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US4728452A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal corrosion inhibition in closed cooling systems

Assignee: Pony Industries Inc
•
Filing: 1986-01-17
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Granted: 1988-03-01
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Expires: 2006-01-17
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Abstract

Abstract The corrosion of metals in closed, aqueous cooling systems having a pH of 7.5 to 10.5 is inhibited by adding to the system a coolant concentrate comprising water, at least 10% by weight of a water soluble nitrite or a mixture of a water soluble nitrite and a water soluble nitrate, 0.2 to 2.0% by weight of at least one water soluble azole, and 0.1 to 1.0% by weight of a water soluble molybdate, to provide in the system concentrations of at least 200 ppm of the nitrite or nitrite/nitrate mixture, 2 to 20 ppm of the azole and 1 to 10 ppm of the molybdate.

Inventors

  • 👤 Gerald D. Hansen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:56
CPC Classifications
C; C23; C23F; C23F11/00; C23F11/08; C09; C09K; C09K5/00; C09K5/20

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 105 words
A metal corrosion inhibited coolant composition, comprising: (1) a water-soluble nitrite or a mixture of a water-soluble nitrite and a water-soluble nitrate, a water-soluble azole selected from triazoles, thiazoles and mixtures of these and a water-soluble molybdate, (2) sufficient dilution water to provide from about 200 to about 500 ppm of nitrite or mixture of nitrite and nitrate, from about 2 to about 8 ppm azole and from about 2 to about 10 ppm molybdate, and (3) a buffer present in said composition in an amount sufficient to maintain the pH of said composition to between about 7.5 and 10.5; wherein said composition is silicate-free.
Claim 2
Dependent Claim 105 words
A metal corrosion inhibited coolant composition, comprising: (1) a water-soluble nitrite or a mixture of a water-soluble nitrite and a water-soluble nitrate, a water-soluble azole selected from triazoles, thiazoles and mixtures of these and a water-soluble molybdate, (2) sufficient dilution water to provide from about 200 to about 500 ppm of nitrite or mixture of nitrite and nitrate, from about 2 to about 8 ppm azole and from about 2 to about 10 ppm molybdate, and (3) a buffer present in said composition in an amount sufficient to maintain the pH of said composition to between about 7.5 and 10.5; wherein said composition is silicate-free.
Claim 3
Dependent Claim 26 words
The coolant composition of claim 1 additionally containing a freezing point depressing amount of at least one alcohol, at least one glycol or a mixture thereof.
Claim 4
Dependent Claim 24 words
The coolant composition of claim 2 wherein the alcohol, glycol or mixed alcohol-glycol component comprises about 40% to 80% by weight of the coolant.
Claim 5
Dependent Claim 34 words
The coolant composition of claim 1 wherein the nitrite is sodium nitrite, the nitrate is sodium nitrate, the azole is sodium tolyltriazole, sodium mercaptobenzothiazole or a mixture thereof, and the molybdate is sodium molybdate.
Claim 6
Dependent Claim 28 words
In a process for inhibiting the corrosion of metals in constant contact with an aqueous coolant, the improvement wherein said aqueous coolant comprises the composition of claim 1.
Claim 7
Dependent Claim 28 words
In a process for inhibiting the corrosion of metals in constant contact with an aqueous coolant, the improvement wherein said aqueous coolant comprises the composition of claim 4.
Claim 8
Dependent Claim 34 words
A cooling system comprising the metal corrosion inhibited coolant composition of claim 1, and an apparatus for containing and transporting said composition, wherein said apparatus includes a metal surface in contact with said composition.
Claim 9
Dependent Claim 12 words
The cooling system of claim 7, wherein said metal surface includes aluminum.

References Cited (Backward Citations)

US2147395A Cited
US3335096A Cited
US4098720A Cited
US4149969A Cited
US4548787A Cited
US4452715A Cited
US4561990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-01 1991-08-31 1992-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-01 1995-08-31 1996-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-01 1999-08-31 2000-03-01 $7700.00 Window Closed / Lapsed

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