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US4729987A Expired / Lapsed US ⏱️ 0.0 years remaining

Insecticidal O,O-diethyl-O-(2-(1,1-dimethylethyl)-5-pyrimidinyl)-phosphorothioate

Assignee: Dow Chemical Co
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Filing: 1986-10-21
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Granted: 1988-03-08
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Expires: 2006-10-21
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Abstract

Abstract Compounds of the formula: ##STR1## wherein R is hydrogen; alkyl of 1 to 8 carbons; alkylthiomethyl, alkylsulfinylmethyl or alkylsulfonylmethyl wherein alkyl contains 1 to 4 carbons; phenyl; phenylthio; alkylthio, alkylsulfinyl or alkylsulfonyl wherein alkyl contains 1 to 4 carbons; or alkylthioethylthio wherein alkyl contains 1 to 2 carbons; R' is hydrogen, methyl or alkylthio of 1 to 2 carbons; R" is hydrogen or methyl; X is oxygen or sulfur; R'" is alkyl of 1 to 2 carbons; and R"" is --OR'" or --S-alkyl of 1 to 4 carbons, are highly useful insecticides which are particularly valuable when applied to the soil, but are also useful applied to foliage of crops or trees. Especially good control is obtained of corn rootworm, codling moth, thrips, leafhoppers, and nematodes. The compounds are conveniently applied in the form of a composition containing a pesticidal carrier such as an inert solvent or a finely divided inert solid in which case the composition is preferably granulated. An effective application rate is in the range of about 0.1 to about 5 pounds per acre when soil incorporated, and about 0.5 to about 2,000 ppm for foliar applications.

Inventors

  • 👤 Walter Reifschneider

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 22:15
CPC Classifications
A; A01; A01N; A01N57/00; A01N57/10; A01N57/16; C; C07; C07F; C07F9/00; C07F9/02; C07F9/547; C07F9/645; C07F9/6509; C07F9/6512

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 17 words
A compound of the formula ##STR5## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R"" is ethoxy.
Claim 2
Dependent Claim 17 words
A compound of the formula ##STR5## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R"" is ethoxy.
Claim 3
Dependent Claim 42 words
A composition comprising an agricultural carrier selected from the group consisting of surface active dispersing agents and finely divided inert solids in admixture with a pyrimidinyl phosphate having the formula: ##STR6## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R'" is ethoxy.
Claim 4
Dependent Claim 42 words
A composition comprising an agricultural carrier selected from the group consisting of surface active dispersing agents and finely divided inert solids in admixture with a pyrimidinyl phosphate having the formula: ##STR6## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R'" is ethoxy.
Claim 5
Independent Claim 37 words
A method which comprises applying to crop land soil an insecticidal amount but less than a phytotoxic amount of a pyrimidinyl phosphate having the formula ##STR7## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R'" is ethoxy.
Claim 6
Independent Claim 37 words
A method which comprises applying to crop land soil an insecticidal amount but less than a phytotoxic amount of a pyrimidinyl phosphate having the formula ##STR7## wherein R is 1,1-dimethylethyl; R'" is ethyl; and R'" is ethoxy.
Claim 7
Dependent Claim 24 words
The method as in claim 3 in which the defined pyrimidinyl phosphate is applied to the soil of crop lands in an insecticidal amount.
Claim 8
Dependent Claim 24 words
The method as in claim 4 in which the defined pyrimidinyl phosphate is applied to the soil of corn, sorghum, cotton or sugar beets.
Claim 9
Dependent Claim 32 words
The method of claim 5 in which the defined pyrimidinyl phosphate is applied to the soil of corn at a rate in the range of about 0.1 to 2 pounds per acre.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-08 1991-09-07 1992-03-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-08 1995-09-07 1996-03-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-08 1999-09-07 2000-03-08 $7700.00 Window Closed / Lapsed

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