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Linear polyethylene, fluorocarbon polymer and polyalkylsiloxane compositions, and improved method of film extrusion using same

Assignee: Mobil Oil AS
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Filing: 1986-08-29
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Granted: 1988-04-26
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Expires: 2006-08-29
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Abstract

Abstract The extrudability of linear polymers of ethylene such as low density copolymers of ethylene and C4-C10 olefins (LLDPE) into thin films is improved by adding small amounts, e.g. 250 to 1000 ppm of each of a fluorocarbon polymer, e.g. polyvinylidene fluoride, and of a polyalkylsiloxane, e.g. poly(methyl-octyl-siloxane), to reduce melt fracture, head pressure and extruder power.

Inventors

  • 👤 Shaw-Chang Chu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:04
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0807; C08L23/0815; C08L2205/00; C08L2205/02; C08L2205/03; C08L2205/035; C08L27/00; C08L27/02; C08L27/12; C08L27/16; C08L83/00; C08L83/04

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 124 words
A method of extruding a linear polyethylene polymer composition through a film extruder in which the improvement comprises incorporating 0.01 to 0.5 weight percent of said composition of a fluorocarbon polymer having a fluorine to carbon ratio of at least 1:2 which is fluid at temperatures of between 120° C. and 300° C.; and 0.01 to 0.5 weight percent of said composition of a polyalkylsiloxane consisting entirely of methyl-higher alkyl siloxane units or consisting of a major proportion of methyl-higher alkyl siloxane units and a minor proportion of other siloxane units, in which the fluorocarbon polymer and the polyalkylsiloxane are present in amounts to reduce melt fracture, reduce head pressure and reduce extruder power compared to extrusion without the fluorocarbon polymer and the polyalkylsiloxane.
Claim 2
Independent Claim 124 words
A method of extruding a linear polyethylene polymer composition through a film extruder in which the improvement comprises incorporating 0.01 to 0.5 weight percent of said composition of a fluorocarbon polymer having a fluorine to carbon ratio of at least 1:2 which is fluid at temperatures of between 120° C. and 300° C.; and 0.01 to 0.5 weight percent of said composition of a polyalkylsiloxane consisting entirely of methyl-higher alkyl siloxane units or consisting of a major proportion of methyl-higher alkyl siloxane units and a minor proportion of other siloxane units, in which the fluorocarbon polymer and the polyalkylsiloxane are present in amounts to reduce melt fracture, reduce head pressure and reduce extruder power compared to extrusion without the fluorocarbon polymer and the polyalkylsiloxane.
Claim 3
Dependent Claim 32 words
The method claim 1 in which said linear polyethylene polymer is a copolymer of ethylene and a higher olefin containing 4 to 10 carbon atoms, having a density of 0.90 to 0.94.
Claim 4
Dependent Claim 24 words
The method of claim 1 in which said linear polyethylene is a copolymer of ethylene and butene having a density of 0.90 and 0.94.
Claim 5
Dependent Claim 24 words
The method of claim 1 in which said linear polyethylene is a copolymer of ethylene and hexene having a density of 0.90 and 0.94.
Claim 6
Dependent Claim 24 words
The method of claim 1 in which said linear polyethylene is a copolymer of ethylene and octene having a density of 0.90 and 0.94.
Claim 7
Dependent Claim 13 words
The method of claim 1 in which said fluorocarbon polymer is polyvinylidene fluoride.
Claim 8
Dependent Claim 33 words
The method of claim 6 in which said linear polyethylene polymer is a copolymer of ethylene and a higher olefin containing 4 to 10 carbon atoms, having a density of 0.90 and 0.94.
Claim 9
Dependent Claim 13 words
The method of claim 4 in which said fluorocarbon polymer is polyvinylidene fluoride.
Claim 10
Dependent Claim 31 words
The method of claim 1 in which said fluorocarbon polymer comprises 0.01 to 0.05 weight percent of the composition and said polyalkylsiloxane comprises 0.01 and 0.05 weight percent of the composition.

References Cited (Backward Citations)

CA655293A Cited
US2888419A Cited
US4076698A Cited
US4076698B1 Cited
GB934468A Cited
US3125547A Cited
US3865897A Cited
US3929708A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-26 1991-10-26 1992-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-26 1995-10-26 1996-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-26 1999-10-26 2000-04-26 $7700.00 Window Closed / Lapsed

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