US4736067A
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New dimethyl derivatives of 3-nitro-4-aminoaniline, process for their preparation and their use for dyeing keratinic fibers
Assignee: L'Oréal SA
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Filing: 1984-09-06
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Granted: 1988-04-05
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Expires: 2004-09-06
Abstract
Abstract New dimethyl derivatives of 3-nitro-4-aminoaniline, process for their preparation, and their use for dyeing keratinic fibres. The invention relates to dimethyl derivatives of 3-nitro-4-aminoaniline of formula: ##STR1## in which CH 3 is in position 2 or 5 of the benzene ring and R 1 and R 2 denote independently of each other a hydrogen atom, a lower alkyl group, a lower mono- or polyhydroxyalkyl or a lower aminoalkyl group in which the amino group is optionally mono- or disubstituted by a lower alkyl radical or by a lower mono- or polyhydroxyalkyl radical, it being understood that the two symbols R 1 and R 2 can be simultaneously other than hydrogen only when the mobile CH 3 radical is in position 5, or cosmetically acceptable salts of these compounds, as well as the process for preparing them and their use in dye compositions, in particular for hair, equally for direct coloring and for coloring by an oxidation route.
Inventors
- 👤 Andree Bugaut
- 👤 Alain Genet
- 👤 Jean Cotteret
- 👤 Alex Junino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 19:56
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/418; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61Q5/10
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
117 words
Dimethyl derivative of 3-nitro-4-aminoaniline, having the following formula (I): ##STR14## in which the radical CH 3 of a variable position is in position 2 or 5 of the benzene ring and R 1 and R 2 denote, independently of each other, a hydrogen atom, a lower alkyl group, a lower mono- or polyhydroxyalkyl group or lower aminoalkyl group in which the amino group is optionally mono- or disubstituted by a lower alkyl radical or by a lower mono- or polyhydroxyalkyl radical, it being understood that the two symbols R 1 and R 2 can be simultaneously other than hydrogen only when the mobile CH 3 radical is in position 5, and cosmetically acceptable salts of this compound.
Claim 2
Dependent Claim
117 words
Dimethyl derivative of 3-nitro-4-aminoaniline, having the following formula (I): ##STR14## in which the radical CH 3 of a variable position is in position 2 or 5 of the benzene ring and R 1 and R 2 denote, independently of each other, a hydrogen atom, a lower alkyl group, a lower mono- or polyhydroxyalkyl group or lower aminoalkyl group in which the amino group is optionally mono- or disubstituted by a lower alkyl radical or by a lower mono- or polyhydroxyalkyl radical, it being understood that the two symbols R 1 and R 2 can be simultaneously other than hydrogen only when the mobile CH 3 radical is in position 5, and cosmetically acceptable salts of this compound.
Claim 3
Dependent Claim
21 words
Compound according to claim 1, wherein at least one of the radicals R 1 and R 2 denotes a hydrogen atom.
Claim 4
Dependent Claim
21 words
Compound according to claim 1 which is chosen from the group consisting of: 2,6-dimethyl-3-nitroparaphenylenediamine, 5,6-dimethyl-3-nitroparaphenylenediamine, 4-amino-2,6-dimethyl-3-nitro-N-methylaniline, 4-amino-5,6-dimethyl-3-nitro-N-β-hydroxyethylaniline, 4-amino-5,6-dimethyl-3-nitro-N-β,γ-dihydroxypropylaniline, 4-amino-5,6-dimethyl-3-nitro-N-β-aminoethylaniline, and 4-amino-5,6-dimethyl-3-nitro-N-β-diethylaminoethylaniline.
Claim 5
Dependent Claim
29 words
Dyeing composition for keratinic fibres, which comprises, in a solvent medium, a quantity which is effective for dyeing, of at least one compound such as defined in claim 1.
Claim 6
Dependent Claim
49 words
Composition according to claim 4, intended for dyeing human hair, which comprises in a cosmetically acceptable medium, at least one compound of formula (I) in proportions of from 0.001 to 5% by weight, and preferably between 0.05 and 2% by weight relative to the total weight of the composition.
Claim 7
Dependent Claim
14 words
Composition according to claim 4 which has a pH of between 3 and 11.5.
Claim 8
Dependent Claim
28 words
Dyeing composition according to claim 4 wherein the solvents are chosen from the group consisting of water, lower alkanols, aromatic alcohols, polyols, and their ethers or their mixtures.
Claim 9
Dependent Claim
41 words
Composition according to claim 4 which additionally comprises cosmetic adjuvants chosen from the group comprising anionic, cationic, nonionic or amphoteric surface-active agents or their mixtures, thickeners, dispersing agents, penetrating agents, sequestering agents, film-forming agents, buffers, perfumes, and alkalising or acidifying agents.
Claim 10
Dependent Claim
45 words
Composition according to claim 4 intended to be employed for direct colouring of human hair, which contains, in addition, other direct colorants chosen from the group consisting of azo colorants, anthraquinone colorants and nitro derivatives of the benzene series other than those of formula (I).
Claim 11
Dependent Claim
31 words
Composition according to claim 4, intended to be employed as a hair-setting lotion, which takes the form of an aqueous, alcoholic or aqueous alcoholic solution containing at least one cosmetic resin.
Claim 12
Dependent Claim
23 words
Composition according to claim 4, intended to be employed for oxidation dyeing, which additionally comprises at least one precursor of an oxidation colorant.
Claim 13
Dependent Claim
20 words
Composition according to claim 11, which has a pH of between 7 and 11.5 and additionally contains a reducing agent.
Claim 14
Dependent Claim
42 words
A process for colouring keratinic fibres, wherein an effective quantity of a composition as defined in claim 9 is applied to the fibres, is left in place for 5 to 50 minutes, followed by rinsing, washing if appropriate, rinsing again and drying.
Claim 15
Dependent Claim
32 words
Process for colouring keratinic fibres, wherein an effective quantity of a composition as defined in claim 10 is applied to the washed and rinsed fibres, which are wound if appropriate and dried.
Claim 16
Dependent Claim
50 words
Process for colouring keratinic fibres, wherein an effective quantity of a composition as defined in claim 11, optionally with the addition of an oxidising agent, is applied to the fibres, is left for 10 to 50 minutes, followed by rinsing, washing with a shampoo if appropriate, rinsing again and drying.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-04-05 | 1991-10-05 | 1992-04-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-04-05 | 1995-10-05 | 1996-04-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-04-05 | 1999-10-05 | 2000-04-05 | $7700.00 | Window Closed / Lapsed |