US4247657A
Expired / Lapsed
US
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Process for the production of alkali metal-cellulose-silicates and their reaction products
Assignee: Individual
•
Filing: 1980-01-16
•
Granted: 1981-01-27
•
Expires: 2000-01-16
Abstract
Abstract Small particles of cellulose-containing plants, fine granular oxidated, silicon compounds and an alkali metal hydroxide are mixed, then heated to 150° C. to 220° C. while agitating until the plant particles soften or melt, thereby producing an alkali metal cellulose silicate condensation product.
Inventors
- 👤 David Blount
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 23:44
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/64; C08G18/6484; C08B; C08B15/00; C08B15/05; C08B15/06; C08G18/6469; C08G77/00
Claims Analysis
Total Claims: 37
Claim 1
Independent Claim
235 words
The process for the production of polyisocyanate-cellulose-silicate products by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide; (b) heating the mixture at 150° C. to 270° C. while agitating for 5 to 60 minutes, thereby; (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 2 parts by weight of the alkali metal-cellulose-silicate condensation product as produced in step (c) and 1 to 4 parts by weight of an organic polyisocyanate, then; (e) agitating for 10 to 60 minutes at a temperature between 20° C. to 70° C., thereby; (f) producing a polyisocyanate-alkali meal-cellulose prepolymer; then (g) adding 10% to 100% by weight of a curing agent, based on the weight of the prepolymer, and selected from the group consisting of water, water containing 1% to 10% by weight of an amine catalyst, water containing 10% to 60% by weight of a polyhydroxyl compound, water containing 10% to 60% by weight of silica sol, water containing up to 5% by weight of an emulsifying agent, water containing 10% to 50% by weight of sodium silicate and mixtures thereof, is added to the said prepolymer while agitating at 20° C. to 80° C. for 5 to 20 minutes, thereby producing a cellular solid or solid polyisocyanate-cellulose-silicate product.
Claim 2
Dependent Claim
235 words
The process for the production of polyisocyanate-cellulose-silicate products by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide; (b) heating the mixture at 150° C. to 270° C. while agitating for 5 to 60 minutes, thereby; (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 2 parts by weight of the alkali metal-cellulose-silicate condensation product as produced in step (c) and 1 to 4 parts by weight of an organic polyisocyanate, then; (e) agitating for 10 to 60 minutes at a temperature between 20° C. to 70° C., thereby; (f) producing a polyisocyanate-alkali meal-cellulose prepolymer; then (g) adding 10% to 100% by weight of a curing agent, based on the weight of the prepolymer, and selected from the group consisting of water, water containing 1% to 10% by weight of an amine catalyst, water containing 10% to 60% by weight of a polyhydroxyl compound, water containing 10% to 60% by weight of silica sol, water containing up to 5% by weight of an emulsifying agent, water containing 10% to 50% by weight of sodium silicate and mixtures thereof, is added to the said prepolymer while agitating at 20° C. to 80° C. for 5 to 20 minutes, thereby producing a cellular solid or solid polyisocyanate-cellulose-silicate product.
Claim 3
Dependent Claim
115 words
The process of claim 1 wherein the organic polyisocyanate is selected from the group consisting of tolylene 2,4-diisocyanate, tolylene 2,6-diisocyanate and mixtures thereof, phosgenation products of condensates of aniline or anilines alkylsubstituted on the nucleus with aldehydes or ketones, solutions of distillation residues accumulating during the production of tolylene diisocyanate or diphenyl methane diisocyanate or hexamethylene diisocyanate in monomeric polyisocyanates or in organic solvents, mixtures of said distillation residues and modified polyisocyanates containing carbodiimide groups, allophanate groups, isocyanurate groups, urea groups, imide groups, amide groups or biuret groups, said modified polyisocyanates prepared by modifying organic polyisocyanates thermally or catalytically by air, water, urethanes, alcohols, amides, amines, carboxylic acids, or carboxylic acid anhydrides, and mixtures thereof.
