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US4725460A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical filter and the method of preparing the same

Assignee: Panasonic Holdings Corp
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Filing: 1985-03-12
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Granted: 1988-02-16
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Expires: 2005-03-12
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Abstract

Abstract This invention provides an optical filter comprises of a pair of solid polymer films, wherein (1) a first solid polymer film has a planar alignment of a cholesteric liquid crystal structure of either clockwise or counterclockwise helical structure, which alignment allows the light of a specified wavelength to be scattered selectively, and (2) a second solid polymer film has a planar alignment of a cholesteric liquid crystal structure of a helical structure whose helical direction is the opposite to that of the first solid polymer film, which alignment allows the light at the specified wavelength to be scattered selectively, wherein the optical axes of the first and second solid polymer films are made substantially parallel to each other. This invention also provides preparation methods of an optical filter mentioned above.

Inventors

  • 👤 Yoshihiro Matsuo
  • 👤 Shoichi Ishihara
  • 👤 Kazuhisa Morimoto
  • 👤 Seiichi Nagata
  • 👤 Tetsu Ogawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 19:48
CPC Classifications
C; C09; C09K; C09K19/00; G; G02; G02B; G02B5/00; G02B5/30; G02B5/3016; C09K2323/00; C09K2323/03; C09K2323/031; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 126 words
An optical filter comprising a pair of a first solid polymer film having planar alignment of a cholesteric liquid crystal structure of either clockwise or counterclockwise helical structure, which alignment allows the light of a specified wavelength to be scattered selectively, and a second solid polymer film having a planar alignment of a cholesteric liquid crystal structure of a helical structure whose helical direction is the opposite to that of the first solid polymer film, which alignment allows the light at the specified wavelength to be scattered selectively; wherein the first and second polymer films being layered in close contact with each other, and being layered so that the optical axes of the first and second solid polymer films are made substantially parallel to each other.
Claim 2
Dependent Claim 126 words
An optical filter comprising a pair of a first solid polymer film having planar alignment of a cholesteric liquid crystal structure of either clockwise or counterclockwise helical structure, which alignment allows the light of a specified wavelength to be scattered selectively, and a second solid polymer film having a planar alignment of a cholesteric liquid crystal structure of a helical structure whose helical direction is the opposite to that of the first solid polymer film, which alignment allows the light at the specified wavelength to be scattered selectively; wherein the first and second polymer films being layered in close contact with each other, and being layered so that the optical axes of the first and second solid polymer films are made substantially parallel to each other.
Claim 3
Dependent Claim 63 words
An optical filter according to claim 1, wherein at least two said pairs of solid polymer films are layered so that the optical axes of the solid polymer films are made substantially parallel to each other, and each pair of solid polymer films has a planar alignment which allows the light to be scattered selectively at a specified wavelength different with each other.
Claim 4
Dependent Claim 32 words
An optical filter according to claims 1 or 2, wherein the refractive indexes of each solid polymer film which constitutes said pair of solid polymer films are substantially equal to each other.
Claim 5
Dependent Claim 18 words
An optical filter according to claims 1 or 2, wherein said cholesteric liquid crystal structure comprises polypeptide compounds.
Claim 6
Dependent Claim 35 words
An optical filter according to claims 1 or 2, wherein said cholesteric liquid crystal structure comprises a polymer made by the radiation polymerization from monomers of an acrylic compound having at least one unsaturated radical.
Claim 7
Independent Claim 260 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a first lyotropic liquid crystal of the cholesteric phase in the planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has either a clockwise or counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing a second lyotropic liquid crystal layer between the first solid polymer film and a substrate which is placed parallel to the first solid polymer film in a uniform thickness of cholesteric phase in the planar alignment, which lyotropic liquid crystal is a second mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a helical structure whose helical direction is the opposite to that in the first solid polymer film; and the step of fixing the planar alignment by radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; wherein the components and their concentrations in the first and second mixed solutions and the polymerization temperature are determined so that the product of the refractive index and the helical pitch of the cholesteric phase in the first solid polymer film is equal to that in the second solid polymer film and are made substantially parallel to each other.
Claim 8
Independent Claim 260 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a first lyotropic liquid crystal of the cholesteric phase in the planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has either a clockwise or counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing a second lyotropic liquid crystal layer between the first solid polymer film and a substrate which is placed parallel to the first solid polymer film in a uniform thickness of cholesteric phase in the planar alignment, which lyotropic liquid crystal is a second mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a helical structure whose helical direction is the opposite to that in the first solid polymer film; and the step of fixing the planar alignment by radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; wherein the components and their concentrations in the first and second mixed solutions and the polymerization temperature are determined so that the product of the refractive index and the helical pitch of the cholesteric phase in the first solid polymer film is equal to that in the second solid polymer film and are made substantially parallel to each other.
