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US4741936A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminate preform for a multi-layer polyester bottle

Assignee: Toyo Seikan Group Holdings Ltd
•
Filing: 1986-12-02
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Granted: 1988-05-03
•
Expires: 2006-12-02
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Abstract

Abstract A process for the production of a multi-layer pipe to be used for formation of a bottle by draw-blow-forming, comprising forming by co-extrusion a pipe having inner and outer layers of a polyester composed mainly of ethylene terephthalate units and an intermediate layer of an oxygen-barrier resin interposed between the inner and outer layers, an adhesive resin layer is preferably interposed between every two adjacent layers. The co-extruded multi-layer pipe in the molten state so that the diameter of the pipe is sized is uniform. The process continues by cooling the outer portion of the molten multi-layer pipe by contact with water and simultaneously introducing an inert gas or an inert gas containing a water mist into the interior of the pipe to thereby cool the inner portion of the pipe and prevent oxidation in the pipe A. Multi-layer pipe prepared according to this process is excellent in the transparency and the draw-formability into a multi-layer drawn bottle.

Inventors

  • 👤 Shigezo Nohara
  • 👤 Takeshi Sugimoto
  • 👤 Kozaburo Sakano
  • 👤 Yoshimichi Ohkubo
  • 👤 Junichi Matsuo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 07:45
CPC Classifications
B; B29; B29C; B29C48/00; B29C48/03; B29C48/09; B29C48/16; B29C48/18; B29C48/21; B29C48/25; B29C48/30; B29C48/32; B29C48/335; B29C48/336; B29C48/3366; B29C48/88; B29C48/90; B29C48/908; B29C48/91; B29C48/911; B29C48/9115; B29C48/919; B29C49/00; B29C49/02; B29C49/04; B29C49/071; B29C49/22; B29D; B29D22/00; B29D22/003; B29D23/00; B32; B32B; B32B1/00; B32B1/08; B32B27/00; B32B27/06; B32B27/08; B32B27/30; B32B27/306; B32B27/36; B29C2949/00; B29C2949/07; B29C2949/072; B29C2949/0722; B29C2949/0723; B29C2949/0724; B29C2949/073; B29C2949/0731; B29C2949/0732; B29C2949/0733; B29C2949/076; B29C2949/0768; B29C2949/077; B29C2949/0772; B29C2949/0773; B29C2949/0777; B29C2949/078; B29C2949/081; B29C2949/0811; B29C2949/082; B29C2949/0861; B29C2949/0862; B29C2949/0872; B29C2949/30; B29C2949/3008; B29C2949/3012; B29C2949/3016; B29C2949/302; B29C2949/3024; B29C2949/3026; B29C2949/3028; B29C2949/303; B29C2949/3032; B29C2949/3034; B29C2949/3036; B29C2949/3038; B29C2949/3041; B29C2949/3042; B29C2949/3044; B29C2949/3046; B29C2949/3086; B29C2949/3088; B29C2949/3092; B29K; B29K2067/00; B29K2995/00; B29K2995/0037; B29K2995/0068; B29K2995/0069; B32B2307/00; B32B2307/70; B32B2307/724; B32B2307/7242; B32B2307/7244; B32B2310/00; B32B2310/04; B32B2310/0445; B32B2310/0463; B32B2310/0472; B32B2367/00; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379; Y10T428/1383; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/31504; Y10T428/31786; Y10T428/31797

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 126 words
A multi-layer polyester bottle formed of a laminate comprising (i) inner and outer layers of a polyester composed mainly of ethylene terephthalate units, (ii) an intermediate layer of an oxygen-barrier resin and (iii) an adhesive resin layer interposed between every two adjacent layers, said bottle being obtaining by (I) co-extruding said resin into a pipe comprising said laminate, said pipe having the thickness ratio of the inner polyester layer to the outer polyester layer of from 1/1.1 to 1/5, (II) solidifying the extruded pipe by cooling, (III) cutting the solidified pipe into a predetermined size, (IV) forming a closed bottom on one end of the cut pipe, (V) heating the obtained preform at a drawing temperature and (VI) biaxially stretch-blow-forming the heated preform into the bottle.
Claim 2
Dependent Claim 126 words
A multi-layer polyester bottle formed of a laminate comprising (i) inner and outer layers of a polyester composed mainly of ethylene terephthalate units, (ii) an intermediate layer of an oxygen-barrier resin and (iii) an adhesive resin layer interposed between every two adjacent layers, said bottle being obtaining by (I) co-extruding said resin into a pipe comprising said laminate, said pipe having the thickness ratio of the inner polyester layer to the outer polyester layer of from 1/1.1 to 1/5, (II) solidifying the extruded pipe by cooling, (III) cutting the solidified pipe into a predetermined size, (IV) forming a closed bottom on one end of the cut pipe, (V) heating the obtained preform at a drawing temperature and (VI) biaxially stretch-blow-forming the heated preform into the bottle.
Claim 3
Dependent Claim 25 words
A vessel according to claim 1, wherein the thickness ratio of the inner polyester layer to the outer polyester layer is from 1/2 to 1/3.
Claim 4
Dependent Claim 33 words
A vessel according to claim 1, wherein said adhesive layer is from a group consisting of a copolyester type adhesive, a polyester-ether type adhesive, an epoxy-modifified thermoplastic resin and an acid-modified thermoplastic resin.
Claim 5
Dependent Claim 24 words
A vessel according to claim 1, wherein the thickness ratio of the outer polyester layer to the adhesive layer is from 5/1 to 100/1.
Claim 6
Dependent Claim 16 words
A vessel according to claim 1, wherein the inner and outer layers are polyethylene terephthalate (PET).
Claim 7
Dependent Claim 15 words
A vessel according to claim 1, wherein the oxygen-barrier resin is an ethylene/vinyl alcohol copolymer.
Claim 8
Dependent Claim 31 words
A vessel according to claim 6, wherein the ethylene/vinyl alcohol copolymer is one having an ethylene content of 15 to 50 mole % and a saponification degree of at least 96%.
Claim 9
Dependent Claim 31 words
A vessel according to claim 6, wherein the ethylene/vinyl alcohol copolymer is one having an ethylene content of 25 to 45 mole % and a saponification degree of at least 90%.

References Cited (Backward Citations)

US4398642A Cited
US4436778A Cited
US4528219A Cited
US4451512A Cited
US4646925A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-03 1991-11-02 1992-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-03 1995-11-02 1996-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-03 1999-11-02 2000-05-03 $7700.00 Window Closed / Lapsed

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