Claim 4
Dependent Claim
12 words
The process of claim 1 wherein the organic polyisocyanate is tolylene diisocyanate.
Claim 5
Dependent Claim
9 words
The product produced by the process of claim 1.
Claim 6
Dependent Claim
128 words
The process for the production of polyurethane-cellulose-silicate cellular solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide, (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 6 minutes, thereby (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 1 to 3 parts by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), 1 to 3 parts by weight of a polyol, and 1 to 3 parts by weight of an organic polyisocyanate; the resultant mixture is allowed to react, thereby (e) reducing a polyurethane-cellulose-silicate cellular solid product.
Claim 7
Dependent Claim
128 words
The process for the production of polyurethane-cellulose-silicate cellular solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide, (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 6 minutes, thereby (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 1 to 3 parts by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), 1 to 3 parts by weight of a polyol, and 1 to 3 parts by weight of an organic polyisocyanate; the resultant mixture is allowed to react, thereby (e) reducing a polyurethane-cellulose-silicate cellular solid product.
Claim 8
Dependent Claim
9 words
The product produced by the process of claim 5.
Claim 9
Dependent Claim
29 words
The process of claim 5 wherein the organic polyisocyanate is selected from the group consisting of tolylene-2,4-diisocyanate, tolylene-2,6-diisocyanate and mixtures thereof and the phosgenation product of aniline-formaldehyde condensation products.
Claim 10
Dependent Claim
122 words
The process for the production of polyurethane-cellulose-silicate cellular solid or solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide, (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes, thereby (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 1 to 4 parts by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), and 3 parts by weight of an isocyanate-terminated polyurethane prepolymer; the resultant mixture is allowed to react, thereby (e) producing a polyurethane-cellulose-silicate cellular solid or solid product.
Claim 11
Dependent Claim
122 words
The process for the production of polyurethane-cellulose-silicate cellular solid or solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide, (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes, thereby (c) producing a water-soluable alkali metal-cellulose-silicate condensation product; (d) mixing 1 to 4 parts by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), and 3 parts by weight of an isocyanate-terminated polyurethane prepolymer; the resultant mixture is allowed to react, thereby (e) producing a polyurethane-cellulose-silicate cellular solid or solid product.
Claim 12
Dependent Claim
29 words
The process of claim 8 wherein the isocyanate-terminated polyurethane prepolymer is selected from the group consisting of an isocyanate-terminated polyester, isocyanate-terminated polyether, isocyanate-terminated polybutadiene, isocyanate-terminated polysulfide and mixtures thereof.
Claim 13
Dependent Claim
9 words
The product produced by the process of claim 8.
Claim 14
Dependent Claim
140 words
The process for the production of polyisocyanate-cellulose-silicate cellular solid or solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes, thereby (c) producing a water-soluble alkali metal-cellulose-silicate condensation product; (d) mixing 1 part by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), is added to water to produce an aqueous solution containing 20% to 60% solids, then mixed with 1 to 10 parts by weight of an organic polyisocyanate or polyisothiocyanate, and the resultant mixture is allowed to react, thereby (e) producing a polyisocyanate-cellulose-silicate cellular solid or solid product.
Claim 15
Dependent Claim
140 words
The process for the production of polyisocyanate-cellulose-silicate cellular solid or solid product by the following steps: (a) mixing 3 parts by weight of a cellulose-containing plant with 1 to 2 parts by weight of an oxidated silicon compound and 2 to 5 parts by weight of an alkali metal hydroxide (b) heating the mixture at 150° C. to 220° C. while agitating for 5 to 60 minutes, thereby (c) producing a water-soluble alkali metal-cellulose-silicate condensation product; (d) mixing 1 part by weight of the alkali metal-cellulose-silicate condensation product, as produced in step (c), is added to water to produce an aqueous solution containing 20% to 60% solids, then mixed with 1 to 10 parts by weight of an organic polyisocyanate or polyisothiocyanate, and the resultant mixture is allowed to react, thereby (e) producing a polyisocyanate-cellulose-silicate cellular solid or solid product.
