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US4745155A Expired / Lapsed US ⏱️ 0.0 years remaining

Emulsified crack or joint filler

Assignee: Owens Corning Fiberglas Technology Inc
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Filing: 1986-09-25
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Granted: 1988-05-17
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Expires: 2006-09-25
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Abstract

Abstract The present invention provides an aqueous emulsion joint and crack filler capable of passing the ASTM Specification 1190 for joint and crack fillers. The emulsion solids are the reaction product of asphalt, an extender oil, a mixture of elastomers, an acrylamide and a vinyl monomer. The preferred elastomer mixture includes a liquid rubber and at least one block copolymer of styrene and a conjugated diene, such as triblock and diblock copolymers of styrene and butadiene. The preferred emulsion medium is water containing a surfactant and an acrylamide polymer. The emulsion is poured at ambient temperature into a joint or crack, and cures rapidly to ensure minimal traffic interruption.

Inventors

  • 👤 Anthony V. Grossi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:07
CPC Classifications
C; C08; C08L; C08L95/00; C08L95/005

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 120 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising an aqueous emulsion of the reaction product of an asphalt having a penetration of about 210 to about 325, an extender oil, which is a hydrocarbon oil, a mixture of elastomers, said mixture including a liquid rubber and at least one block copolymer, said liquid rubber being a hydroxy terminated homopolymer or copolymer of a conjugated diene and said block copolymer being a copolymer of one or more conjugated dienes and one or more ethylenic monomers, a vinyl aromatic monomer and an acrylamide, and the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Specification D-1190.
Claim 2
Dependent Claim 120 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising an aqueous emulsion of the reaction product of an asphalt having a penetration of about 210 to about 325, an extender oil, which is a hydrocarbon oil, a mixture of elastomers, said mixture including a liquid rubber and at least one block copolymer, said liquid rubber being a hydroxy terminated homopolymer or copolymer of a conjugated diene and said block copolymer being a copolymer of one or more conjugated dienes and one or more ethylenic monomers, a vinyl aromatic monomer and an acrylamide, and the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Specification D-1190.
Claim 3
Dependent Claim 17 words
A composition as defined in claim 1, wherein the liquid rubber is a hydroxy-terminated homopolymer of butadiene.
Claim 4
Dependent Claim 24 words
A composition as defined in claim 1, wherein the mixture of elastomers includes at least one block copolymer of styrene and a conjugated diene.
Claim 5
Dependent Claim 44 words
A composition as defined in claim 1, wherein the mixture of elastomers includes a mixture of a triblock copolymer of styrene a butadiene and a diblock copolymer of styrene and butadiene, the amount of said diblock copolymer exceeding the amount of said triblock copolymer.
Claim 6
Dependent Claim 14 words
A composition as defined in claim 1, wherein the vinyl aromatic monomer is styrene.
Claim 7
Dependent Claim 112 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising the reaction product of: ______________________________________ Ingredient Weight % ______________________________________ Asphalt of Penetration 210-300 65-75 Extender Oil which is a 2-10 Hydrocarbon Oil Hydroxy-terminated Polymer 1-6 of a Conjugated Diene Block Copolymer of a 9-20 Conjugated Diene and a Vinyl Monomer Vinyl Monomer 5-10 Acrylamide 0.1-3 ______________________________________ reacted under reflex for an extended period at an elevated temperature and emulsified in a cationic emulsification medium comprising water, a surfactant and a high molecular weight acrylamide polymer, and the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the specification of ASTM Specification D-1190.
Claim 8
Dependent Claim 112 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising the reaction product of: ______________________________________ Ingredient Weight % ______________________________________ Asphalt of Penetration 210-300 65-75 Extender Oil which is a 2-10 Hydrocarbon Oil Hydroxy-terminated Polymer 1-6 of a Conjugated Diene Block Copolymer of a 9-20 Conjugated Diene and a Vinyl Monomer Vinyl Monomer 5-10 Acrylamide 0.1-3 ______________________________________ reacted under reflex for an extended period at an elevated temperature and emulsified in a cationic emulsification medium comprising water, a surfactant and a high molecular weight acrylamide polymer, and the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the specification of ASTM Specification D-1190.
