Multi-layer plastic laminate structure

Claim 2

A multi-layer plastic structure comprising a layer of a polyester composed mainly of ethylene terephthalate units or butylene terephthalate units and a gas barrier layer containing an olefin-vinyl alcohol copolymer, said two layers being laminated together through a layer of a thermoplastic resin adhesive containing recurring ester groups and recurring amide groups wherein said ester groups are at a concentration of 53-990 millimoles per 100 g of the resin and said amide groups are at a concentration of 45 to 840 millimoles per 100 g. of the resin.

Claim 3

A hollow-formed vessel composed of a multi-layer plastic structure as set forth in claim 1.

Claim 4

A sheet-formed vessel composed of a multi-layer plastic structure as set forth in claim 1.

Claim 5

A multi-layer plastic structure as set forth in claim 1, wherein the thermoplastic layer adhesive contains in the polymer chain ester groups at a concentration of 89 to 800 millimoles per 100 g of the resin and amide groups at a concentration of 89 to 800 millimoles per 100 g of the resin.

Claim 6

A multi-layer plastic structure as set forth in claim 1, wherein the ratio of the thickness of the polyester layer to the gas barrier layer is in the range of from 200/1 to 5/1 and wherein the thickness ratio of the polyester layer to the adhesive layer is in the range of from 150/1 to 5/1.

Claim 7

A multi-layer plastic structure as set forth in claim 1, wherein the thermoplastic resin adhesive has a melting point or flow-initiating temperature of 100° to 280° C.

Claim 8

A multi-layer plastic structure as set forth in claim 1, wherein the thermoplastic resin adhesive is a polyester-amide.

Claim 9

A multi-layer plastic structure as set forth in claim 7, wherein the polyester-amide comprises recurring units represented by the following formula: --CO--R.sup.1 --CONH--R.sup.2 --NHCO--R.sup.1 --COOR.sup.3 O--(1) wherein R 1 stands for a phenylene group or alkylene group, and R 2 and R 3 each stand for an alkylene group.

Claim 10

A multi-layer plastic structure as set forth in claim 7, wherein the polyester-amide comprises recurring units represented by the following formula: --O--R.sup.4 --CONH--R.sup.5 --CO-- (2) wherein R 4 and R 5 each stand for an alkylene group or aralkylene group.

Claim 11

A multi-layer plastic structure as set forth in claim 7, wherein the polyester-amide comprises at least one recurring unit represented by the following formula: --CO--R.sup.1 --COO--R.sup.3 --O-- (3) wherein R 1 stands for a phenylene group or alkylene group, and R 3 stands for an alkylene group, and at least one recurring unit selected from the group consisting of units of the following formula: --NH--R.sup.2 --NHCO--R.sup.6 --CO-- (4) and --NH--R.sup.5 --CO-- (5) wherein R 2 stands for an alkylene group, R 6 stands for a phenylene group or alkylene group, and R 5 stands for an alkylene group or aralkylene group.

Claim 12

A multi-layer plastic structure as set forth in claim 7 wherein the polyester-amide has a melting point or flow-initiating temperature of from 150° to 240° C. and has an intrinsic viscosity of at least 0.01 l/g as measured at a temperature of 30° C. in a mixed solvent comprising phenol and tetrachloroethane at a weight ratio of 50/50.

Claim 13

A multi-layer plastic structure as set forth in claim 1, wherein the thermoplastic resin adhesive is a blend or polyester-polyamide a block copolymer containing a polyester and a polyamide at a weight ratio of from 10/90 to 90/10.

Claim 14

A multi-layer plastic structure as set forth in claim 12 wherein the polyester is at least one thermoplastic copolyester which is the reaction product of a diol component and a dicarboxylic acid component wherein at least 50 mole% of the diol component is ethylene glycol or 1,4-butane diol, at least 50 mole% of the dicarboxylic acid component is terephthalic acid and at least 1 mole% of the total of the diol component and the dicarboxylic acid component is other than terephthalic acid, ethylene glycol and 1,4-butane diol; and the polyamide is at least one linear aliphatic homopolyamide or copolyamide having 3 to 30 amide groups on the average per 100 carbon atoms.

Claim 15

A multi-layer plastic structure as set forth in claim 1, which is a five-layer structure comprised of outer layers of the polyester, an inner layer of the gas barrier layer and the adhesive layer between each of said outer layers and said inner layer.

Claim 16

A multi-layer plastic structure as set forth in claim 14, wherein the ratio of the thickness of the polyester layer to the gas barrier layer is in the range of from 200/1 to 5/1 and wherein the thickness ratio of the polyester layer to the adhesive layer is in the range of from 150/1 to 5/1.