Mutiaxially oriented high performance laminates comprised of uniaxially oriented sheets of thermotropic liquid crystal polymers

Claim 3

The method of claim 1 wherein said thermal bonding conditions include heating at least one of said sheets to a temperature in excess of the melting temperature of the polymer which comprises said at least one sheet and pressing said sheets together.

Claim 4

The method of claim 2 wherein said at least one sheet is heated to a temperature between the melting temperature of the polymer which comprises said sheet and about 20 centigrade degrees in excess of said melting temperature.

Claim 5

The method of claim 1 wherein said at least two sheets are oriented at an angle of between about 30° and 90° relative to one another.

Claim 6

The method of claim 1 wherein said at least two sheets are oriented at an angle of about 90° relative to one another.

Claim 7

The method of claim 1 wherein said laminate is heat treated at a temperature below the melting temperature of the polymer comprising said at least two sheets and for a period of time sufficient to increase the melting temperature of said polymer.

Claim 8

The method of claim 6 wherein said melting temperature is increased from between about 20 to about 50 centigrade degrees.

Claim 9

The method of claim 6 wherein said heat treatment temperature ranges from about 10 to about 30 centigrade degrees below the melting temperature of the polymer and said heat treatment occurs in a non-oxidizing atmosphere.

Claim 10

The method of claim 1 wherein said polymer comprises a wholly aromatic polymer.

Claim 11

The method of claim 9 wherein said polymer comprises a wholly aromatic polyester.

Claim 12

The method of claim 10 wherein said polymer comprises a wholly aromatic polyester which comprises not less than about 10 mole percent of recurring units which include a naphthalene moiety.

Claim 13

The method of claim 11 wherein said wholly aromatic polyester exhibits an inherent viscosity of at least 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 14

The method of claim 11 wherein said naphthalene moiety of said wholly aromatic polyester is selected from the group consisting of a 6-oxy-2-naphthoyl moiety, a 2,6-dioxynaphthalene moiety, and a 2,6-dicarboxynaphthalene moiety.

Claim 15

The method of claim 10 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II, and III wherein: ##STR18## and wherein said polyester comprises approximately 30 to 70 mole percent of moiety I and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, an alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 16

The method of claim 10 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I and II wherein: ##STR19## and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, and approximately 10 to 90 mole percent of moiety II and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, and alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 17

The method of claim 10 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II, III, an IV wherein ##STR20## where R is methyl, chloro, bromo, or mixtures thereof, and is substituted for a hydrogen atom present upon the aromatic ring, and wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, an alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 18

The method of claim 10 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR21## III is a dioxy aryl moiety of the formula --0--Ar--O-- wherein Ar is a divalent radical comprising at least one aromatic ring, and IV is a dicarboxy aryl moiety of the formula ##STR22## where Ar' is a divalent radical comprising at least one aromatic ring, and wherein the polyester comprises approximately 20 to 40 mole percent of moiety I, in excess of 10 up to about 50 mole percent of moiety II, in excess of 5 up to about 30 mole percent of moiety III, and in excess of 5 up to about 30 mole percent of moiety IV, and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 19

The method of claim 10 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II and III wherein: ##STR23## II is a dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula ##STR24## where Ar' is a divalent radical comprising at least one aromatic ring, and wherein the polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 20

The method of claim 9 wherein said wholly aromatic polymer comprises a melt processable poly(ester-amide) which is capable of forming an anisotropic melt phase and which consists essentially of the recurring moieties I, II, and III and optionally IV wherein: ##STR25## II is ##STR26## where A is a divalent radical comprising at least one aromatic ring of a divalent transcyclohexane radical; III is [Y--Ar--Z], where Ar is a divalent radical comprising at least one aromatic ring, Y is O, NH, or NR, and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms or an aryl group; and IV is [O--Ar'--O], where Ar' is a divalent radical comprising at least one aromatic ring; and wherein said poly(ester-amide) comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, approximately 5 to 45 mole percent of moiety III, and approximately 0 to 40 mole percent of moiety IV, and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 21

A laminate which exhibits multiaxial orientation, possesses desirable mechanical properties and desirable thermal and chemical resistance comprised of at least two sheets of a substantially unidirectionally oriented polymer which is capable of forming an anisotropic melt phase, said at least two sheets being thermally bonded together and oriented at an angle with respect to one another.

Claim 22

A laminate which exhibits multiaxial orientation, possesses desirable mechanical properties and desirable thermal and chemical resistance comprised of at least two sheets of a substantially unidirectionally oriented polymer which is capable of forming an anisotropic melt phase, said at least two sheets being thermally bonded together and oriented at an angle with respect to one another.

