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US4731338A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for selective intermixing of layered structures composed of thin solid films

Assignee: Raytheon Co
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Filing: 1986-10-09
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Granted: 1988-03-15
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Expires: 2006-10-09
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Abstract

Abstract A multilayer structure formed of two or more separate layers of different materials can be selectively intermixed so as to become compositionally transmuted, such that the distinction between the different original materials is lost, at least partially. This intermixing is accomplished by employing irradiation with a pulsed or rapidly scanned laser or electron beam. In addition,the intermixing can be accomplised by multiple pulses from the laser or electron beam so as to increase the degree of intermixing, thereby obtaining a more complete mixing.

Inventors

  • 👤 John D. Ralston
  • 👤 Anthony L. Moretti
  • 👤 Ravinder K. Jain

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:33
CPC Classifications
H; H10; H10P; H10P95/00; H10P95/90; H10P14/00; H10P14/20; H10P14/38; H10P14/3824; H10P32/00; H10P32/10; H10P32/14; H10P32/17; H10P32/174

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 133 words
A method for selective intermixing of a multilayer structure, commonly known as a compositional superlattice, formed by a plurality of alternating layers of two different semiconducting materials, such that one set of layers, known as the quantum-well layers, is composed of a semiconductor material of smaller energy band gap, and the other set of layers, known as the barrier layers, is composed of a semiconductor material of larger band gap, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said quantum-well layers and said barrier layers, said method comprising the steps of: providing a compositional superlattice; and irradiating said compositional superlattice with an energy source to selectively intermix the quantum-well layers and the barrier layers in said compositional superlattice.
Claim 2
Independent Claim 133 words
A method for selective intermixing of a multilayer structure, commonly known as a compositional superlattice, formed by a plurality of alternating layers of two different semiconducting materials, such that one set of layers, known as the quantum-well layers, is composed of a semiconductor material of smaller energy band gap, and the other set of layers, known as the barrier layers, is composed of a semiconductor material of larger band gap, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said quantum-well layers and said barrier layers, said method comprising the steps of: providing a compositional superlattice; and irradiating said compositional superlattice with an energy source to selectively intermix the quantum-well layers and the barrier layers in said compositional superlattice.
Claim 3
Dependent Claim 29 words
A method for selective intermixing as claimed in claim 1, wherein the energy source comprises a pulsed or rapidly scanned laser beam or electron beam, or suitable combinations thereof.
Claim 4
Dependent Claim 16 words
A method for selective intermixing as claimed in claim 1, wherein said quantum-well layers are GaAs.
Claim 5
Dependent Claim 19 words
A method for selective intermixing claimed in claim 1, wherein said quantum-well layers are approximately 100 Å in thickness.
Claim 6
Dependent Claim 28 words
A method for selective intermixing as claimed in claim 2, wherein said laser or electron beam consists of a single pulse from a pulsed laser or electron beam.
Claim 7
Dependent Claim 38 words
A method for selective intermixing as claimed in claim 2, wherein said laser or electron beam consists of a rapidly scanned beam whose dwell times on each irradiated portion of the sample are much less than a second.
Claim 8
Dependent Claim 22 words
A method for selective intermixing as claimed in claim 3, wherein said barrier layers are Al 0 .3 Ga 0 .7 As.
Claim 9
Dependent Claim 27 words
A method for selective intermixing as claimed in claim 3, wherein said barrier layers are Al x Ga 1-x As having a variable Al mole fraction x.
Claim 10
Dependent Claim 20 words
A method for selective intermixing as claimed in claim 4, wherein said barrier layers are approximately 100 Å in thickness.
Claim 11
Dependent Claim 38 words
A method for selective intermixing as claimed in claim 5, further comprising the step of irradiating said superlattice with multiple pulses from one or more lasers and electron beams, and combinations thereof, to increase the degree of intermixing.
Claim 12
Independent Claim 73 words
A method for selective intermixing of a multilayer structure originally consisting of two or more thin separate layers of at least two distinct materials to obtain laterally and/or vertically isolated regions exhibiting physical properties different than said multilayer structure, said method comprising the steps of: providing a multilayer structure; and irradiating said multilayer structure with a transient or pulsed energy source so as to selectively intermix the separate layers within said multilayer structure.
Claim 13
Independent Claim 73 words
