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US4725529A Expired / Lapsed US ⏱️ 0.0 years remaining

Developing inhibitor arrangment in light-sensitive silver halide color photographic materials

Assignee: Konica Minolta Inc
•
Filing: 1986-04-21
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Granted: 1988-02-16
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Expires: 2006-04-21
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Abstract

Abstract There is disclosed a light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of the light-sensitive silver halide emulsion layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or developing inhibitor precursor through the reaction with the oxidized product of a developing agent, the developing inhibitor or developing inhibitor precursor released from the DIR compound being diffusive, wherein the following conditions A: DIR compounds are added and incorporated in the emulsion layers so that the developing inhibitor released from the DIR compound incorporated in one color-sensitive silver halide emulsion layer and the developing inhibitor released from the DIR compound incorporated in the other color-sensitive silver halide emulsion layer are reversed in developing inhibiting power when the DIR compounds to be incorporated in the respective light-sensitive silver halide emulsion layers are exchanged with each other, and also each DIR compound may have greater inhibiting power for the other light-sensitive silver halide emulsion layer rather than for the light-sensitive silver halide emulsion layer in which it is incorporated, is satisfied for the at least two light-sensitive silver halide emulsion layers different in color sensitivities.

Inventors

  • 👤 Hiroshi Shimazaki
  • 👤 Eiichi Sakamoto
  • 👤 Satoshi Nakagawa
  • 👤 Hiroshi Inoie
  • 👤 Minoru Ishikawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 02:06
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/305; G03C7/30594; Y; Y10; Y10S; Y10S430/00; Y10S430/156; Y10S430/158