Claim 9
Dependent Claim 28 words
A method of preparing an optical filter according to claim 6, wherein one of said substrates at the outer side is a transparent film or a transparent plate.
Claim 10
Dependent Claim 28 words
A method of preparing an optical filter according to claim 6, wherein one of said substrates at the outer side is a color filter or a multicolor filter.
Claim 11
Dependent Claim 28 words
A method of preparing an optical filter according to claim 6, wherein one of said substrates at the outer side is a quarter-wavelength plate or a half-wavelength plate.
Claim 12
Dependent Claim 24 words
A method of preparing an optical filter according to claim 6, wherein two pairs of solid polymer films are adhered with a binding agent.
Claim 13
Dependent Claim 23 words
A method of preparing an optical filter according to claim 6, wherein said binding agent contains monomers which polymerize and hardens under radiation.
Claim 14
Dependent Claim 27 words
A method of preparing an optical filter according to claim 6, wherein said polypeptide compound is an acidic polyamino acid or an acidic polyamino acid ester derivative.
Claim 15
Dependent Claim 25 words
A method of preparing an optical filter according to claim 6, wherein said monomer is an acrylic compound, a methacrylic compound or an allyl compound.
Claim 16
Independent Claim 237 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a lyotropic liquid crystal of a uniform thickness in the cholesteric phase in the planar alignment on a substrate; which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has either clockwise or counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing lyotropic liquid crystal in a uniform thickness in the cholesteric phase on the surface of the first solid polymer film; which lyotropic liquid crystal is made of a second mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a helical structure whoses helical direction is the opposite to that of the second solid polymer film; and the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; wherein the components and their concentrations in the first and the second mixed solutions and the polymerization temperature are determined so that the product of the refractive index and the helical pitch of the cholesteric phase in the first solid polymer film is equal to that in the second solid polymer film.
Claim 17
Independent Claim 237 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a lyotropic liquid crystal of a uniform thickness in the cholesteric phase in the planar alignment on a substrate; which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has either clockwise or counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing lyotropic liquid crystal in a uniform thickness in the cholesteric phase on the surface of the first solid polymer film; which lyotropic liquid crystal is made of a second mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a helical structure whoses helical direction is the opposite to that of the second solid polymer film; and the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; wherein the components and their concentrations in the first and the second mixed solutions and the polymerization temperature are determined so that the product of the refractive index and the helical pitch of the cholesteric phase in the first solid polymer film is equal to that in the second solid polymer film.
Claim 18
Dependent Claim 24 words
The method of preparing an optical filter according to claim 14, wherein one of said substrates is a transparent film or a transparent plate.
Claim 19
Dependent Claim 24 words
A method of preparing an optical filter according to claim 14, wherein one of said substrates is a color filter or a multicolor filter.
Claim 20
Dependent Claim 24 words
A method of preparing an optical filter according to claim 14, wherein one of said substrate is a quarter-wavelength plate or a half-wavelength plate.
Claim 21
Dependent Claim 27 words
A method of preparing an optical filter according to claim 14, wherein said polypeptide compound is an acidic polyamino acid or an acidic polyamino acid ester derivative.
Claim 22
Dependent Claim 27 words
A method of preparing an optical filter according to claim 14, wherein one of said monomers is an acrylic compound, a methacrylic compound or an allyl compound.
Claim 23
Independent Claim 197 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a first lyotropic liquid crystal of the cholesteric phase in a planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a clockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing a second lyotropic liquid crystal of the cholesteric phase in a planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; the step of binding the first and second solid polymer films with a binding agent of a uniform thickness so as to form layered composite.
Claim 24
Independent Claim 197 words
A method of preparing an optical filter consisting of a pair of solid polymer films, comprising the step of placing a first lyotropic liquid crystal of the cholesteric phase in a planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a clockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a first solid polymer film is produced; the step of placing a second lyotropic liquid crystal of the cholesteric phase in a planar alignment between two parallel substrates in a uniform thickness, which lyotropic liquid crystal is made of a first mixed solution of polypeptide compounds and monomers which can polymerize under radiation, which cholesteric phase has a counterclockwise helical structure; the step of fixing the planar alignment by the radiation polymerization at a predetermined temperature so that a second solid polymer film is produced; the step of binding the first and second solid polymer films with a binding agent of a uniform thickness so as to form layered composite.
Claim 25
Dependent Claim 34 words
A method according to claim 20, wherein said binding agent contains monomers which can polymerize under radiation to form a solid binding layer and the step of binding includes a step of radiation polymerization.

References Cited (Backward Citations)

US4384016A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-02-15 1991-08-17 1992-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-02-15 1995-08-17 1996-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-02-15 1999-08-17 2000-02-16 $7700.00 Window Closed / Lapsed

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