Patent US4728596A successfully refreshed from Google Patents.
US4728596A
Expired / Lapsed
US
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Light-sensitive element for silver salt diffusion transfer with iodine trapping layer
Assignee: Fujifilm Holdings Corp
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Filing: 1986-01-22
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Granted: 1988-03-01
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Expires: 2006-01-22
Abstract
Abstract A light-sensitive element for the silver salt diffusion transfer method is described, comprising a support bearing thereon at least a light-sensitive silver halide emulsion layer containing silver iodide, wherein at least one layer for trapping on iodide ion is provided between the support and the emulsion layer. This light-sensitive element provides a silver image which is improved in fading and discoloration during storage.
Inventors
- 👤 Hideki Takaki
- 👤 Yukio Karino
- 👤 Noriyuki Inoue
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:47
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/02; G03C8/04; G03C8/06
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
123 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion containing silver iodide provided on the support, further comprising at least one layer capable of trapping iodide ions which is a layer of light-insensitive silver iodobromide having a silver iodide content of from 0.5 to 20 mol% provided between the support and light-sensitive silver halide emulsion layer.
Claim 2
Dependent Claim
123 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion containing silver iodide provided on the support, further comprising at least one layer capable of trapping iodide ions which is a layer of light-insensitive silver iodobromide having a silver iodide content of from 0.5 to 20 mol% provided between the support and light-sensitive silver halide emulsion layer.
Claim 3
Dependent Claim
52 words
A method as in claim 1, wherein the silver iodobromide layer for trapping iodide ions is a silver iodobromide emulsion layer wherein the weight ratio of silver to binder is from about 1/4 to 1/100 and the amount of silver in the coated silver halide is about 0.5 g/m 2 or less.
Claim 4
Dependent Claim
27 words
A method as in claim 1, wherein said light-insensitive silver iodobromide layer has a sensitivity 1/5 or less the sensitivity of the light-sensitive silver halide emulsion layer.
Claim 5
Dependent Claim
130 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion layer containing silver iodide provided on the support, and at least one layer capable of trapping iodide ions is provided between the support and the light-sensitive silver halide emulsion layer, wherein said layer capable of trapping iodide ions is a layer containing a cationic polyelectrolyte which does not contain iodide ions as counter ions.
Claim 6
Dependent Claim
130 words
In a method for forming an image by silver salt diffusion transfer where an imagewise exposed silver halide photographic element is superposed on an image-receiving element containing a silver-precipitating agent and then an alkaline processing solution containing a solvent for silver halide is introduced between the light-sensitive and image-receiving elements in the presence of a developing agent, the improvement wherein the imagewise exposed silver halide photographic element comprises a support and a light-sensitive silver halide emulsion layer containing silver iodide provided on the support, and at least one layer capable of trapping iodide ions is provided between the support and the light-sensitive silver halide emulsion layer, wherein said layer capable of trapping iodide ions is a layer containing a cationic polyelectrolyte which does not contain iodide ions as counter ions.
Claim 7
Dependent Claim
190 words
A method as in claim 4, wherein said layer capable of trapping iodide ions contains a compound represented by formula (I): ##STR16## wherein: A represents a repeating unit resulting from copolymerization of a copolymerizable monomer containing at least two ethylenically unsaturated groups; B represents a repeating unit resulting from copolymerization of an ethyleneically unsaturated monomer copolymerizable with the monomer forming A and the other repeating unit; R 1 represents a hydrogen atom or a lower alkyl group having from 1 to 6 carbon atoms; L is a divalent group having from 1 to about 12 carbon atoms; R 2 , R 3 and R 4 each represents an alkyl group having from 1 to about 20 carbon atoms, or an aralkyl group having from 7 to about 20 carbon atoms; or two of R 2 , R 3 and R 4 combine together in combination with Q to form a ring structure; Q represents N or P; X.sup.⊖ represents an anion except for an iodide ion; x is from about 0.2 to 15 mol%; y is from 0 to about 90%; and z is from about 5 to 99 mol%.
Claim 8
Dependent Claim
30 words
A method as claimed in claim 5, wherein x is from 1.0 to 10 mol%, y is from 20 to 60 mol% and z is from 30 to 70 mol%.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-01 | 1991-08-31 | 1992-03-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-01 | 1995-08-31 | 1996-03-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-01 | 1999-08-31 | 2000-03-01 | $7700.00 | Window Closed / Lapsed |