Claim 9
Dependent Claim 17 words
A composition as defined in claim 6, wherein the hydroxy-terminated polymer is a hydroxy-terminated homopolymer of butadiene.
Claim 10
Dependent Claim 42 words
A composition as defined in claim 6, wherein the block copolymer is a mixture of about 2% to about 5% of a triblock copolymer of styrene and butadiene and about 7% to about 15% of a diblock copolymer of styrene and butadiene.
Claim 11
Independent Claim 151 words
The method of making an emulsified composition useful as a cold-pour crack and joint filler, said composition having an emulsion solids residue meeting ASTM Specification D-1190, comprising the steps of reacting an asphalt having a penetration of about 210-about 325, an extender oil which is a hydrocarbon oil, a liquid rubber which is a hydroxy-terminated polymer of a conjugated diene, at least one block copolymer of one or more conjugated dienes and one or more ethylenic monomers, a vinyl aromatic monomer and an acrylamide for about 20 to about 30 hours at a temperature of from about 300° F. to about 400° F. under reflux to obtain a reaction product, and emulsifying the reaction product in an emulsification medium of water, a surfactant and a high molecular weight acrylamide, the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Spefication D-1190.
Claim 12
Independent Claim 151 words
The method of making an emulsified composition useful as a cold-pour crack and joint filler, said composition having an emulsion solids residue meeting ASTM Specification D-1190, comprising the steps of reacting an asphalt having a penetration of about 210-about 325, an extender oil which is a hydrocarbon oil, a liquid rubber which is a hydroxy-terminated polymer of a conjugated diene, at least one block copolymer of one or more conjugated dienes and one or more ethylenic monomers, a vinyl aromatic monomer and an acrylamide for about 20 to about 30 hours at a temperature of from about 300° F. to about 400° F. under reflux to obtain a reaction product, and emulsifying the reaction product in an emulsification medium of water, a surfactant and a high molecular weight acrylamide, the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Spefication D-1190.
Claim 13
Dependent Claim 13 words
A method as defined in claim 9, wherein the conjugated diene is butadiene.
Claim 14
Dependent Claim 24 words
A method as defined in claim 9, wherein the at least one block copolymer is a block copolymer of styrene and a conjugated diene.
Claim 15
Dependent Claim 25 words
A method as defined in claim 11, wherein the at least one block copolymer is a mixture of a diblock copolymer and a triblock copolymer.
Claim 16
Dependent Claim 31 words
A composition as defined in claim 3, wherein the mixture of elastomers includes a mixture of a triblock copolymer of styrene and butadiene and a diblock copolymer of styrene and butadiene.
Claim 17
Dependent Claim 127 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising an aqueous emulsion of the reaction product of an asphalt, which has a penetration of from about 210 to 325 at 77° F., an extender oil which is a hydrocarbon oil high in saturates and low in aromatics, a mixture of elastomers wherein said mixture includes a liquid rubber, which is a hydroxy-terminated homopolymer or copolymer of a conjugated diene and wherein said mixture further includes a mixture of a triblock copolymer of styrene and butadiene and a diblock copolymer of styrene and butadiene, a vinyl aromatic monomer and an acrylamide, the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Specification D-1190.
Claim 18
Dependent Claim 127 words
An emulsified composition useful as a cold-pour crack and joint filler, said composition comprising an aqueous emulsion of the reaction product of an asphalt, which has a penetration of from about 210 to 325 at 77° F., an extender oil which is a hydrocarbon oil high in saturates and low in aromatics, a mixture of elastomers wherein said mixture includes a liquid rubber, which is a hydroxy-terminated homopolymer or copolymer of a conjugated diene and wherein said mixture further includes a mixture of a triblock copolymer of styrene and butadiene and a diblock copolymer of styrene and butadiene, a vinyl aromatic monomer and an acrylamide, the reactant materials being selected and employed in amounts so that the solid emulsion residue meets the requirements of ASTM Specification D-1190.
Claim 19
Dependent Claim 11 words
The composition of claim 14 wherein said ethylenic monomer is styrene.

References Cited (Backward Citations)

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US4316829A Cited
US4394481A Cited
US4419489A Cited
US4456633A Cited
US4507365A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-17 1991-11-16 1992-05-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-17 1995-11-16 1996-05-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-17 1999-11-16 2000-05-17 $7700.00 Window Closed / Lapsed

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