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US4719267A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat curable one package polyurethane resin composition

Assignee: Essex Specialty Products LLC
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Filing: 1986-08-06
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Granted: 1988-01-12
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Expires: 2006-08-06
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Abstract

Abstract A heat curable one package polyurethane resin composition adaptable to use for automotive seam sealing, particularly under high solids acrylic enamel paints, said composition comprising an isocyanate terminated polyurethane prepolymer having pendant epoxy groups along the polymer chain and the isocyanate groups of which are blocked by reaction with an oxime, and a curing agent having at least two active hydrogen atoms per molecule, such as a polyol, a polyamine, or a blocked polyamine.

Inventors

  • 👤 Sidky Rizk
  • 👤 Harry W. S. Hsieh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:09
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/10; C09K3/1006; C09K3/1021; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/12; C08G18/28; C08G18/40; C08G18/4009; C08G18/4045; C08G2270/00; C09K2003/1034; C09K2003/1059

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 76 words
A one-package, solventless heat curable polyurethane resin composition consisting essentially of (1) an isocyanate terminated polyurethane prepolymer having pendant epoxy groups along the polymer chain and prepared by reacting an excess of a polyisocyanate with a mixture of a polyol and a di-o-methylol derivative of Bisphenol A diglycidyl ether, the isocyanate groups of which prepolymer are blocked by reaction with an oxime; and (2) a curing agent having at least two active hydrogen atoms per molecule.
Claim 2
Dependent Claim 76 words
A one-package, solventless heat curable polyurethane resin composition consisting essentially of (1) an isocyanate terminated polyurethane prepolymer having pendant epoxy groups along the polymer chain and prepared by reacting an excess of a polyisocyanate with a mixture of a polyol and a di-o-methylol derivative of Bisphenol A diglycidyl ether, the isocyanate groups of which prepolymer are blocked by reaction with an oxime; and (2) a curing agent having at least two active hydrogen atoms per molecule.
Claim 3
Dependent Claim 13 words
A composition as in claim 1 wherein said polyol is a polyether polyol.
Claim 4
Dependent Claim 14 words
A composition as in claim 2 wherein said polyether polyol is a polyether diol.
Claim 5
Dependent Claim 14 words
A composition as in claim 3 wherein said polyether diol is a polyoxyalkylene diol.
Claim 6
Dependent Claim 12 words
A composition as in claim 1 wherein said oxime is cyclohexanone oxime.
Claim 7
Dependent Claim 14 words
A composition as claimed in claim 1 wherein said curing agent is an amine.
Claim 8
Dependent Claim 52 words
A composition as in claim 1 wherein said curing agent is polyamide condensation product obtained by reacting approximately equimolecular amounts of an amine selected from the group consisting of diethylene triamine and triethylene tetramine with an anhydride selected from the group consisting of phthalic anhydride, hexahydrophthalic anhydride, maleic anhydride, and succinic anhydride.
Claim 9
Dependent Claim 18 words
A composition as in claim 7 wherein said amine is diethylene triamine and said anhydride is phthalic anhydride.
Claim 10
Dependent Claim 13 words
A composition as in claim 1 wherein said curing agent is a polyol.
Claim 11
Dependent Claim 24 words
A heat curable sealant comprising a composition as in claim 1 in combination with at least one filler suitable for use in elastomeric compositions.

References Cited (Backward Citations)

US3375299A Cited
DE1644813A1 Cited
US3639657A Cited
US3645943A Cited
US3886228A Cited
US4101497A Cited
EP0024501A1 Cited
US4500604A Cited
US4507443A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-11 1991-07-13 1992-01-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-11 1995-07-13 1996-01-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-11 1999-07-13 2000-01-12 $7700.00 Window Closed / Lapsed

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