US4749676A
Expired / Lapsed
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Process for the preparation of a crystalline, swellable sheet silicate of the saponite type
Assignee: Hoechst AG
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Filing: 1986-11-24
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Granted: 1988-06-07
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Expires: 2006-11-24
Abstract
Abstract A crystalline swellable sheet silicate of the saponite type, of the formula [Mg.sub.6 (Si.sub.8-x Al.sub.x)O.sub.20 (OH).sub.4 ].sup.x-.(x/z)M.sup.z+ n H 2 O in which x is a number which is less than 1.5 but at least 0.2, z is an integer from 1 to 3, M denotes a cation having the valency of z and n is a number less than 20, is prepared. For this purpose, an aqueous solution or suspension containing magnesium ions, a silica source, an alumina source and a sodium oxide source are combined. The atomic ratio of Mg/Si and Mg/Al used in this procedure correspond to the composition of the desired saponite. The atomic ration (Na-Al):(Mg+Si+3/2.Al) should be between x/5 and 1, Na denoting the amount of sodium atoms present in alkaline compounds. The pH of the reaction mixture should be at least 9.0. The crystals of the resulting synthetic saponite in the sodium form are separated off from the mother liquor and, if appropriate, treated with an aqueous solution or suspension of a salt having the cation M z+ , and, when cation exchange is complete, are separated off from the aqueous phase.
Inventors
- 👤 Thomas Blumenthal
- 👤 Hans-Jurgen Kalz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 15:53
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253; C01; C01B; C01B33/00; C01B33/20; C01B33/36; C01B33/38; C01B33/40
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
211 words
A process for the preparation of a crystalline, swellable synthetic sheet silicate having spaonite structure, of the formula [Mg.sub.6 (Si.sub.8-x Al.sub.x)O.sub.20 (OH).sub.4 ].sup.x-.(x/z)M.sup.z+ n H.sub.2 O in which x is a number which is less than 1.5 but at least 0.2, z is an integer from 1 to 3, M denotes a cation having a valency of z and n is a number less than 20, said process comprising the steps of: heating an aqueous solution or suspension containing magnesium ions to a temperature of 110°-250° C. under autogenous pressure, adding to the heated aqueous solution or suspension a silica source, an alumina source and a sodium oxide source; the amounts of magnesium ions, silica source, alumina source, and sodium oxide source being selected such that the Mg/Si and Mg/Al atomic ratios correspond to the composition of the desired trioctahedral silicate, the atomic ration (Na-Al):(Mg+Si+3/2.Al) is between s/5 and 1, Na denoting the amount of sodium atoms present in alkaline compounds, the molar ratio of sodium oxide/magnesium oxide is from 1 to 5, and the pH of the reaction mixture is at least 9.0; and the resulting crystals of the synthetic sheet silicate are separated off in the sodium form from the mother liquor, whereby M z+ is Na + .
Claim 2
Dependent Claim
211 words
A process for the preparation of a crystalline, swellable synthetic sheet silicate having spaonite structure, of the formula [Mg.sub.6 (Si.sub.8-x Al.sub.x)O.sub.20 (OH).sub.4 ].sup.x-.(x/z)M.sup.z+ n H.sub.2 O in which x is a number which is less than 1.5 but at least 0.2, z is an integer from 1 to 3, M denotes a cation having a valency of z and n is a number less than 20, said process comprising the steps of: heating an aqueous solution or suspension containing magnesium ions to a temperature of 110°-250° C. under autogenous pressure, adding to the heated aqueous solution or suspension a silica source, an alumina source and a sodium oxide source; the amounts of magnesium ions, silica source, alumina source, and sodium oxide source being selected such that the Mg/Si and Mg/Al atomic ratios correspond to the composition of the desired trioctahedral silicate, the atomic ration (Na-Al):(Mg+Si+3/2.Al) is between s/5 and 1, Na denoting the amount of sodium atoms present in alkaline compounds, the molar ratio of sodium oxide/magnesium oxide is from 1 to 5, and the pH of the reaction mixture is at least 9.0; and the resulting crystals of the synthetic sheet silicate are separated off in the sodium form from the mother liquor, whereby M z+ is Na + .
Claim 3
Dependent Claim
54 words
The process as claimed in claim 1, wherein the said resulting crystals separated off from the mother liquor are treated with an aqueous solution or suspension of a salt having a cation M z+ other than N + , and, after ion exchange is complete, the thus-treated crystals are separated from the aqueous phase.
Claim 4
Dependent Claim
74 words
The process as claimed in claim 1, wherein the silica source, the alumina source, and the sodium oxide source are added in the form of their aqueous solutions or suspensions, the resulting mixture, which is at a temperature in the range of 110° to 373° C., is maintained in this temperature range for a prolonged period of time, and the silica source is added before either the alumina source or the sodium oxide source.
Claim 5
Dependent Claim
16 words
The process as claimed in claim 1, wherein the synthetic sheet silicate is a synthetic saponite.
Claim 6
Dependent Claim
29 words
The process as claimed in claim 1, wherein said sodium oxide source comprises a mixture of sodium carbonate and sodium hydroxide in a molar ration of 1:5 to 1:3.
Claim 7
Dependent Claim
21 words
The process as claimed in claim 1, wherein the aqueous solution or suspension containing magnesium ions is heated to 150°-250° C.
Claim 8
Dependent Claim
25 words
The process as claimed in claim 3, wherein said resulting mixture is maintained at a temperature of 150°-250° C. for a prolonged period of time.
Claim 9
Dependent Claim
18 words
The process as cliamed in claim 1, wherein the reaction mixture contains at least 20 g/l of (silica+alumina).
References Cited (Backward Citations)
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