Claim 23

The laminate of claim 20 wherein said sheets are thermally bonded together by heating at least one of said sheets to a temperature in excess of the melting temperature of the polymer which comprises said at least one sheet and pressing said sheets together.

Claim 24

The laminate of claim 21 wherein said at least one sheet is heated to a temperature between the melting temperature of the polymer which comprises said sheet and about 20 centigrade degrees in excess of said melting temperature.

Claim 25

The laminate of claim 20 wherein said at least two sheets are oriented at an angle of between about 30° and 90° relative to one another.

Claim 26

The laminate of claim 20 wherein said at least two sheets are oriented at an angle of about 90° relative to one another.

Claim 27

The laminate of claim 20 wherein said laminate has been subjected to a heat treatment at a temperature below the melting temperature of the polymer comprising said at least two sheets and for a period of time sufficient to increase the melting temperature of said polymer.

Claim 28

The laminate of claim 25 wherein said melting temperature is increased from between about 20 to about 50 centigrade degrees.

Claim 29

The laminate of claim 25 wherein said heat treatment temperature ranges from about 10 to about 30 centigrade degrees below the melting temperature of the polymer and said heat treatment occurs in a non-oxidizing atmosphere.

Claim 30

The laminate of claim 20 wherein said polymer comprises a wholly aromatic polymer.

Claim 31

The laminate of claim 28 wherein said polymer comprises a wholly aromatic polyester.

Claim 32

The laminate of claim 29 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II, and III wherein: ##STR27## and wherein said polyester comprises approximately 30 to 70 mole percent of moiety I and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, an alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 33

The laminate of claim 29 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I and II wherein: ##STR28## and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, and approximately 10 to 90 mole percent of moiety II and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, an alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 34

The laminate of claim 29 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR29## where R is methyl, chloro, bromo, or mixtures thereof, and is substituted for a hydrogen atom present upon the aromatic ring, and wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 5 carbon atoms, an alkoxy group of 1 to 5 carbon atoms, halogen, phenyl and substituted phenyl, and mixtures thereof.

Claim 35

The laminate of claim 29 wherein said wholly atomatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring ring moieties I, II, III, and IV wherein: ##STR30## III is a dioxy aryl moiety of the formula [O--Ar--O] wherein Ar is a divalent radical comprising at least one aromatic ring, and IV is a dicarboxy aryl moiety of the formula ##STR31## where Ar' is a divalent radical comprising at least one aromatic ring, and wherein the polyester comprises approximately 20 to 40 mole percent of moiety I, in excess of 10 up to about 50 mole percent of moiety II, in excess of 5 up to about 30 mole percent of moiety III, and in excess of 5 up to about 30 mole percent of moiety IV, and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 36

The laminate of claim 29 wherein said wholly aromatic polyester comprises a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase and consists essentially of the recurring moieties, I, II and III wherein: ##STR32## II is a dioxy aryl moiety of the formula [O--Ar--O] where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula ##STR33## where Ar' is a divalent radical comprising at least one aromatic ring, and wherein the polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 37

The laminate of claim 28 wherein said wholly aromatic polymer comprises a melt processable poly(ester-amide) which is capable of forming an anisotropic melt phase and which consists essentially of the recurring moieties I, II, III and optionally IV wherein: ##STR34## II is ##STR35## where A is a divalent radical comprising at least one aromatic ring or a divalent transcyclohexane radical; III is [Y--Ar--Z], where Ar is a divalent radical comprising at least one aromatic ring, Y is O, NH, or NR, and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms or an aryl group; and IV is [O--Ar'--O], where Ar' is a divalent radical comprising at least one aromatic ring; and wherein said poly(ester-amide) comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, approximately 5 to 45 mole percent of moiety III, and approximately 0 to 40 mole percent of moiety IV, and wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, substituted phenyl, and mixtures thereof.

Claim 38

The laminate of claim 20 wherein said polymer comprises a wholly aromatic polyester which comprises not less than about 10 mole percent of recurring units which include a naphthalene moiety.

Claim 39

The laminate of claim 36 wherein said wholly aromatic polyester exhibits an inherent viscosity of at least 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.

Claim 40

The laminate of claim 36 wherein said naphthalene moiety of said wholly aromatic polyester is selected from the group consisting of a 6-oxy-2-naphthoyl moiety, a 2,6-dioxynaphthalene moiety, and a 2,6-dicarboxynaphthalene moiety.