having copolymerized therein a total of about 100 to 800 parts by weight per million parts by weight polymer of the residue of a methine compound or mixture of methine compounds having the formula ##STR28## wherein R 1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical; A 1 is an unsubstituted or substituted phenylene radical; A 2 is an unsubstituted or substituted 1,4-phenylene radical; R 2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; R 3 is cyano or ##STR29## and R 4 is one of the substituents which R 3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals.
Claim 3
Dependent Claim
68 words
The composition of claim 1 wherein the polymer is a linear polyester and the methine compound has the formula ##STR30## wherein R 1 is hydrogen or alkyl; R 3 is cyano or ##STR31## R 4 is one of the substituents which R 3 can represent or carbamoyl, alkanoyl, alkylsulfonyl, arylsulfonyl, phenyl or tolyl; and R 5 and R 6 each independently is hydrogen. alkyl, alkoxy, halogen or ##STR32##
Claim 4
Dependent Claim
43 words
A composition of claim 1 wherein the polymer is a linear polyester and the methine compound has the formula ##STR33## wherein R 1 is hydrogen or lower alkyl; and R 4 is cyano, lower alkoxycarbonyl, carbamoyl, lower alkylsulfonyl, phenylsulfonyl, tolylsulfonyl, phenyl or tolyl.
Claim 5
Dependent Claim
41 words
The composition of any of claims 1 to 3 wherein the polyester acid moiety is comprised of at least about 50 mol % terephthalic acid residue, and the glycol moiety at least about 50 mol % ethylene glycol or 1,4-cyclohexanedimethanol residue.
Claim 6
Dependent Claim
36 words
The composition of any of claims 1 to 3 wherein the polyester is comprised of from about 75 to 100 mol % terephthalic acid residue and from about 75 to 100 mol % ethylene glycol residue.
Claim 7
Dependent Claim
64 words
The composition of claim 1 wherein the polymer is unsaturated polyester having an acid moiety comprised of fumaric or maleic acid or mixtures thereof and up to about 60 mol % of one or a mixture of o-phthalic, isophthalic, or terephthalic acids, and having a glycol moiety comprised of one or a mixture of propylene glycol, neopentyl gylcol, 2,2,4-trimethyl-1,3-pentanediol, ethylene glycol or diethylene glycol.
Claim 8
Dependent Claim
51 words
The composition of claim 6 wherein the acid moiety is comprised of from about 75 to 100 mol % o-phthalic acid and maleic acid in a mole ratio of from about 1/2 to about 2/1, and the glycol moiety is comprised of from about 75 to 100 mol % propylene glycol.
Claim 9
Dependent Claim
14 words
The composition of claim 6 containing a curing amount of an ethylenically unsaturated monomer.
Claim 10
Dependent Claim
10 words
A cured, formed article of the composition of claim 8.
Claim 11
Dependent Claim
27 words
A fiber of the conposition of claim 1 dyed with from about 0.01 to about 5.0% by weight based on weight of fiber of a disperse dye.
Claim 12
Dependent Claim
9 words
A formed article of the composition of claim 1.
Claim 13
Dependent Claim
9 words
A formed article of the composition of claim 4.
Claim 14
Dependent Claim
9 words
A formed article of the composition of claim 5.
Claim 15
Dependent Claim
9 words
A formed article of the composition of claim 6.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-06-07 | 1991-12-07 | 1992-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-07 | 1995-12-07 | 1996-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-07 | 1999-12-07 | 2000-06-07 | $7700.00 | Window Closed / Lapsed |