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 150 words
A light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of said light-sensitive silver halide emulsion-layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or a developing inhibitor precursor through the reaction with the oxidized product of a developing inhibitor, the developing inhibitor or developing inhibitor precursor released from said DIR compound being diffusive, wherein, in said at least two light-sensitive silver halide emulsion layers different in color sensitivities, the developing inhibitor(s) and/or developing inhibitor precursor(s) released from said DIR compounds contained in said at least two light-sensitive silver halide emulsion layers are different from each other and also each DIR compound may have greater inhibiting power for the other light-sensitive silver halide emulsion layer rather than for the light-sensitive silver halide emulsion layer in which it is incorporated.
Claim 2
Dependent Claim 150 words
A light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of said light-sensitive silver halide emulsion-layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or a developing inhibitor precursor through the reaction with the oxidized product of a developing inhibitor, the developing inhibitor or developing inhibitor precursor released from said DIR compound being diffusive, wherein, in said at least two light-sensitive silver halide emulsion layers different in color sensitivities, the developing inhibitor(s) and/or developing inhibitor precursor(s) released from said DIR compounds contained in said at least two light-sensitive silver halide emulsion layers are different from each other and also each DIR compound may have greater inhibiting power for the other light-sensitive silver halide emulsion layer rather than for the light-sensitive silver halide emulsion layer in which it is incorporated.
Claim 3
Dependent Claim 32 words
A light-sensitive silver halide color photographic material according to claim 1, wherein said diffusive DIR compound has a developing inhibitor or developing inhibitor precursor having a diffusiveness of not less than 0.34.
Claim 4
Dependent Claim 123 words
A light-sensitive silver halide color photographic material according to claim 2, wherein said light-sensitive silver halide color photographic material comprises a developing inhibitor A and a developing inhibitor B are used in a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, respectively, and when A is greater than B with respect to the developing inhibiting power for the green-sensitive silver halide emulsion layer and A is not greater than B with respect to the developing inhibiting power for the red-sensitive silver halide emulsion layer, a DIR compound having the developing inhibitor B is added in the green-sensitive silver halide emulsion layer and a DIR compound having the developing inhibitor A is added in the red-sensitive silver halide emulsion layer.
Claim 5
Dependent Claim 123 words
A light-sensitive silver halide color photographic material according to claim 2, wherein said light-sensitive silver halide color photographic material comprises a developing inhibitor C and a developing inhibitor D are used in a blue-sensitive silver halide emulsion layer and a green-sensitive silver halide emulsion layer, respectively, and when C is greater than D with respect to the developing inhibiting power for the blue-sensitive silver halide emulsion layer and C is not greater than D with respect to the developing inhibiting power for the green-sensitive silver halide emulsion layer, a DIR compound having the developing inhibitor D is added in the blue-sensitive silver halide emulsion layer and a DIR compound having the developing inhibitor C is added in the green-sensitive silver halide emulsion layer.
Claim 6
Dependent Claim 122 words
A light-sensitive silver halide color photographic material according to claim 2, wherein said light-sensitive silver halide color photographic material comprises a developing inhibitor E and a developing inhibitor F are used in a blue-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, respectively, and when E is greater than F with respect to the developing inhibiting power for the blue-sensitive silver halide emulsion layer and E is not greater than F with respect to the developing inhibiting power for the red-sensitive silver halide emulsion-layer, a DIR compound having the developing inhibitor F is added in the blue-sensitive silver halide emulsion layer and a DIR compound having the developing inhibitor E is added in the red-sensitive silver halide emulsion layer.
Claim 7
Dependent Claim 87 words
A light-sensitive silver halide color photographic material according to claim 2, wherein said photographic material comprises a green-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR39## where R represents a hydrogen atom or a hydroxy group, or a benztriazole derivative and a red-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR40## where R' represents a hydrocarbon group having carbon atoms of not more than 6.
Claim 8
Dependent Claim 87 words
A light-sensitive silver halide color photographic material according to claim 2, wherein said photographic material comprises a green-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR41## where R represents a hydrogen atom or a hydroxy group, or a benztriazole derivative and a blue-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR42## where R' represents a hydrocarbon group having carbon atoms of not more than 6.
Claim 9
Dependent Claim 51 words
A light-sensitive silver halide color photographic material according to claim 6, wherein said photographic material comprises a green-sensitive silver halide emulsion layer containing a diffusive DIR compound having an inhibiting group of ##STR43## and a red-sensitive silver halide emulsion layer containing a diffusive DIR compound having an inhibiting group of ##STR44##
Claim 10
Dependent Claim 93 words
A light-sensitive silver halide color photographic material according to claim 1, wherein the strength relationship or developing inhibiting power of the developing inhibitor released from the DIR compound incorporated in a first color-sensitive silver halide emulsion layer to the first emulsion layer is smaller than that to a second color-sensitive silver halide emulsion layer, and strength relationship or developing inhibiting power of the developing inhibitor released from the DIR compound incorporated in the second color-sensitive silver halide emulsion layer to the second emulsion layer is smaller than that to the first emulsion layer.
Claim 11
Dependent Claim 99 words
A light-sensitive silver halide color photographic material having two or more light-sensitive silver halide emulsion layers of different color sensitivities on a support, and wherein said photographic material comprises a green-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR45## where R represents a hydrogen atom or a hydroxy group, or a benztriazole derivative; and a red-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR46## where R' represents a hydrocarbon group having not more than 6 carbon atoms.
Claim 12
Dependent Claim 99 words
A light-sensitive silver halide color photographic material having two or more light-sensitive silver halide emulsion layers of different color sensitivities on a support, and wherein said photographic material comprises a green-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR45## where R represents a hydrogen atom or a hydroxy group, or a benztriazole derivative; and a red-sensitive silver halide emulsion layer containing a diffusive DIR compound having at least one of an inhibiting group of ##STR46## where R' represents a hydrocarbon group having not more than 6 carbon atoms.

References Cited (Backward Citations)

US3632345A Cited
US4267264A Cited
GB2010818A Cited
US4477560A Cited
EP0115304A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-02-15 1991-08-17 1992-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-02-15 1995-08-17 1996-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-02-15 1999-08-17 2000-02-16 $7700.00 Window Closed / Lapsed

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