US4738207A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Non-polluting method of burning fuel for heat and CO2
Assignee: Individual
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Filing: 1987-01-06
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Granted: 1988-04-19
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Expires: 2007-01-06
Abstract
Abstract A non-polluting method of, and apparatus for, burning fuel to produce heat and a CO 2 -rich hot flue gas stream is described. Fuel (e.g., coal, oil, gas, wood, inter alia) is passed into a gasifier bed (12) containing particles of calcium sulfate and, optionally, calcium oxide. Bed 12 is fluidized by product gas containing an oxygen-transfer mediator (or source thereof) such as hydrogen, and fuel is partially oxidized to gas-phase products including CO and CO 2 at a temperature above the carbonation temperature of calcium oxide, calcium sulfate being reduced to calcium sulfide. The gas-phase products are passed into the base of a combustion bed (28) containing particles of calcium sulfate in the presence of an oxygen-transfer mediator and CO is oxidized to CO 2 at a temperature above the carbonation temperature of calcium oxide. Calcium sulfide-containing particles from the gasifier and combustion beds (12 and 28) are fluidized by an oxidizing gas (e.g. air) in respective oxidation beds (42,45) and CaS is exothermically oxidized to CaSO 4 for re-use. Preferably the particles circulate from the gasifier bed (12) to a first oxidation bed (42), then to the combustion bed (28), a second oxidation bed (45) and back to the gasifier bed (12) via underflow weirs connecting the beds. The gas from each bed is at the temperature of the respective bed (e.g. 850° to 1000° C.) and is used for steam raising, preheating air, etc.
Inventors
- 👤 Gerald Moss
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:34
CPC Classifications
F; F23; F23C; F23C10/00; F23C10/002; B; B01; B01J; B01J8/00; B01J8/18; B01J8/24; B01J8/26; C; C01; C01B; C01B32/00; C01B32/50; F23C6/00; F23C6/04; Y; Y02; Y02P; Y02P20/00; Y02P20/10; Y02P20/129
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
208 words
A non-polluting method of combusting a carbon-containing fuel to produce heat and a CO 2 -rich gas comprising the steps of: (a) passing the fuel into a first conversion bed (CB1) containing particles comprising calcium sulfate at an elevated reaction temperature above the CO 2 --CaCO 3 equilibrium temperature, the bed being fluidized by an upwardly-passing gas containing an oxygen-transfer mediator which mediates the transfer of oxygen from calcium sulfate to the fuel so that at least some of the fuel is converted to at least partially oxidised gas-phase products at substantially the elevated temperature of the bed and calcium sulfate is reduced to calcium sulfide with substantially no liberation of sulfur moieties; and (b) circulating at least some of the said gas-phase products to the base of a second fluidized conversion bed (CB2) containing particles comprising calcium sulfate at an elevated reaction temperature above the CO 2 --CaCO 3 equilibrium temperature, said gas phase products passing upwardly through said second conversion bed and fluidizing particles therein in the presence of an oxygen-transfer mediator so that carbon monoxide is converted to CO 2 at substantially the elevated reaction temperature of the second bed and calcium sulfate is reduced to calcium sulfide with substantially no liberation of sulfur moieties.
Claim 2
Dependent Claim
208 words
A non-polluting method of combusting a carbon-containing fuel to produce heat and a CO 2 -rich gas comprising the steps of: (a) passing the fuel into a first conversion bed (CB1) containing particles comprising calcium sulfate at an elevated reaction temperature above the CO 2 --CaCO 3 equilibrium temperature, the bed being fluidized by an upwardly-passing gas containing an oxygen-transfer mediator which mediates the transfer of oxygen from calcium sulfate to the fuel so that at least some of the fuel is converted to at least partially oxidised gas-phase products at substantially the elevated temperature of the bed and calcium sulfate is reduced to calcium sulfide with substantially no liberation of sulfur moieties; and (b) circulating at least some of the said gas-phase products to the base of a second fluidized conversion bed (CB2) containing particles comprising calcium sulfate at an elevated reaction temperature above the CO 2 --CaCO 3 equilibrium temperature, said gas phase products passing upwardly through said second conversion bed and fluidizing particles therein in the presence of an oxygen-transfer mediator so that carbon monoxide is converted to CO 2 at substantially the elevated reaction temperature of the second bed and calcium sulfate is reduced to calcium sulfide with substantially no liberation of sulfur moieties.
Claim 3
Dependent Claim
50 words
A method as in claim 1 in which the said gas-phase products from the first conversion bed contain oxygen-transfer mediator, and a portion of said products is circulated to the base of the first conversion bed and constitutes at least part of the upwardly-passing gas which fluidizes the first bed.
Claim 4
Dependent Claim
19 words
A method as in claim 1 wherein the upwardly-passing gas which fluidizes the first conversion bed contains water vapour.
Claim 5
Dependent Claim
20 words
A method as in claim 1 in which the upwardly-passing gas which fluidizes the second conversion bed contains water vapour.
Claim 6
Dependent Claim
54 words
A method as in claim 1 in which CaS-containing particles are circulated from the first bed to an oxidizing bed (OB1) wherein they are fluidized by an oxygen-containing gas and CaS is thereby converted to CaSO 4 at an elevated temperature, particles containing CaSO 4 being returned directly and/or indirectly to the first bed.
