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US4721579A
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Sodium carboxymethyl derivatives of polyoxyalkylene glycols, their production, and use in functional fluids
Assignee: BASF Corp
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Filing: 1980-08-15
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Granted: 1988-01-26
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Expires: 2000-08-15
Abstract
Abstract A new type of ionic thickener for water-based products including functional fluids such as hydraulic fluids, cosmetic emulsions, etc. These new thickeners are prepared from polyoxyalklylene glycols, higher alkyl monoepoxides, lower alkyl monohalo lower alkyl carboxylates, and alkali metal hydroxide. These novel thickeners are generally characterized by the following formula: ##STR1## wherein R is a methylene or lower polymethylene group, R' is a higher alkyl group and R" is selected from the group consisting of oxyethylene groups and heteric or block copolymer mixtures of oxyethylene and other lower oxyalkylene groups, said copolymer containing at least 75 percent oxyethylene groups.
Inventors
- 👤 Bongsub Kim
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 14:41
CPC Classifications
A; A61; A61Q; A61Q19/00; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61K8/86; C; C08; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2603; C08G65/2606; C08G65/2609; C08G65/32; C08G65/321; C08G65/338; C10; C10M; C10M173/00; C10M173/02; C10M2201/00; C10M2201/02; C10M2207/00; C10M2207/02; C10M2207/021; C10M2207/022; C10M2209/00; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/107; C10M2209/108; C10N; C10N2020/00; C10N2020/01; C10N2050/00; C10N2050/01
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
39 words
A 4000 to, 20,000 molecular weight polyoxyalkylene polymer thickener characterized by the following formula: ##STR4## wherein R is a methylene or lower polymethylene group, R' is a higher alkyl group, and R" is a chain of lower oxyalkylene groups.
Claim 2
Dependent Claim
39 words
A 4000 to, 20,000 molecular weight polyoxyalkylene polymer thickener characterized by the following formula: ##STR4## wherein R is a methylene or lower polymethylene group, R' is a higher alkyl group, and R" is a chain of lower oxyalkylene groups.
Claim 3
Dependent Claim
68 words
The polymer of claim 1 wherein the R groups contain about 1 to 4 carbon atoms, the R' groups contain about 8 to 28 aliphatic carbon atoms, and R" contains about 90 to 450 oxyalkylene groups which are oxyethylene groups or heteric or block copolymers of oxyethylene and lower oxyalkylene groups having about 3 to 4 carbon atoms, said copolymers containing at least about 75 percent oxyethylene groups.
Claim 4
Dependent Claim
17 words
The polymer of claim 1 wherein R is a methylene group, and R" is all oxyethylene groups.
Claim 5
Dependent Claim
23 words
In an aqueous functional fluid the improvement wherein said functional fluid includes an effective thickening amount of the polymeric product of claim 1.
Claim 6
Dependent Claim
76 words
The improved functional fluid of claim 4 wherein the R groups of said polymeric product contain about 1 to 4 carbon atoms, the R' groups contain about 8 to 28 aliphatic carbon atoms, and R" contains about 90 to 450 oxyalkylene groups which are straight chain oxyethylene groups or heteric or block copolymers of oxyethylene and lower oxyalkylene groups having about 3 to 4 carbon atoms, said copolymers containing at least about 75 percent oxyethylene groups.
Claim 7
Dependent Claim
19 words
The improved functional fluid of claim 5 wherein R is a methylene group, and R" is all oxyethylene groups.
Claim 8
Dependent Claim
105 words
A process for producing a polymeric thickener product having a molecular weight of about 4,000 to 25,000 which comprises reacting a high molecular weight polyoxyethylene glycol containing about 90 to 450 oxyethylene groups or a heteric or block polyoxyethylene copolymer with lower alkylene oxides having about 3 to 4 carbon atoms and containing at least about 75 percent oxyethylene groups with an alkali metal, reacting the product thereof with a higher alkyl monoepoxide containing about 10 to 30 aliphatic carbon atoms, reacting the latter product with a lower alkyl monohalo lower alkyl carboxylate containing about 1 to 4 carbon atoms, and an alkali metal hydroxide.
Claim 9
Dependent Claim
105 words
A process for producing a polymeric thickener product having a molecular weight of about 4,000 to 25,000 which comprises reacting a high molecular weight polyoxyethylene glycol containing about 90 to 450 oxyethylene groups or a heteric or block polyoxyethylene copolymer with lower alkylene oxides having about 3 to 4 carbon atoms and containing at least about 75 percent oxyethylene groups with an alkali metal, reacting the product thereof with a higher alkyl monoepoxide containing about 10 to 30 aliphatic carbon atoms, reacting the latter product with a lower alkyl monohalo lower alkyl carboxylate containing about 1 to 4 carbon atoms, and an alkali metal hydroxide.
Claim 10
Dependent Claim
94 words
The process of claim 7 wherein the polyoxyalkylene glycol is reacted with the alkali metal at a temperature of about 20° to 200° C. for about 0.5 to 10 hours, the epoxide is reacted at a temperature from about 50° to 200° C. for about 0.5 to 10 hours, the lower alkyl monohalo lower alkyl carboxylate is reacted at a temperature of about 20° C. to 150° C. for a period of about 10 minutes to 5 hours, and the product is saponified with the alkali metal hydroxide for about 0.5 to 10 hours.
Claim 11
Dependent Claim
34 words
The process of claim 8 wherein said polyoxyalkylene glycol is polyoxyethylene glycol, said lower alkyl monohalo lower alkyl carboxylate is ethylmonochloroacetate, and said alkali metal in both the first and last steps is sodium.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1991-01-25 | 1991-07-27 | 1992-01-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-01-25 | 1995-07-27 | 1996-01-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-01-25 | 1999-07-27 | 2000-01-26 | $7700.00 | Window Closed / Lapsed |