US4743624A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the production of flame-retardant polyurethane products
Assignee: Individual
•
Filing: 1987-06-11
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Granted: 1988-05-10
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Expires: 2007-06-11
Abstract
Abstract Flame-retardant polyurethane products are produced by mixing and reacting a basic salt-forming compound with an acidic salt-forming compound containing phosphorus and/or halogen compounds in a polyol and/or a polyisocyanate, then reacting the polyol and polyisocyanate. The flame-retardant polyurethane products may be used for thermal and sound insulation, as a coating agent, as an adhesive. for caulking, for cushioning and for molding useful objects.
Inventors
- 👤 David H. Blount
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 17:55
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K3/00; C08K3/01; C08K3/016; C08K3/10
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
327 words
The process of preparing a flame retardant foamed polyurethane products which process comprises of mixing and reacting: (A) A salt-forming basic compound selected from the group consisting of alkali metal compounds selected from the group consisting of compounds containing sodium, potassium, lithium, rubidium, cesium and mixtures thereof, except for alkali metal sulfate compounds, alkali metal halide compounds and alkali metal, alkaline earth metal compounds selected form the group consisting of compounds containing calcium, magnesium, barium, strontium and mixtures thereof, except for alkaline earth metal sulfate, alkaline earth metal halides and alkaline earth metal nitrates, metal compounds selected from the group consisting of compounds containing beryllium, copper, zinc, aluminum, tin, titanium, zirconium, lead, arsenic, antimony, bismuth, molybdenum, tungsten, manganese, iron, nickel, cobalt and mixtures thereof, except for metal sulfates, and metal halide and metal nitrates, ammonia compounds selected form the group consisting of ammonia, ammonium carbonate, amino compounds, amines, ammonia salts of organic acid, quaternary ammonium hydroxides, ammonium silicate and mixtures thereof except for ammonium salts of sulfuric acid, nitric acid and acid halides and mixtures thereof in the amount of 1 to 300 parts by weight; (B) salt-forming acidic compounds selected from the group consisting of phosphorous-containing compounds, halogen-containing compounds, and mixtures thereof in the amount of 1 to 100 parts by weight; (C) compound containing one or more active hydrogen that will react with a polyisocyanate compound in the amount of 1 to 200 parts by weight; (D) compounds containing at least two isocyanate groups in the amount of 50 to 100 parts by weight, the said mixing will be carried out in such a way that components (A) and (B) are reacted in (C) or (D) or in both (C) and (D) before (C) and (D) are reacted, (E) up to 50 percent by weight of an inert liquid, boiling in the range of -25° C. to 80° C., is included in the reaction mixture as blowing agent and the reaction proceeds with concomitant foaming.
Claim 2
Dependent Claim
327 words
The process of preparing a flame retardant foamed polyurethane products which process comprises of mixing and reacting: (A) A salt-forming basic compound selected from the group consisting of alkali metal compounds selected from the group consisting of compounds containing sodium, potassium, lithium, rubidium, cesium and mixtures thereof, except for alkali metal sulfate compounds, alkali metal halide compounds and alkali metal, alkaline earth metal compounds selected form the group consisting of compounds containing calcium, magnesium, barium, strontium and mixtures thereof, except for alkaline earth metal sulfate, alkaline earth metal halides and alkaline earth metal nitrates, metal compounds selected from the group consisting of compounds containing beryllium, copper, zinc, aluminum, tin, titanium, zirconium, lead, arsenic, antimony, bismuth, molybdenum, tungsten, manganese, iron, nickel, cobalt and mixtures thereof, except for metal sulfates, and metal halide and metal nitrates, ammonia compounds selected form the group consisting of ammonia, ammonium carbonate, amino compounds, amines, ammonia salts of organic acid, quaternary ammonium hydroxides, ammonium silicate and mixtures thereof except for ammonium salts of sulfuric acid, nitric acid and acid halides and mixtures thereof in the amount of 1 to 300 parts by weight; (B) salt-forming acidic compounds selected from the group consisting of phosphorous-containing compounds, halogen-containing compounds, and mixtures thereof in the amount of 1 to 100 parts by weight; (C) compound containing one or more active hydrogen that will react with a polyisocyanate compound in the amount of 1 to 200 parts by weight; (D) compounds containing at least two isocyanate groups in the amount of 50 to 100 parts by weight, the said mixing will be carried out in such a way that components (A) and (B) are reacted in (C) or (D) or in both (C) and (D) before (C) and (D) are reacted, (E) up to 50 percent by weight of an inert liquid, boiling in the range of -25° C. to 80° C., is included in the reaction mixture as blowing agent and the reaction proceeds with concomitant foaming.
Claim 3
Dependent Claim
48 words
The process of claim 1 wherein the compound containing at least one active hydrogen that will react with a polyisocyanate compound is selected from the group consisting of monohydroxy compounds, polyhydroxy compounds, amines, silicone polyols, amino compounds, compounds containing thiol groups, compounds containing carboxyl groups and mixtures thereof.
Claim 4
Dependent Claim
31 words
The process of claim 1 wherein the compounds containing at least two isocyanate groups are selected from the group consisting of aliphatic, cycloaliphatic, araliphatic, aromatic and heterocyclic polyisocyanates and mixtures thereof.
Claim 5
Dependent Claim
48 words
The process of claim 1 wherein the phosphorous-containing compound is selected from the group consisting of phosphoric acid, phosphinic acid, phosphonic acid, phosphonous acid, phosphinous acid, phosphine oxide, phosphorus trichloride, alkylchlorophosphines, organic acid phosphates, phosphorus oxychloride, monoaluminum phosphate, hydrogen-containing salts of phosphoric acid, hypophosphorous acid and mixtures thereof.
Claim 6
Dependent Claim
37 words
The process of claim 1 wherein the halogen-containing compound is selected from the group consisting of hydrochloric acid, hydrofluoric acid, hydrobromide acid, hydroiodic acid, chlorine, bromide, alkylating agents containing halides, hydrogen chloride, hydrogen bromide, and mixtures thereof.
Claim 7
Dependent Claim
20 words
The process of claim 1 wherein up to 10 percent by weight of activator is included in the reaction mixture.
Claim 8
Dependent Claim
21 words
The process of claim 1 wherein up to 20 percent by weight of foam stabilizer is included in the reaction mixture.
Claim 9
Dependent Claim
21 words
The process of claim 1, wherein up to 20 percent by weight of emulsifying agent is included in the reaction mixture.
Claim 10
Dependent Claim
20 words
The process of claim 1, wherein an inorganic or organic particulate or pulverulent material is included in the reaction mixture.
Claim 11
Dependent Claim
9 words
The product produced by the process of claim 1.
Claim 12
Dependent Claim
9 words
The product produced by the process of claim 10.
Claim 13
Dependent Claim
22 words
The process of claim 1 wherein up to 300 percent by weight of a modifying compound is added to the reaction mixture.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-05-10 | 1991-11-09 | 1992-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-05-10 | 1995-11-09 | 1996-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-05-10 | 1999-11-09 | 2000-05-10 | $7700.00 | Window Closed / Lapsed |