Claim 7
Dependent Claim
43 words
A method as in claim 5 in which the amount of oxygen in the oxygen-containing gas is in excess of that required for conversion of CaS to CaSO 4 whereby conversion of CaS to CaO with liberation of sulfur moieties is substantially suppressed.
Claim 8
Dependent Claim
36 words
A method as in claim 5 in which at least some of the CaSO 4 -containing particles from the oxidizing bed are circulated to the second bed for use in converting CO to CO 2 .
Claim 9
Dependent Claim
18 words
A method as in claim 5 in which heat is recovered from oxygen-depleted gas leaving the oxidizing bed.
Claim 10
Dependent Claim
56 words
A method as in claim 1 in which CaS-containing particles are circulated from the second conversion bed (CB2) to an oxidizing bed (OB2) wherein they are fluidized by an oxygen-containing gas and CaS is thereby converted to CaSO 4 at an elevated temperature, particles containing CaSO 4 being returned directly and/or indirectly to the second bed.
Claim 11
Dependent Claim
43 words
A method as in claim 9 in which the amount of oxygen in the oxygen-containing gas is in excess of that required for conversion of CaS to CaSO 4 whereby conversion of CaS to CaO with liberation of sulfur moieties is substantially suppressed.
Claim 12
Dependent Claim
39 words
A method as in claim 9 in which at least some of the CaSO 4 -containing particles from the oxidizing bed are circulated to the second conversion bed for use in converting fuel to at least partially-oxidized gas-phase products.
Claim 13
Dependent Claim
19 words
A method as in claim 9 in which heat is recovered from oxygen-depleted gas leaving the oxidizing bed (OB2).
Claim 14
Dependent Claim
68 words
A method as in claim 9 in which particles are circulated substantially continuously or intermittently in a circuit comprising, in series, the first conversion bed (CB1), a first oxidizing bed (OB1) wherein they are fluidized by an oxygen-containing gas and CaS is thereby converted to CaSO 4 at an elevated temperature, the second conversion bed (CB2), the said (second) oxidizing bed OB2, and the first conversion bed (CB1).
Claim 15
Dependent Claim
27 words
A method as in claim 1 in which particles are added to at least one of the beds to maintain the chemical activity of the particles therein.
Claim 16
Dependent Claim
13 words
A method as in claim 14 in which said particles comprise calcium carbonate.
Claim 17
Dependent Claim
25 words
A method as in claim 14 in which a portion of the particles in the beds is discarded to maintain the amount of particles therein.
Claim 18
Dependent Claim
34 words
A method as in claim 1 in which the particles include particles comprising CaO or a mixed compound comprising CaO to fix sulfur from the fuel as a solid compound comprising calcium and sulfur.
Claim 19
Dependent Claim
63 words
A method as in claim 17 comprising circulating a portion of the particles to a regenerating bed wherein the particles are contacted with a regenerating gas to convert the said solid compound comprising calcium and sulfur to calcium oxide with the liberation of sulfur as sulfur moieties and returning at least some of the regenerated particles to at least one of the beds.
Claim 20
Dependent Claim
24 words
A method as in claim 1 comprising passing the gas-phase products from the first conversion bed in indirect heat-exchange relationship with a heat-recovery fluid.
Claim 21
Dependent Claim
27 words
A method as in claim 1 comprising passing the CO 2 -rich gas from the second conversion bed in indirect heat exchange relationship with a heat-recovery fluid.
Claim 22
Dependent Claim
12 words
A CO 2 -rich gas produced by the method of claim 1.
Claim 23
Dependent Claim
140 words
Apparatus for combusting a carbon-containing fuel to produce heat and a CO 2 -rich gas comprising means defining a first conversion bed space for containing a first conversion bed (CB1), means defining a second conversion bed space for containing a second conversion bed (CB2), means for passing carbon-containing fuel into said first conversion bed space, means for circulating at least partially oxidized gas-phase products from an upper region of the first conversion bed space to lower region of the first and second conversion bed spaces to serve as at least part of an upwardly-passing gas in said bed spaces for fluidizing particles therein, means for regulating the relative proportions of said gas-phase products passing to each of the conversion bed spaces, and means for recovering a CO 2 -rich gas from an upper region of the second conversion bed space.
Claim 24
Dependent Claim
140 words
Apparatus for combusting a carbon-containing fuel to produce heat and a CO 2 -rich gas comprising means defining a first conversion bed space for containing a first conversion bed (CB1), means defining a second conversion bed space for containing a second conversion bed (CB2), means for passing carbon-containing fuel into said first conversion bed space, means for circulating at least partially oxidized gas-phase products from an upper region of the first conversion bed space to lower region of the first and second conversion bed spaces to serve as at least part of an upwardly-passing gas in said bed spaces for fluidizing particles therein, means for regulating the relative proportions of said gas-phase products passing to each of the conversion bed spaces, and means for recovering a CO 2 -rich gas from an upper region of the second conversion bed space.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-04-19 | 1991-10-19 | 1992-04-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-04-19 | 1995-10-19 | 1996-04-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-04-19 | 1999-10-19 | 2000-04-19 | $7700.00 | Window Closed / Lapsed |