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US4731405A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic moulding materials with high tracking resistance

Assignee: Bayer AG
•
Filing: 1986-11-28
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Granted: 1988-03-15
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Expires: 2006-11-28
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Abstract

Abstract The present invention relates to moulding materials, containing halogenated copolycarbonates, graft polymers based on an acrylate rubber, thermoplastic copolymers, tetrafluoroethylene polymers, metal compounds of antimony or bismuth, TiO2 and also, if appropriate, low molecular weight, organic halo compounds, stabilizers, flow agents, antistatic agents and/or mould release agents, and also a process for the preparation of these moulding materials.

Inventors

  • 👤 Jurgen Kirsch
  • 👤 Horst Peters
  • 👤 Peter Baasch
  • 👤 Hans-Jurgen Kress
  • 👤 Christian Lindner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:18
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/42; H01B3/421; H01B3/426; C; C08; C08L; C08L69/00

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 294 words
A thermoplastic moulding material containing (A) 60 to 85 parts by weight of a copolycarbonate containing 3 to 20% by weight of halogen, of a divalent phenol and a divalent halogenated phenol, (B) 10 to 30 parts by weight of a graft polymer of (1) 5 to 90 parts by weight, of a mixture of (i) 50 to 95% by weight of styrene, α-methylstyrene, nuclear-substituted styrene, methylmethacrylate or mixtures thereof, and (ii)50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof, on (2) 95 to 10 parts by weight of an acrylate rubber having a glass transition temperature T G ≦10° C. (C) 5 to 30 parts by weight of a thermoplastic copolymer from (1) 50 to 95% by weight of styrene, α-methylstyrene, nuclear-substituted styrene, methyl methacrylate or mixtures thereof, and (2) 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-sustituted maleimide or mixture thereof, wherein the percentages of A, B and C must add up to 100 (D) 0.05 to 2.0 parts by weight, relative to 100 parts by weight of A+B+C, of a tetrafluoroethylene polymer having a density of 2.0 to 2.3 g/cm 3 and a mean particle diameter of 100 to 1000 μm, and (E) 1 to 5 parts by weight, relative to 100 parts by weight of A+B+C, of antimony trioxide, antimony carbonate, bismuth trioxide or bismuth carbonate and (F) 4 to 12 parts by weight, relative to 100 parts by weight of A+B+C, of titanium dioxide and, (G) 0 to 15 parts by weight, relative to 100 parts by weight of A+B+C, of a low-molecular weight, organic halogen compound, the halogen content resulting from components A+G, however, not exceeding 20% by weight, relative to the total weight of components A+G.
Claim 2
Dependent Claim 294 words
A thermoplastic moulding material containing (A) 60 to 85 parts by weight of a copolycarbonate containing 3 to 20% by weight of halogen, of a divalent phenol and a divalent halogenated phenol, (B) 10 to 30 parts by weight of a graft polymer of (1) 5 to 90 parts by weight, of a mixture of (i) 50 to 95% by weight of styrene, α-methylstyrene, nuclear-substituted styrene, methylmethacrylate or mixtures thereof, and (ii)50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof, on (2) 95 to 10 parts by weight of an acrylate rubber having a glass transition temperature T G ≦10° C. (C) 5 to 30 parts by weight of a thermoplastic copolymer from (1) 50 to 95% by weight of styrene, α-methylstyrene, nuclear-substituted styrene, methyl methacrylate or mixtures thereof, and (2) 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-sustituted maleimide or mixture thereof, wherein the percentages of A, B and C must add up to 100 (D) 0.05 to 2.0 parts by weight, relative to 100 parts by weight of A+B+C, of a tetrafluoroethylene polymer having a density of 2.0 to 2.3 g/cm 3 and a mean particle diameter of 100 to 1000 μm, and (E) 1 to 5 parts by weight, relative to 100 parts by weight of A+B+C, of antimony trioxide, antimony carbonate, bismuth trioxide or bismuth carbonate and (F) 4 to 12 parts by weight, relative to 100 parts by weight of A+B+C, of titanium dioxide and, (G) 0 to 15 parts by weight, relative to 100 parts by weight of A+B+C, of a low-molecular weight, organic halogen compound, the halogen content resulting from components A+G, however, not exceeding 20% by weight, relative to the total weight of components A+G.
Claim 3
Dependent Claim 25 words
A moulding material according to claim 1, in which the halogen-containing copolycarbonate of component A. is of a dihydric phenol and a dihydric brominated phenol.
Claim 4
Dependent Claim 38 words
A moulding material according to claim 1 in which the graft polymer of component B is composed of 30to 80 parts by weight of the mixture (1) and 70 to 20 parts by weight of the rubber (2).
Claim 5
Dependent Claim 20 words
A moulding material according to claim 1 containing component D in an amount of 0.1 to 1.0 part by weight.
Claim 6
Dependent Claim 20 words
A moulding material according to claim 1, containing component E, in an amount of 2 to 4 parts by weight.
Claim 7
Dependent Claim 20 words
A moulding material according to claim 1 containing component F in an amount of 5 to 10 parts by weight.
Claim 8
Dependent Claim 24 words
A moulding material according to claim 1, additionally containing at least one additive selected from stabilizers, flow control agents, antistats and/or mould release agents.
Claim 9
Dependent Claim 37 words
A moulding material according to claim 1, in which the copolycarbonate of component A is a copolycarbonate based on bisphenol A with up to 15% by weight, relative to the sum of the diphenols of bis-(3,5-dibromo-4-hydroxyphenyl)propane. propane.
Claim 10
Dependent Claim 49 words
A moulding material according to claim 1, in which the thermoplastic copolymer of component C is formed of at least one monomer selected from styrene, α-methylstyrene, halogenostyrene and p-methylstyrene as component 1., and at least one monomer selected form acrylonitrile, methacrylonitrile, methyl methacylate and maleic anhydride as component 2.
Claim 11
Dependent Claim 35 words
A moulding material according to claim 1, in which the thermoplastic copolymer of component C is formed of 60 to 80% by weight of component 1. and 40 to 20% by weight of component 2.
Claim 12
Dependent Claim 23 words
A moulding material according to claim 1, in which the tetrafluoroethylene polymer of component D contains 65 to 76% by weight of fluorine.
Claim 13
Dependent Claim 28 words
A moulding material according to claim 1, in which the compounds of component G are selected from decabromodiphenyl ether, octabromodiphenyl, tribromotetrachlorotoluene or an oligocarbonate based on tetrabromobisphenol A.
Claim 14
Dependent Claim 43 words
A process for the production of a moulding material according to claim 1 in which components A to F and, G are mixed and the mixture is then melt-compounded or melt-extruded at temperatures of 200° to 330° C. in melt-compounding or melt-extrusion apparatus.
Claim 15
Dependent Claim 35 words
A process according to claim 13 for the production of a moulding material, in which at least one additive selected from stabilizers, flow control agents, antistats and mould release agents is included in the mixture.

References Cited (Backward Citations)

US3673278A Cited
DE2211826A1 Cited
FR2223422A1 Cited
US3901844A Cited
US4503183A Cited
EP0131751A1 Cited
US4649168A Cited
US4636544A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-15 1991-09-14 1992-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-15 1995-09-14 1996-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-15 1999-09-14 2000-03-15 $7700.00 Window Closed / Lapsed

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