A method for selective intermixing of a multilayer structure originally consisting of two or more thin separate layers of at least two distinct materials to obtain laterally and/or vertically isolated regions exhibiting physical properties different than said multilayer structure, said method comprising the steps of: providing a multilayer structure; and irradiating said multilayer structure with a transient or pulsed energy source so as to selectively intermix the separate layers within said multilayer structure.
Claim 14
Dependent Claim 20 words
A method for selective intermixing as claimed in claim 11, wherein the energy source comprises a laser or electron beam;
Claim 15
Dependent Claim 28 words
A method for selective intermixing as claimed in claim 12, wherein said laser or electron beam consist of a single pulse from a pulsed laser or electron beam.
Claim 16
Dependent Claim 38 words
A method of selective intermixing as claimed in claim 12, wherein said laser or electron beam consists of a rapidly scanned beam whose dwell times on each irradiated portion of the multilayer structure are less than a second.
Claim 17
Dependent Claim 37 words
A method for selective intermixing as claimed in claim 13, further comprising the step of irradiating said multilayer structure with multiple pulses from various lasers or electron beams, or combinations thereof, to increase the degree of intermixing.
Claim 18
Independent Claim 122 words
A method for selective intermixing of a two layer structure, commonly known as a single heterostructure, in which the first thin layer is composed of one semiconductor material, and the second thin layer is deposited over said first layer and is composed of another semiconductor material of different band gap than said first layer, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said two semiconductor layers, said method comprising the steps of: providing a single heterostructure; and irradiating said single heterostructure with a pulsed or rapidly scanned laser beam or electron beam, or suitable combinations thereof to selectively intermix the two semiconductor layers in said single heterostructure.
Claim 19
Independent Claim 122 words
A method for selective intermixing of a two layer structure, commonly known as a single heterostructure, in which the first thin layer is composed of one semiconductor material, and the second thin layer is deposited over said first layer and is composed of another semiconductor material of different band gap than said first layer, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said two semiconductor layers, said method comprising the steps of: providing a single heterostructure; and irradiating said single heterostructure with a pulsed or rapidly scanned laser beam or electron beam, or suitable combinations thereof to selectively intermix the two semiconductor layers in said single heterostructure.
Claim 20
Independent Claim 98 words
A method for selective intermixing of a three layer semiconductor structure, commonly known as a double heterostructure, in which the middle layer is composed of a semiconductor material of energy band gap different than that of the two surrounding semiconductor layers, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said three semiconductor layers, said method comprising the steps of: providing a double heterostructure; and irradiating said double heterostructure with an energy source to selectively intermix the three semiconductor layers in said double heterostructure.
Claim 21
Independent Claim 98 words
A method for selective intermixing of a three layer semiconductor structure, commonly known as a double heterostructure, in which the middle layer is composed of a semiconductor material of energy band gap different than that of the two surrounding semiconductor layers, to obtain laterally and/or vertically isolated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said three semiconductor layers, said method comprising the steps of: providing a double heterostructure; and irradiating said double heterostructure with an energy source to selectively intermix the three semiconductor layers in said double heterostructure.
Claim 22
Independent Claim 83 words
A method for selective intermixing of a multilayer structure, commonly known as a doping superlattice, formed by the introduction of different impurity atoms into alternating layers of one semiconducting material, to obtain laterally and/or vertically integrated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said layers, said method comprising the steps of: providing a doping superlattice; and irradiating said doping superlattice with an energy source to selectively intermix the layers in said doping superlattice.
Claim 23
Independent Claim 83 words
A method for selective intermixing of a multilayer structure, commonly known as a doping superlattice, formed by the introduction of different impurity atoms into alternating layers of one semiconducting material, to obtain laterally and/or vertically integrated regions, said regions exhibiting optical and electronic properties different than those of the alloy generated by intermixing said layers, said method comprising the steps of: providing a doping superlattice; and irradiating said doping superlattice with an energy source to selectively intermix the layers in said doping superlattice.

References Cited (Backward Citations)

US4318752A Cited
US4511408A Cited
US4639275A Cited
US4585491A Cited
US4637122A Cited
US4578128A Cited
US4654090A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-15 1991-09-14 1992-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-15 1995-09-14 1996-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-15 1999-09-14 2000-03-15 $7700.00 Window Closed / Lapsed

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