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US4735839A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical information recording medium

Assignee: Ricoh Co Ltd
•
Filing: 1986-06-26
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Granted: 1988-04-05
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Expires: 2006-06-26
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Abstract

Abstract An optical information recording medium comprises a plastic substrate and a recording layer containing an indole type polymethine compound wherein the substituents attached to N atoms in the indole and indolene rings must be different from each other. The compound provides high solubility in alcoholic solvents, high storage stability (light resistance, heat resistance, etc.) and the like.

Inventors

  • 👤 Tsutomu Sato
  • 👤 Tatsuya Eida
  • 👤 Keiko Ichinose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 22:01
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/249; G11B7/2495; G11B7/246; G11B7/247; G11B7/2472; G11B7/252; G11B7/257; G11B2007/25705; G11B2007/25706; G11B2007/2571; G11B2007/25713; G11B2007/25715; G11B2007/25718; G11B7/2475; G11B7/248; G11B7/253; G11B7/2531; G11B7/2533; G11B7/2534; G11B7/2572; G11B7/2575; G11B7/2578; Y; Y10; Y10S; Y10S430/00; Y10S430/146; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 297 words
An optical information recording medium which comprises a substrate and a recording layer at least 100 Å thick, containing at least one of the compounds represented by the formulas (I) and (II) ##STR28## in which R 1 , R 2 , R 3 and R 4 may be the same or different and each is an alkyl group, an alkenyl group, an alkoxy group or an aralkyl group, these groups being optionally substituted; R 5 is an alkyl group having 1 to 3 carbon atoms which is unsubstituted or substituted; R 6 is an alkyl group having 3 to 18 carbon atoms which is unsubstituted or substituted, --(CH 2 ) a --OCOR or --(CH 2 ) a --OR where R is an alkyl group of 1 to 3 carbon atoms and a is 1 to 5, with the proviso that when R 5 is C3 alkyl, R 6 is not C 3 alkyl; R 7 is hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a hydroxyl group, a halogen atom, an unsubstituted or substituted amino group, an alkanoyloxy group or an aralkyl group; Z represents atom groups necessary to form 4 to 8-membered rings, preferably 5- to 6-membered ring, which are unsubstituted or substituted and may be condensed with an aromatic ring; A is --CH═CH-- 1 or --CH═CH--CH═ 1 ; B is ═CH--CH═ m or --CH═CH-- m CH═; m and 1 is 0 or 1 to 3, and n is 2 or 3; and X is an acid anion, and the benzene nuclei in the indole and indolenine rings may be substituted by one or more groups selected from an alkyl group, an alkenyl group, an alkoxy group, a halogen atom or an aralkyl group, or may be condensed with one or more benzene rings.
Claim 2
Dependent Claim 297 words
An optical information recording medium which comprises a substrate and a recording layer at least 100 Å thick, containing at least one of the compounds represented by the formulas (I) and (II) ##STR28## in which R 1 , R 2 , R 3 and R 4 may be the same or different and each is an alkyl group, an alkenyl group, an alkoxy group or an aralkyl group, these groups being optionally substituted; R 5 is an alkyl group having 1 to 3 carbon atoms which is unsubstituted or substituted; R 6 is an alkyl group having 3 to 18 carbon atoms which is unsubstituted or substituted, --(CH 2 ) a --OCOR or --(CH 2 ) a --OR where R is an alkyl group of 1 to 3 carbon atoms and a is 1 to 5, with the proviso that when R 5 is C3 alkyl, R 6 is not C 3 alkyl; R 7 is hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a hydroxyl group, a halogen atom, an unsubstituted or substituted amino group, an alkanoyloxy group or an aralkyl group; Z represents atom groups necessary to form 4 to 8-membered rings, preferably 5- to 6-membered ring, which are unsubstituted or substituted and may be condensed with an aromatic ring; A is --CH═CH-- 1 or --CH═CH--CH═ 1 ; B is ═CH--CH═ m or --CH═CH-- m CH═; m and 1 is 0 or 1 to 3, and n is 2 or 3; and X is an acid anion, and the benzene nuclei in the indole and indolenine rings may be substituted by one or more groups selected from an alkyl group, an alkenyl group, an alkoxy group, a halogen atom or an aralkyl group, or may be condensed with one or more benzene rings.
Claim 3
Dependent Claim 41 words
A recording medium of claim 1 wherein R 5 is unsubstituted C 1 -C 3 alkyl and R 6 is unsubstituted C 3 -C 18 alkyl with the proviso that R 5 and R 6 are not C 3 alkyl concurrently.
Claim 4
Dependent Claim 43 words
A recording medium of claim 1 wherein R 5 is unsubstituted C 1 -C 3 alkyl and R 6 is --(CH 2 ) a --OCOR or --(CH 2 ) a --OR where R is C 1 -C 3 alkyl and a is 1-5.
Claim 5
Dependent Claim 35 words
A recording medium of claim 1 wherein the recording layer contains a compound of the formula (I) in the proportion of 50 to 100% by weight based on the total solids of said recording layer.
Claim 6
Dependent Claim 35 words
A recording medium of claim 1 wherein the recording layer contains a compound of the formula (II) in the proportion of 50 to 100% by weight based on the total solids of said recording layer.
Claim 7
Dependent Claim 36 words
A recording medium of claim 1 wherein the recording layer contains compounds of the formulas (I) and (II) in the proportion of 50 to 100% by weight based on the total solids of said recording layer.
Claim 8
Dependent Claim 16 words
A recording medium of claim 1 wherein the recording layer is provided directly on the substrate.
Claim 9
Dependent Claim 17 words
A recording medium of claim 1 wherein a protective layer is further provided on the recording layer.
Claim 10
Dependent Claim 11 words
A recording medium of claim 1 wherein the substrate is plastics.
Claim 11
Dependent Claim 17 words
A recording medium of claim 9 wherein the plastic substrate is an injection-molded polymethyl methacrylate or polycarbonate.
Claim 12
Dependent Claim 28 words
A recording medium of claim 1 wherein the recording layer contains further a stabilizer in the proportion of 0.02 to 1 mole per one mole of the compound.
Claim 13
Dependent Claim 18 words
A recording medium of claim 11 wherein the stabilizer is metal complex compounds, aminium compounds or triphenylamine compounds.
Claim 14
Dependent Claim 19 words
A recording medium of claim 1 wherein the recording layer has the thickness of 100 Å to 5000 Å.
Claim 15
Dependent Claim 19 words
A recording medium of claim 13 wherein the recording layer has the thickness of 200 Å to 1500 Å.
Claim 16
Dependent Claim 19 words
A recording medium of claim 14 wherein the recording layer has the thickness of 400 Å to 800 Å.
Claim 17
Dependent Claim 27 words
A recording medium of claim 1 wherein the recording layer is formed by coating a solvent solution containing a compound of claim 1 onto a plastic substrate.
Claim 18
Dependent Claim 21 words
A recording medium of claim 16 wherein the solvent is an alcoholic solvent or a mixed solvent thereof with other solvents.
Claim 19
Dependent Claim 16 words
A recording medium of claim 17 wherein the solvent is methanol, methanol/1,2-dichloroethane, methanol/acetone or methanol/Methyl Cellosolve.

References Cited (Backward Citations)

US3916069A Cited
JPS5967092A Cited
US4600625A Cited
US4551413A Cited
JPS605078A Cited
JPS60226036A Cited
JPS60230891A Cited
JPS60252345A Cited
GB2165658A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-05 1991-10-05 1992-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-05 1995-10-05 1996-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-05 1999-10-05 2000-04-05 $7700.00 Window Closed / Lapsed

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