Claim 16
Dependent Claim
21 words
The process of claim 11 wherein the polyisocyanate is selected from the group consisting of tolylene diisocyanate, polyphenyl-polymethylene-isocyanates and mixtures thereof.
Claim 17
Dependent Claim
9 words
The product produced by the process of claim 11.
Claim 18
Dependent Claim
24 words
The process of claim 1 wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide and mixtures thereof.
Claim 19
Dependent Claim
32 words
The process of claim 1 wherein the oxidated silicon compound is selected from the group consisting of silica, natural silicates containing free silicic acid radicals, sodium silicate, potassium silicate and mixtures thereof.
Claim 20
Dependent Claim
24 words
The process of claim 5 wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide and mixtures thereof.
Claim 21
Dependent Claim
32 words
The process of claim 5 wherein the oxidated silicon compound is selected from the group consisting of silica, natural silicates containing free silicic acid radicals, sodium silicate, potassium silicate and mixtures thereof.
Claim 22
Dependent Claim
24 words
The process of claim 8 wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide and mixtures thereof.
Claim 23
Dependent Claim
32 words
The process of claim 8 wherein the oxidated silicon compound is selected from the group consisting of silica, natural silicates containing free silicic acid radicals, sodium silicate, potassium silicate and mixtures thereof.
Claim 24
Dependent Claim
24 words
The process of claim 11 wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide and mixtures thereof.
Claim 25
Dependent Claim
32 words
The process of claim 11 wherein the oxidated silicon compound is selected from the group consisting of silica, natural silicates containing free silicic acid radicals, sodium silicate, potassium silicate and mixtures thereof.
Claim 26
Dependent Claim
24 words
The process of claim 1 wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, potassium hydroxide and mixture thereof.
Claim 27
Dependent Claim
32 words
The process of claim 1 wherein the oxidated silicon compound is selected from the group consisting of silica, natural silicates containing free silicic acid radicals, sodium silicate, potassium silicate and mixtures thereof.
Claim 28
Dependent Claim
29 words
The process of claim 1 wherein a chemically inert blowing agent, boiling within the range of from -25° C. to 80° C., is added to the polyisocyanate-alkali metal-cellulose prepolymer.
Claim 29
Dependent Claim
20 words
The process of claim 1 wherein the inorganic or organic particulate or pulverulent fillers are added to the reaction mixture.
Claim 30
Dependent Claim
12 words
The process of claim 1 wherein the reaction is accompanied by foaming.
Claim 31
Dependent Claim
28 words
The process of claim 5 wherein a chemically inert blowing agent, boiling within the range of from -25° C. to 80° C., is added to the reaction mixture.
Claim 32
Dependent Claim
28 words
The process of claim 8 wherein a chemically inert blowing agent, boiling within the range of from -25° C. to 80° C., is added to the reaction mixture.
Claim 33
Dependent Claim
12 words
The process of claim 8 wherein the reaction is accompanied by foaming.
Claim 34
Dependent Claim
25 words
The process of claim 5 wherein the polyisocyanate is selected from the group consisting of aliphatic, cycloaliphatic, araliphatic, aromatic and heteroryclic polyisocyanates and mixtures thereof.
Claim 35
Dependent Claim
28 words
The process of claim 11 wherein a chemically inert blowing agent, boiling within the range of from -25° C. to 80° C., is added to the reaction mixture.
Claim 36
Dependent Claim
39 words
The process of claim 1 wherein, up to 50% by weight, percentage based on the reaction mixture, of a chemically inert blowing agent, boiling within the range of from -25° to 80° C., is added to the reaction mixture.
Claim 37
Dependent Claim
12 words
The process of claim 1 wherein the reaction is accompanied by foaming.
References Cited (Backward Citations)
US2030738A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-27 | 1984-07-28 | 1985-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-27 | 1988-07-28 | 1989-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-27 | 1992-07-28 | 1993-01-27 | $7700.00 | Window Closed / Lapsed |