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US4728596A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive element for silver salt diffusion transfer with iodine trapping layer

Assignee: Fujifilm Holdings Corp
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Filing: 1986-01-22
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Granted: 1988-03-01
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Expires: 2006-01-22
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Abstract

Abstract A light-sensitive element for the silver salt diffusion transfer method is described, comprising a support bearing thereon at least a light-sensitive silver halide emulsion layer containing silver iodide, wherein at least one layer for trapping on iodide ion is provided between the support and the emulsion layer. This light-sensitive element provides a silver image which is improved in fading and discoloration during storage.

Inventors

  • 👤 Hideki Takaki
  • 👤 Yukio Karino
  • 👤 Noriyuki Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:47
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/02; G03C8/04; G03C8/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 123 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion containing silver iodide provided on the support, further comprising at least one layer capable of trapping iodide ions which is a layer of light-insensitive silver iodobromide having a silver iodide content of from 0.5 to 20 mol% provided between the support and light-sensitive silver halide emulsion layer.
Claim 2
Dependent Claim 123 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion containing silver iodide provided on the support, further comprising at least one layer capable of trapping iodide ions which is a layer of light-insensitive silver iodobromide having a silver iodide content of from 0.5 to 20 mol% provided between the support and light-sensitive silver halide emulsion layer.
Claim 3
Dependent Claim 52 words
A method as in claim 1, wherein the silver iodobromide layer for trapping iodide ions is a silver iodobromide emulsion layer wherein the weight ratio of silver to binder is from about 1/4 to 1/100 and the amount of silver in the coated silver halide is about 0.5 g/m 2 or less.
Claim 4
Dependent Claim 27 words
A method as in claim 1, wherein said light-insensitive silver iodobromide layer has a sensitivity 1/5 or less the sensitivity of the light-sensitive silver halide emulsion layer.
Claim 5
Dependent Claim 130 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion layer containing silver iodide provided on the support, and at least one layer capable of trapping iodide ions is provided between the support and the light-sensitive silver halide emulsion layer, wherein said layer capable of trapping iodide ions is a layer containing a cationic polyelectrolyte which does not contain iodide ions as counter ions.
Claim 6
Dependent Claim 130 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion layer containing silver iodide provided on the support, and at least one layer capable of trapping iodide ions is provided between the support and the light-sensitive silver halide emulsion layer, wherein said layer capable of trapping iodide ions is a layer containing a cationic polyelectrolyte which does not contain iodide ions as counter ions.
Claim 7
Dependent Claim 190 words
A method as in claim 4, wherein said layer capable of trapping iodide ions contains a compound represented by formula (I): ##STR16## wherein: A represents a repeating unit resulting from copolymerization of a copolymerizable monomer containing at least two ethylenically unsaturated groups; B represents a repeating unit resulting from copolymerization of an ethyleneically unsaturated monomer copolymerizable with the monomer forming A and the other repeating unit; R 1 represents a hydrogen atom or a lower alkyl group having from 1 to 6 carbon atoms; L is a divalent group having from 1 to about 12 carbon atoms; R 2 , R 3 and R 4 each represents an alkyl group having from 1 to about 20 carbon atoms, or an aralkyl group having from 7 to about 20 carbon atoms; or two of R 2 , R 3 and R 4 combine together in combination with Q to form a ring structure; Q represents N or P; X.sup.⊖ represents an anion except for an iodide ion; x is from about 0.2 to 15 mol%; y is from 0 to about 90%; and z is from about 5 to 99 mol%.
Claim 8
Dependent Claim 30 words
A method as claimed in claim 5, wherein x is from 1.0 to 10 mol%, y is from 20 to 60 mol% and z is from 30 to 70 mol%.

References Cited (Backward Citations)

US3619186A Cited
US3708300A Cited
US4015989A Cited
US3958995A Cited
US4131469A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-01 1991-08-31 1992-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-01 1995-08-31 1996-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-01 1999-08-31 2000-03-01 $7700.00 Window Closed / Lapsed

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